• Title/Summary/Keyword: 황화학

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Improvement of Water Quality in Shrimp Aquaculture Farms of Southwestern Coastal Area of Korea (서남해역 새우 양식장의 수질현황과 수질개선방안)

  • Kim Do-Hee;Lee Ha-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.4
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    • pp.159-163
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    • 2004
  • This study was performed to estimate the water quality of pH, salinity, dissolved oxygen, ammonium and sulfur hydroxides of sediment in shrimp aquaculture farms of Southwestern coastal of Korea from June to September, 2003. We surveyed the status of water quality and achieved the improve water and sediment quality to restraint the production of ammonium and sulfur hydroxides from sediment of shrimp aquaculture farms. The concentrations of dissolved oxygen increased from noon to the evening for 6 hour and decreased to 2.98 ppm at six o'clock in the next morning and increased repeatedly, even though DO level has a different level in sunny day and cloudy day. This results suggest that the most importance time of the control of DO in shrimp aquaculture farm is next early morning and if the DO concentration increased continuously which may be growing up the concentrations of NH₄/sup +/ and H₂S. The measured of pH and salinity were suitable to growth of shrimp. However, the level of ammonium and sulfur hydroxides produced from the sediments of shrimp aquaculture farms were 2.30 ppm and 0.075 ppm, respectively, which are exceeded to the concentration of guide line for the growth of shrimp. In the results of this study, we found it difficult to improve the water quality using of the present frame of shrimp aquaculture farms. Then, we can improved water quality of DO, NH₄/sup +/ and sediment quality of ORP, H₂S and also achieved down to the rate of shrimp fatal by changed the frame of shrimp aquaculture farms in the scale of laboratory.

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Development of 10 μmol/mol Hydrogen Sulfide Primary Standard Gas for Odor Measurements (악취측정용 10 μmol/mol 황화수소 표준가스 개발)

  • Kim, Yong-Doo;Bae, Hyun-Kil;Kim, Dalho;Oh, Sang-Hyub;Lee, Jin Hong;Lee, Sangil
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.46-51
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    • 2018
  • Hydrogen sulfide from landfill and sewage treatment plant is a major odor component and causes many civil petitions. Rapidly developing industries release hydrogen sulfide, an odorous gas, to the atmosphere. This study aims to develop a $10{\mu}mol/mol$ concentration level hydrogen sulfide primary standard gas for odor measurement. The hydrogen sulfide gas was prepared at a nominal concentration of $10{\mu}mol/mol$ in nitrogen using the gravimetric method described in ISO 6142. Replicate standard gases were produced in 4 aluminium cylinders, and their concentrations were verified by GC-AED. The uncertainty of production was less than 0.50 %, and the variation of the 4 replicates was 0.22 %. The wall adsorption of hydrogen sulfide in cylinders was 0.10 % at 1500 psi, and the concentration was estimated to be long-term stable for one year. The relative expanded uncertainty of the preparation consistency, adsorption and long-term stability of this hydrogen sulfide standard gas was less than 1.05 % (95 % of confidence level, k=2).

Acute Toxicity of Nitrite, Ammonia and Hydrogen Sulfide for Early Developmental Stages of Fenneropenaeus chinensis (대하의 초기생활사에 있어 아질산, 암모니아 및 황화수소의 급성독성)

  • Ji, Jeong-Hun;Gang, Ju-Chan
    • Journal of fish pathology
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    • v.17 no.3
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    • pp.199-205
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    • 2004
  • Effects of nitrite, ammonia and hydrogen sulfide on survival of the early developmental stages of Fenneropenaeus chinensis were determined under continuous flow-through system. The 96hr-$LC_{50}$ values of mysis stage were 18.4 mg/L, 0.69 mg/L and 13.5 $\mu{g}/L$ for nitrite, ammonia and hydrogen sulfide, respectively; 28.3 mg/L, 1.23 mg/L and 20.7 $\mu{g}/L$ for post larva stage and 39.8 mg/L, 1.73 mg/L and 28.5 $\mu{g}/L$ for juvenile stage, respectively. The Fenneropenaeus chinensis sensitivity for the three pollutants was in the order of hydrogen sulfide>ammonia>nitrite. The mysis/post larva, mysis/juvenile and post larva/juvenile ratios of nitrite, ammonia and hydrogen sulfide toxicity were >1.5, >2.0 and <1.5 times, respectively, and mysis were found to be more sensitive to pollutants than juvenile in all cases.

Histochemical Studies of the Goblet Cell of the Oviduct in Korean Ring-necked Pheasants(Phasianus colchicus karpowi) (한국산 꿩 난관의 술잔세포에 관한 조직화학적 연구)

  • 최성도;로경란;김인식;양홍현
    • Korean Journal of Poultry Science
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    • v.29 no.3
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    • pp.177-183
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    • 2002
  • The study was designed to investigate the aspects of the goblet cell of the oviduct in laying Korean ring-necked pheasants by histochemical methods (PAS, alcian blue-PAS, alcian blue pH 2.5, alcian blue pH 1.0, and aldehyde fuchsin-alcian blue stain). Twelve laying Korean ring-necked pheasants were used. The results were summarized as follows. The goblet cell of the oviduct of the Korean ring-necked pheasant contained sulfated acid mucosubstances and neutral mucosubstances in the infundibulum. The compounds of sulfated acid mucosubstances, nonsulfated acid mucosubstances, and neutral mucosubstances are present in goblet cells of the magnum, vagina and openings of the tubular gland of the uterus of the oviduct in the Korean ring-necked pheasant. The goblet cell of the isthmus and uterus of the oviduct of the Korean ring-necked pheasant contained neutral mucosubstances except openings of the tubular gland of the uterus. The histochemical characteristics of secretory granules of goblet cells in oviduct of the Korean ring-necked pheasant were not related to the position of eggs in oviduct.

Induction of Red Discoloration in Rice var. Tongil with Certain Metabolic Inhibitors (대사저해제에 의한 "통일"벼 적고현상 유발에 관하여)

  • Beyoung-Hwa Kwack;Chan Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.15
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    • pp.115-121
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    • 1974
  • Artificial induction of nitrogen deficiency symptoms (leaf chlorosis) with two root respiratory inhibitors(DNP and Na$_2$S) was studied and regarded to be the same characteristic to red discoloration in rice var. Tongil seedling leaves as well as adult ones. Tongil(IR 667) was shown to be more nitrogen sensitive and have more distinctive appearance of the leaf discoloration than Punggwang(a native Japonica-type varity.) Conclusions were drawn from the present data that so-called red discoloration of Tongil under the natural field conditions is brought about either by insufficient nitrogen supply in soils or certain factors which may limit at any time the root absorption of nitrogen (low temperature, toxic gases or substances, poor drainage, around roots, etc.) in soils even with ample supply of it.

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Hydrogen Sulfide Removal of Biogas from Sewage Treatment Plant with Micro-bubble Generation System (마이크로버블 장치를 이용한 하수처리장 바이오가스의 황화수소 제거)

  • Jung, Jae-Ouk;Jung, Yong-Jun
    • Journal of Wetlands Research
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    • v.22 no.4
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    • pp.239-244
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    • 2020
  • Prior to utilization of energy and power generation, the biogas from anaerobic digestion of sewage treatment plant(46,000㎡/d) should be purified particularly hydrogen sulfide among the various kinds of impurities. This study has focused on the methane decreasing rate and the removal of both hydrogen sulfide and carbon dioxide. In the case of partial circulation, 59.7% of methane gas was decreased to 57.4% in spite of oxidation process with micro-bubble. Carbon dioxide was removed from 38% to 32% and 76.1% of hydrogen sulfide was removed where 1,400ppm was introduced to the DIWS system, which indicated that DIWS system can be of use for the hydrogen sulfide removal of biogas from sewage treatment plant.

Myosin Heavy Chain Covalenily Modified at Its Reactive Site Sulfhydryl Residues is Preferentially Degraded by Calpain (활성화 부위의 황화기가 화학적으로 변형된 Myosin Heavy Chain의 Calpain에 의한 선택적 분해)

  • 곽규봉;정성수;이창호;하두봉;정진하
    • The Korean Journal of Zoology
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    • v.36 no.3
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    • pp.347-352
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    • 1993
  • N-ethylmaleimide at low concentrations is known to interact specifically with 2 sulfhydryl residues in myosin heavy chain. Calpain, a Ca$^2$+-dependent neutral protease isolated from chick skeletal muscle, was found to preferentially degrade the alkylated protein but much less significantly the unmodified protein. Exposure of myosin to KMnO$_4$, which is also known to interact with sulthydryl groups, also caused the rapid degradation of the myosin heavy chain. Furthermore, treatment of each agent with increasing concentrations results in a greater loss of the myosin ATPase activity, indicating that the modification occurred at the reactive site sulfhydryl residues. These results suggest that the covalent modification at the reactive site salfhydryl residues in the myosin heavy chain may mark the protein for degradation by intracellular proteases such as calpain.

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Characterization of Uranium Removal and Mineralization by Bacteria in Deep Underground, Korea Atomic Energy Research Institute (KAERI) (한국원자력연구원 지하심부 미생물에 의한 용존우라늄 제거 및 광물화 특성)

  • Oh, Jong-Min;Lee, Seung-Yeop;Baik, Min-Hoon;Roh, Yul
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.2
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    • pp.107-115
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    • 2010
  • Removal and mineralization of dissolved uranium by bacteria in KURT (KAERI Underground Research Tunnel), Korea Atomic Energy Research Institute (KAERI) was investigated. Two different bacteria, IRB (iron-reducing bacteria) and SRB (sulfate-reducing bacteria) was used, and minerals formed by these bacteria were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Compared to uranyl ions, ferric ions were preferentially reduced by IRB, showing that there is no significant reduction and removal of uranium. However, uranium concentration considerably decreased by addition of Mn(II). Results show that a sulfide mineral such as mackinawite (FeS) is formed by SRB respiration through combination of Fe(II) and S without manganese sulfide formation. In the presence of Mn(II), however, uranium is removed effectively, suggesting that the sorption and incorporation of uranium could be affected by Mn(II) onto the sulide minerals.

Development of Porous Sorbents for Removal of Hydrogen Sulfide from Hot Coal Gas -II. Kinetics of Suffidation on Zinc Oxide - (고온석탄가스에서 황화물을 제거하기 위한 다공성 흡착제의 개발 -II. 산화아연의 황화반응에 관한 연구-)

  • 서인식;이재복;류경옥
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.11-22
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    • 1988
  • Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H$_2$S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO$_2$ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li$_2$O sorbents were ineffective.

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Evidence for Hydrothermal Plume in Manus Basin, SW Pacific: Distribution of Transparency and Hydrogen Sulfide (남서태평양 마누스분지 해역의 열수 plume 증거: 투명도 및 황화수소 분포)

  • Lee, Kyeong-Yong;Park, Yong-Chul;Son, Seung-Kyu
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.363-373
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    • 2000
  • To understand and investigate chemical characteristics of thermal environment in the southwestern Paciflc, we have measured hydrological and chemical parameters such as temperature, salinity, transparency, pH, nutrients and hydrogen sulfide (H$_2$S). Samples were collected with CTD-casting at 12 station, in Manus Basin including PACMANUS, DESMOS and Susu Knolls, Hydrothermal systems consist of circulation zones where seawater interacts with rock, thereby changing chemical and physical characteristics of both the seawater and the rock. The altered seawater, called hydrothermal fluid, is injected back into the ocean from the hydrothermal vent fields and forms hydrothermal plumes. Consequently, we detected hydrothermal plume with transparency and sulfide anomalies at PACMANUS and Susu Knolls. Sulfide, as geochemical tracer of hydrothermal plume, ranged 0-3.31 ${\mu}$M, and averaged 0.63 ${\mu}$M in the study area. The height, flux and activity of the plume are affected by circulations in the deep water and the spread of plume follows along the isopycnal surface. Therefore the observed H$_2$S anomaly can provide important clue for the source location and it appears that the targestsource in the PACMANUS is aligned in the north-south direction.

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