• Title/Summary/Keyword: 황산동

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Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.63-72
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    • 2001
  • An alternating current (AC) corrosion using coupon and electric resistance (ER) probe has been studied. Coupon coupled with ER probe were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, In which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619 in case of coupon and 0.885 in case of ER probe.

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Production of Rice Straw Based Cellulosic Ethanol Using Acidic Saccharification (산당화과정을 이용한 볏짚으로부터 셀룰로스 에탄올의 제조)

  • Lee, Seung-Bum;Jung, Soo-Kyung;Lee, Jae-Dong
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.349-352
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    • 2010
  • The production process of cellulosic ethanol from rice straw using acidic saccharification was studied in this experimental work. The hydration by ultrasonic energy and the acidic saccharification using 10~30 wt% of $H_2SO_4$ were performed as pretreatment processes. Also, 10~50 wt% of yeast for 3~6 days was used for fermentation process. The yield of cellulosic ethanol was decided in the fermentation process. The optimum pretreatment condition was 375W of ultrasonic power and 30 min of hydration time using 20 wt% of $H_2SO_4$ and 2 h of the acidic saccharification time. Finally, the optimum fermentation condition was at the condition of 30 wt% of yeast and 3 days of fermentation time.

Field Tests for the Application of Bottom Ash and Shred Tire as Fill Materials (석탄회 및 폐타이어의 성토재로의 적용성 검토를 위한 현장시험)

  • Lee, Sungjin;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.10
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    • pp.29-37
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    • 2013
  • In this study, we constructed the test embankment with four kinds of sections(2 kinds of bottom ash; tire shred-bottom ash mixture, weathered soil) in field and had been monitoring the behaviour of the test embankment and change of ground water quality for 1 year. In the geotechnical aspects, there was no relative difference of deformation in 4 test materials section and we could not see the possibility of the strength-reduction of coal ash materials by freezing inside of the embankment. In addition, no settlement was observed in the test sections because the base soil of the test sections was rigid enough that no consolidation was occurred. In the examination of water quality, all of the heavy metals and negative ions were detected below the drinking water standards except for sulfate($SO_4^{2-}$). In the beginning of measurement, higher concentrations of sulfate from 4 test sections were detected than drinking water standard for 20 days after beginning of the test but the concentrations decreased below the drinking water standard after 50 days after the tests.

The Experimental Study on The Compressive Strength of Mortar Using High Quality Recycled Fine Aggregate Produced by Sulphuric Water and Low Speed Wet Abraser (황산수와 저속습식마쇄기로 생산된 고품질 순환 잔골재의 모르타르 압축강도에 관한 실험적 연구)

  • Choi, Duck-Jin;Lee, Dae-Guen;Han, Sang-Il;Kim, Ha-Suk;Jun, Myong-Hun;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.485-488
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    • 2008
  • Recycled fine aggregate has low quality because it contains large amount of old mortar. So, its usage is limited to a lower value-add, such as the roadbed material etc. Also, alkaline water occurred from treatment process of the waste concrete is becoming the cause of environmental problem. Accordingly, this study is to develop on the high quality recycled fine aggregate produced by low speed wet abraser using sulphuric. We investigated the properties of compressive strength of the mortar which was manufactured using recycled fine aggregate containing calcined gypsum produced by earlier mentioned process. Test results indicate that mortar using recycled fine aggregate containing calcined gypsum has lowest compressive strength. It seems that low compressive strength is closely associated with the expansion of the specimen by excessive formation of ettringite.

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Anaerobic Corrosion Properties of Sangpyeongtongbo Excavated at Bigyeongdo, Seosan (서산 비경도 출수 상평통보의 혐기성 부식 특성)

  • Kim, Kyu Been;Chung, Kwang Yong
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.167-179
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    • 2017
  • In this study, Sangpyeontongbo excavated at Bigyeongdo, Seosan, were investigated to determine the components of the corrosion products that were formed while they were buried underwater in an anaerobic environment. The causes of corrosion product formation were also determined. Microstructure observation, element mapping, principle component analysis for each year, and the detection of corrosion products were carried out. Results indicate that the concretions of corrosion products on the surface are needle-, hexahedral-, and octahedral-shaped; Pb, Cu, and S were among the elements detected. The Cu-S layer was clearly verified using element mapping. An analysis of major elements for each layer showed that Cu, S, and Pb were present and that most Zn was eliminated. The corrosion products detected were $PbCO_3$ (concretion) and $Cu_{1.96}S$ (metal). Accordingly, the anaerobic corrosion properties of Sangpyeongtongbo are summarized as follows: dezincification, copper sulfide, and lead compound.

Effect of Metal Ions on the Oxidation of Soybean Oil and Its Fried Noodle (각종(各種) 금속(金屬) 이온이 대두유(大豆油)및 그 튀김 면(麵)의 산패(酸敗)에 미치는 영향에 대(對)하여)

  • Choe, Myen;Kim, Tae-Woong;Lee, Yang-Hee
    • Korean Journal of Food Science and Technology
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    • v.9 no.2
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    • pp.157-164
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    • 1977
  • In the present study, the proxidant effect of ferrous and cupric chlorides which added to soybean oil and its fried noodle in the same concentration of the city water and the physically refined underground water were determined. As the inhibitor of metal proxidation, BHA and citric acid which are used widely in oil industry as antioxidants were compared. In both cases of soybean oil and its fried noodle, the addition of cupric chloride and ferrous chloride showed prominent proxidant effect. Especially, cupric chloride marked more proxidant effect than ferrous chloride by 3 to 6 times with the elapse of time. In the inhibition activity of metal proxidation, citric acid was more effective than BHA. The 1ppm of Cu +0.01% of citric acid treated soybean oil showed less proxidant effect than the control at the later stage. The inhibition activity of citric acid on $Fe^{++}$ in soybean oil was more effective than $Cu^{++}$ in soybean oil.

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Inhibition of Pitting Corrosion of Copper Tubes in Wet Sprinkler Systems by Sodium Sulfite (아황산나트륨을 이용한 스프링클러 동배관 공식 부식 방지)

  • Suh, Sang Hee;Suh, Youngjoon;Kwon, HyukSang
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.265-272
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    • 2017
  • Inhibition of pitting corrosion of the copper sprinkler tubes by removing dissolved oxygen in water with sodium sulfite was studied on the wet sprinkler systems operated in 258 household sites. First, air in the sprinkler tubing was removed by vacuum pumping. The tube was then filled with sodium sulfite dissolved in water. Sodium sulfite was very effective in maintaining a very low dissolved oxygen concentration in water in the sprinkler tube for the observation period of six months. Water leakage from the copper sprinkler tube was reduced significantly by using sodium sulfite. Both pitting corrosion process and pitting corrosion inhibition mechanism were investigated by examining microscopical and structural aspects of corrosion pits formed in failed copper sprinkler tube. Pitting corrosion was caused by pressurized air as well as sediments such as sand particles in copper tubes through oxygen concentration cells. It was confirmed microscopically that growth of corrosion pits was stopped by reducing dissolved oxygen concentration to a very level by using sodium sulfite.

Chemical Degradation of Tungsten Oxide Thin Films (텅스텐 산화물 박막의 화학적 퇴화)

  • Lee, Kil-Dong
    • Solar Energy
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    • v.15 no.3
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    • pp.141-149
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    • 1995
  • The tungsten oxide thin films were prepared on $s_i$ wafer by using an electron-beam evaporation technique. Thickness and structure of tungsten oxide film degraded in various electrolytes were analyzed by Rutherford backscattering spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. Thickness of $WO_3$ film was the most dissolved in 1M $H_2SO_4$ electrolytye. We have confirmed that the degradation of this films was accelerated by $H_2O$ in electrolytes. But the electronic structure of film degraded by electrolyte contained of glycerol was not changed as comparision with as-deposited film. The degradation may be attributed to a change of thickness and the surface morphology of the film.

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The Effect of Sulfur Dioxide by Burn out on Enzyme Activity and Lipid Content in Rats (소환시 발생되는 아황산 가스가 흰쥐 혈청 중의 효소 활성도 및 지질 함량에 미치는 영향)

  • Kim, Hae-Dong;Kim, Byung-Hak;Ha, Hun;Cho, Soo-Yeul;Yoon, Soo-Hong
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.61-66
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    • 1997
  • Recently, incidences of pulmonary-related diseases are increasing and natural ecosystem is destroyed year by year owing to air pollutions by industrial noxious gases such as sulfur dioxide and carbon dioxide, etc. Sulfur dioxide produced by oxidation of sulfur compounds is water soluble and causes several kinds of pulmonary diseases, damaging on plants and animals. This study was undertaken to investigate effects of acute exposure of rats to sulfur dioxide using biochemical parameters. The sAST (aspartate transaminase) activity was not significantly affected but sALT (alanine transaminase), sLDH (lactate dehydrogenase) and sALP (alkaline phosphatase) activities were significantly increased by acute sulfur dioxide gas exposure. Also sulfur dioxide gas treatment significantly diminished serum cholinesterase activity. The total lipid, triglyceride, total-, HDL- and LDL-cholesterol contents were significantly increased by sulfur dioxide gas exposures. But the body and liver weight were generally diminished in comparison with control group. Our results' showed increased enzyme activities and lipid contents, but body and liver weight were all diminished by sulfur dioxide gas treatment.

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Evaluation of cement mortars blended with copper alloy slag (구리 합금 슬래그를 혼합한 시멘트 모르타르의 특성)

  • Lee, Jung-Il;Hong, Chang Woo;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.1
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    • pp.39-43
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    • 2015
  • The cement mixtures such as flyash, iron-slag and silica fume have been actively studied in order to increase the quality of concrete. In this study, the grinded copper-slag with different proportion was added to portland cement. The physical properties of the cement mortars, (i.e.) flowability, absorption, compressive strength and flexural strength, were investigated for the potential application to the cement. Also, the influence of the acid on the chemical resistance of the cement mortars with copper-slag was evaluated by monitoring the weight variation of the cement mortars under 5 % sulfuric acid for 28 days.