• Journal of Environmental Health Sciences
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• v.27 no.1
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• pp.119-123
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• 2001

철 농도변화에 따른 대사산물 생성에 대한 반응은 중온조건에서 회분식 실험으로 수해하였다. 철의 농도가 40mg/$\ell$까지는 철 농도의 증가에 따라 수소생성율도 증가하였다. acetate 생성율은 철의 농도가 증가함에 따라 감소하였다. Butyrate, ethanol 및 butanol은 각각 철 농도가 200,200 및 400mg/$\ell$에서 최대 생성율을 나타내었다. 철의 농도가 200mg/$\ell$이상의 농도엘 때에 propionate, i-butyrate 및 valerate 생성율이 철의 농도가 200mg/$\ell$ 이하의 경우 보다 낮았다. 미생물농도의 경우 철 농도가 300mg/$\ell$까지는 농도가 증가함에 따라 미생물농도도 증가하였다.

• Proceedings of the KOSOMBE Conference
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• v.1992 no.11
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• pp.157-160
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• 1992

표면에 여러 가지 기능성기를 가지는 microspheres는 immunoassay, drug delivery system, cell separation등 의용공학분야에 응용이 기대되고 있다. 이들 분야의 응용을 위하여 유화제를 사용하지 않으면서, 기존의 회분식, 반회분식, seed 중합법등의 문제점을 극복한 two stage shot growth technique올 개발하여 여러 가지 기능성기가 표면에 도입된 microspheres를 제조하였으며, 응용의 전단계로서 이들 microspheres에 대한 모델 단백질(BSA)의 흡착실험을 pH, 기능 성기의 종류와 양, BSA농도를 변수로 행하여 최대 흡착량을 보이는 조건을 결정하였다.

• Clean Technology
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• v.18 no.3
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• pp.312-319
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• 2012

Malachite green is used a dye but malachite green is harmful toxic substance. In this study, the adsorption characteristics of zeolite has been investigated for the adsorption of malachite green dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of malachite green by a fixed amount of zeolite have been studied in batch adsorber and fixed bed. The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 25 to $45^{\circ}C$. The estimated values of k and ${\beta}$ are 23.60-46.88, 0.225-0.347, respectively. The mechanism of the adsorption process was determined from the intraparticle diffusion model. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet concentration and initial flow rate of malachite green are increased, the corresponding adsorption breaktime appears to decrease. Breaktime increased with increasing bed height and length of adsorption zone showed similar patterns.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.4
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• pp.2029-2035
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• 2014

In this study, we conducted the adsorption equilibrium and batch experiments of dissolved organic carbon (DOC) in the wastewater by granular activated carbon (GAC). The components of organic compound were Beef extract (1.8 mg/L), Peptone (2.7 mg/L), Humic acid (4.2 mg/L), Tannic acid (4.2 mg/L), Sodium lignin sulfonate (2.4 mg/L), Sodium lauryle sulfate (0.94 mg/L), Arabic gum powder (4.7 mg/L), Arabic acid (polysaccharide) (5.0 mg/L), $(NH_4)_2SO_4$ (7.1 mg/L), $K_2HPO_4$ (7.0 mg/L), $NH_4HCO_3$ (19.8 mg/L), $MgSO_4{\cdot}7H_2O$ (0.71 mg/L), The adsorption characteristics of DOC in synthetic wastewater was described using the mathematical model through a series of isotherm and batch experiments. It showed that there was linear adsorption region in the low DOC concentration (0~2.5 mg/L) and favorable adsorption region in high concentration (2.5~6 mg/L). The synthetic wastewater used was prepared using known quantities of organic and/or inorganic compounds. Adsorption modelling isotherms were predicted by the Freundlich, Langmuir, Sips and hybrid isotherm equations. Especially, hybrid isotherm of Linear and Sips equation was a good adsorption equilibrium in the region of the both the low concentration and high concentration. In applying carbon adsorption for treating water and wastewater, hybrid adsorption equation plus linear equation with Sips equation will be a good new adsorption equilibrium model. Linear driving force approximation (LDFA) kinetic equation with Hybrid (linear+Sips) adsorption isotherm model was successfully applied to predict the adsorption kinetics data in various GAC adsorbent amounts.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.6
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• pp.363-370
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• 2015

The production of polyhydroxyalkanoates (PHAs) using Sequencing Batch Reactor (SBR) was investigated. The experiments were performed in two fabricated SBRs (4 L) of different oxidation state. Synthetic wastewater was used as substrate, using C/N/P ratio of 42:10:1. SBR 1 and SBR 2 were operated in aerobic dynamic feeding (ADF) and anaerobic/oxic dynamic feeding (AODF) condition, respectively. ADF provide feast and famine in aerobic condition, while AODF in anaerobic/oxic condition. PHAs production was found high in AODF than AOF. Maximum PHAs content of 40.0% (w/w)of biomass were produced in AODF mode. Produced PHAs structural and thermal property were good.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.24-30
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• 2002

The laboratory adsorption batch tests were performed to investigate the adsorption characteristics of Pb on kaolinite. The characteristics such as adsorption equilibrium time, adsorption capacity, adsorption isotherm were studied, and also the effects of pH and the mixing ratio on the adsorption of Pb on kaolinite were investigated. Test results show that the adsorption equilibrium state was reached within 24 hours, and the adsorbed amount of Pb increased, but the adsorption efficiency over the initial concentration of 198 mg/l decreased, with increasing the initial concentration of Pb. And the adsorption constant, 1/n was obtained 0.9584 by Freundlich isotherm equation. Regardless of the initial concentration of Pb. the adsorbed amount of Pb as well as the adsorption efficiency were increased with increasing pH values and converged to a certain constant value above 8 of pH values. And also the adsorbed amount of Pb increased with the mixing ratio, but its efficiency increased with the mixing ratio up to 8 and then showed the decreasing tendency above that.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.247-252
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• 2005

The typical treatment method for fluoride polluted water is the flocculation and precipitation method which usually is capable of reducing the fluoride concentration down to the level of about 10 ppm. However, this method is no longer effective for the treatment of contaminated water having less than 10 ppm of fluorides. To remove fluorides in polluted water from the fluoride concentration between 1 to 10 ppm, several adsorbents were prepared mainly based on an activated alumina and the fluoride removal efficiencies of the adsorbents were analyzed. The best fluoride removal efficiency was obtained when the activated alumina treated by sulfuric acid was used as the adsorbent. A proper calcination temperature for the sulfuric acid contained activated alumina was found to be about $500^{\circ}C$. An adsorption isotherm for the adsorbent was also obtained by using Freundlich model. The values of the constants in Freundlich isotherm model were calculated to be K=6.63 and 1/n=0.29 based on the results obtained from the series of batch type adsorption experiments.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.4
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• pp.269-275
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• 1993

The performance of Upflow Anaerobic Sludge Blanket(UASB) reactor for treatment of corn starch wastewater was investigated using continuous and batch experiment. Results showed that the corn starch wastewater had different characteristics in terms of biodegradability and methane potential, depending on the manufacturing precess. COD removal efficiencies were maintained over 70% up to the loading rate of 3.2 kg $COD/m^3{\cdot}day$ and the maximum gas production rate was about 55 l/day, equivalent to 3.5 l/day per liter of reactor volume, at the loading rate of 8.4 kg $COD/m^3{\cdot}day$. In the anaerobic serum bottle test(SBT) carried out along with continuous operation, the sludge activity was found to increase from 0.03 to 0.53 g $COD-CH_4/g\;VSS{\cdot}day$ as granular sludges were developed in 130 days operation. SBT gave valuable informations on the characteristics of wastewaters to be treated as well as on the sludge activity. The overall morphological characteristics of granular sludges cultivated on corn starch wastewaters were similar to those cultivated on various organic industrial wastewaters such as distillery and sugar.

• Journal of the Korean Society of Marine Environment & Safety
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• v.14 no.2
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• pp.105-109
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• 2008

In our country, limiting nutrient is known as phosphorus in the most lakes. Therefore, the removal of phosphorus is a very important process in sewage treatment. However, many of the sewage treatment plants employ the conventional activated sludge process, known to remove $10{\sim}30%$ of phosphorus. Thus, additional phosphorous removal process will be needed. Oyster shells have been known to remove phosphorus in water. The removal efficiency of phosphorus was highest at smallest size of oyster shells and at the highest pH for batch test. The phosphorous removal rate with various calcium concentrations was increased by increasing calcium concentration. At the 20 mg/l of calcium, more than 90% of phosphorous was removed in two hours. The removal efficiency of phosphorous was increased greatly at 300% of recirculation rate. With 300% of recirculation rate, the removal efficiency reached 80% at pH 11. The negative effects of bicarbonate on crystallization were observed in oyster shells. The effects of bicarbonate on rate constant were also investigated by applying these results to experimental equation. The rate constant was decreased at the inverse logarithm bicarbonate concentration.

• Journal of the Korean Geotechnical Society
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• v.15 no.5
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• pp.241-257
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• 1999

Subsurface contamination of industrial hazardous organic substances is a serious social issue. Decomposing the hydrophobic organic compounds in the subsurface is technically difficult and the compounds can last as long-term contaminant sources of groundwater once they are sorbed on the soil. Although the danger of contaminated subsurface has long been recognized little was known about the effective remediation technique. Focusing on the remediation of the p-Cresol and 3, 5-Dichlorobiphenyl among subsurface contaminants, this paper studies the surfactant-enhanced desorption technique. Nonionic surfactant(Triton X-100) and anionic surfactant(SDS ) were used as desorbing solvents for extracting organic compound sorbed on soil particles. Sorption characteristics of soils and organic compounds were analyzed and the applications of surfactant solution were studied through batch tests and the flexible-wall permeameter tests. As a result of the sorption isotherm tests, a log-log linear relation was obtained between the linear-partition coefficient, $K_p$ and the octanol-water partition coefficient, $K_{ow}$ of each organic compound. The result of the batch test also showed that Triton X-100 at 0.5% of solution desorbs the 3, 5-Dichlorobiphenyl 28 times more than the water in the batch tests. The surfactant-enhanced subsurface remediation technique becomes more effective when the contaminants are hydrophobic and hard to be decomposed.