• Title/Summary/Keyword: 활성슬러지 부유물질

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Advanced Treatment of Sewage and Wastewater Using an Integrated Membrane Separation by Porous Electrode-typed Electrolysis (분리막/다공 전극형 전기분해 조합공정을 이용한 하.폐수의 고도처리)

  • Choi, Yong-Jin;Lee, Kwang-Hyun
    • Membrane Journal
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    • v.22 no.2
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    • pp.95-103
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    • 2012
  • To treat nitrate and non-biodegradable organics effectively in sewage, industrial wastewater and livestock wastewater, the activated sludge process integrated by a membrane separation and a porous electrode- electrolysis was proposed and its efficiency was investigated. The proposed system was consisted of 3 processes; activated sludge, membrane filtration and electrolysis. In the study, the membrane filtration played a role in reducing the load of the electrolysis to operate the proposed process stably. The electrolysis consisted of a porous electrode to increase the efficiency due to the extension of the specific surface area. Additionally, redox reaction in the electrolysis was induced by decomposing influent water as current was applied. As a result, hydrogen free radicals and oxygen radicals as intermediates were produced and they acted as oxidants to play a role in decomposing non-degradable organics. It was environmentally-friendly process because intermediates produced by porous electrode were used to treat waste matters without supplying external reagent. Experimental data showed that the proposed process was more excellent than activated sludge process. SS removal efficiencies of the proposed process, membrane filtration and activated sludge process were about 100%, about 100% and about 90%, respectively. COD removal efficiencies of the proposed system, membrane filtration and activated sludge process were about 92%, about 84% and about 78%, respectively. T-N removal efficiencies of the proposed system, membrane filtration and activated sludge process were about 88%, about 67%, and about 58%, respectively. The SS data showed that SS was efficiently removed in the single of the membrane filtration. The COD/T-N data showed that COD/T-N of membrane hybrid process was treated by removing a little soluble organics and SS, and that COD/T-N of electrolysis hybrid process was treated by oxidize organics with high removal rate.

Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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Process variations in SBR and BS-SBR treatment (SBR 및 BS-SBR 처리의 공정변화 연구)

  • 양형재;정윤철;신응배
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.59-68
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    • 1997
  • The main purpose of this study was to determine effects of BS-SBR compared with SBR on the removal of soluble organics and sludge separation. In the BS-SBR process, soluble organics were removed by suspended activated sludge as well as biological fixed films and these two processes occurred simultaneously in one tank. The removal efficiency of soluble COD in the BS-SBR, approximately 97% in both 1 and 3-cycle/d was higher than for SBR. The BS-SBR process was very efficient for SS removal. The averaged SS concentration were 4.8 mg/l over the operation period, the daily SS values were consistently below 10 mg/l in both of 1-cycle and 3-cycle a day. The sludge settling characteristics in BS-SBR were totally different from SBR's. The sludge, dark brown, was well flocculated and its floc size was visible larger than the SBR's.

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Waste Activated Sludge Digestion with Thermophilic Attached Films (친열성(親熱性) 생물막공법(生物膜工法)을 이용(利用)한 폐활성(廢活性) 슬러지의 혐기성(嫌氣性) 소화(消化))

  • Han, Ung Jun;Kabribk, R.M.;Jewell, W.J.
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.5 no.4
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    • pp.31-44
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    • 1985
  • The application of anaerobic attached microbial films in the expanded bed process has recently been examined at high temperatures ($55^{\circ}C$) and with particulate matter. Extrapolation of the kinetics suggested that waste activated sludge (WAS) could be efficiently digested at hydraulic retention times as short as six hours in the expanded bed process. This would represent a 99 percent digester reactor volume reduction and would introduce interesting solids management alternatives if such a high rate process were developed. This paper presents a summary of a 1.5 year study of the feasibility of such a process. Three continuously fed $55^{\circ}C$ laboratory reactor systems were used to define the kinetics and the site of reactions-control completely mixed reactors were compared to the expanded beds (AAFEB) with and without a hydrolysis unit preceding the attached film unit. Well defined laboratory-generated WAS was compared to actual WAS from a domestic sewage treatment facility. Sixty percent of the biodegradable organics were converted in an AAFEB at a 15-hour hydraulic retention time without hydrolysis, whereas greater than 95 perccent of the biodegradable organics were stabilized in a two-stage system consisting of a 3-day HRT hydrolysis reactor followed by a 15-hour HRT AAFEB. The limitations of this high rate process and its potential application are discussed.

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A Biological Reaction Modeling in Sewage Water Treatment Systems (하수처리장에서 생물학적 반응 특성에 대한 모델)

  • 이진락;양일화;이해영
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.4
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    • pp.37-42
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    • 2001
  • This paper resents a biological reaction model of describing processing features in treating wastewater via activated sludge A proposed model is designed by combining fuzzy rules investigating several elements which have influence on variables to be supervised BOD and SS are suggested as common variables in input and output variables, and O$_2$quantity is closed as input variable. We chose triangular type membership functions for input variables and determined the grades in each membership function based upon process data According to simulation result to show the validity of proposed model, fuzzy model's outputs give almost similar data to process output under same input conditions.

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Characteristic Features and Effect of Neo-Hydrofoil Impeller Applied in Sewage Treatment Plants (하수처리 공법별 네오하이드로포일 교반기의 적용 특성 및 효과)

  • Joo, Yoon-Sik;Son, Guntae;Bae, Youngjun;Lee, Seunghwan
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.2
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    • pp.187-196
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    • 2016
  • In this study, a newly developed agitator with hydrofoil impeller applied to actual biological process in advanced wastewater treatment plant was evaluated. Several series of experiments were conducted in two different wastewater treatment plants where actual problems have been occurred such as the production of scums and sludge settling. For more effective evaluation, computational fluid dynamics (CFD) and measurements of MLSS (Mixed Liquor Suspended Solids) and DO (Dissolved Oxygen) were used with other measuring equipments. After the installation of one unit of vertical hydrofoil agitator in plant A, scum and sludge settling problems were solved and more than seventy percent of operational energy was saved. In case of plant B, there were three cells of each anoxic and anaerobic tanks, and each cell had one unit of submersible horizontal agitator. After the integration of three cells to one cell in each tank, and installation of one vertical hydrofoil agitator per tank, all the problems caused by improper mixing were solved and more than eighty percent of operational energy was found to be saved. Simple change of agitator applied to biological process in wastewater treatment plant was proved to be essential to eliminate scum and sludge settling problems and to save input energy.

Modelling of Nitrogen Oxidation in Aerated Biofilter Process with ASM3 (부상여재반응기에서 ASM3를 이용한 질산화 공정 모사)

  • Jun, Byonghee
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.4
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    • pp.19-25
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    • 2007
  • Process analysis with ASM3 (Activated Sludge Model3) was performed to offer basic data for the optimization of aerated biofilter (ABF) process design and operation. This study was focused on the simulation of the nitrification reaction in ABF which was a part of the advanced nutrient treatment process using bio-adsorption. The ABF process has been developed for the removal of suspended solids and nitrification reaction in sewage. A GPS-X (General Purpose Simualtor-X) was used for the sensitivity analysis and operation assessment. Sensitivity of ASM3 parameters on ABF was analysed and 4 major parameters ($Y_A$, $k_{sto}$, ${\mu}_A$, $K_{A,HN}$) were determined by dynamic simulation using 70 days data from pilot plant operation. The optimized values were 0.14 for $Y_A$, 3.5/d for $k_{sto}$, 2.7/d for ${\mu}_A$ and 1.1 mg/L for $K_{A,HN}$, respectively. Simulation with optimized parameter values were conducted and TN, $NH_4{^+}-N$ and $NO_3{^-}-N$ concentrations were estimated and compared with measured data at the range of 10 min to 4 hrs of hydraulic retention time (HRT). The simulated results showed that optimized parameter values could represent the characteristics of ABF process. Especially, the ABF showed relatively high nitrification rate (60%) under very short HRT of 10 min. As a consequence, the ABF was thought to be successfully used in the site which having high variation of influent loading rate.

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The Simultaneous Nitrification and Organics Oxidation of Wastewater in Airlift Biofilm Reactors (공기리프트 생물막 반응기에서의 폐수 질화 및 유기물 동시산화)

  • 서일순;허충희
    • KSBB Journal
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    • v.16 no.6
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    • pp.573-578
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    • 2001
  • The effects of organic supplement (acetate) and dissolved oxygen concentration on the nitrification rate of wastewater were investigated in the 27.7 L pilot-scale airlift biofilm reactor with the granular activated carbon media of 0.613 mm diameter. The ammonium oxidation rate increased stepwise up to 5 kg N/㎥$.$d at the riser air velocity of 0.063 m/s, when the air velocity and the ammonium loading rate were raised alternately. The nitrite build-up was observed during the early stage of the biofilm formation, which disappeared after the reactor operation of 128 days. As increasing the organic loading rate, the organic oxidation rate increased up to 25.0 kg COD/㎥$.$d with the removal efficiency of 94% but the oxidation rates of ammonium and nitrite decreased. The oxidation rates of ammonium and nitrite increased with the dissolved oxygen concentrations. When the pure oxygen was sparged, the ammonium oxidation rate was almost five times higher than that with air at the same velocity.

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Method of Reducing Separation Membrane Fouling Using Microbubbles (마이크로버블을 이용한 분리막 파울링 저감방법)

  • Kyung-Hwan Ku;Younghee Kim
    • Clean Technology
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    • v.29 no.1
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    • pp.31-38
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    • 2023
  • Due to water shortages caused by water pollution and climate change, total organic carbon (TOC) standards have been implemented for wastewater discharged from public sewage treatment facilities. Furthermore, there is a growing interest and body of research pertaining to the reuse of sewage treatment water as a secure alternative water resource. The membrane bio-reactor (MBR) method is commonly used for advanced wastewater treatment because it can remove organic and inorganic ions and it does not require or emit any chemicals. However, the MBR process uses a separation membrane (MF), which requires frequent film cleaning due to fouling caused by a high concentration of mixed liquor suspended solid (MLSS). In this study, process improvement and microbubble cleaning efficiency were evaluated to improve the differential pressure, water flow, and MF fouling, which are the biggest disadvantages of operating the MF. The existing MBR method was improved by installing a precipitation tank between the air tank and the MBR tank in which raw water was introduced. Microbubbles were injected into a separation membrane tank into which the supernatant water from the precipitation tank was introduced. The microbubble generator was operated with a 15 day on, 15 day off cycle for 5 months to collect discharged water samples (4L) and measure TOC. As the supernatant water from the precipitation tank flowed into the separation membrane tank, about 95% of the supernatant water MLSS was removed so the MF fouling from biological contamination was prevented. Due to the application of microbubbles to supernatant water from the precipitation tank, the differential pressure of the separation membrane tank decreased by 1.6 to 2.3 times and the water flow increased by 1.4 times. Applying microbubbles increased the TOC removal rate by more than 58%. This study showed that separately operating the air tank and the separation membrane tank can reduce fouling, and suggested that applying additional microbubbles could improve the differential pressure, water flow, and fouling to provide a more efficient advanced treatment method.

Treatment and Attachment Characteristics of Biofilm of Phanerochaete chrysosporium PSBL-1 in Wastewater (Phanerochaete chrysosporium PSBL-1 생물막을 이용한 오.폐수 처리 및 부착특성)

  • Lee, Soon-Young;Kang, Ki-Cheol;Won, Chan-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.3
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    • pp.271-277
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    • 2008
  • The biofilm of white-rot fungi fully exposed in atmosphere are that operation is easy, management cost and energy waste is low. To develop biofilm of white-rot fungi fully exposed in atmosphere, basic test are as follows. To select most effective microoganism species, investigated treatment characteristics of wastewater containing non-biodegradable material for three species of white-rot fungi(Phanerochaete chrysosporium PSBL-1, Phanerochaete chrysosporium KCTC 6147, Trametes sp. KFCC 10941) and activated sludge. And then investigated attached and detached biomass of selected white-rot fungi species on HBC ring surface. Among the three strains tested, P. chrysosporium PSBL-1 and P. chrysosporium KCTC 6147 showed higher efficiency for organics removal than Trametes sp. KFCC 10941, and P. chrysosporium PSBL-1 showed higher efficiency for nitrogen removal than P. chrysosporium KCTC 6147 and Trametes sp. KFCC 10941. Respectively, 51$\sim$59.8%, 57.5$\sim$60.3% of NBDCOD was removed for P. chrysosporium PSBL-1 and P. chrysosporium 6147 in pH 3.5$\sim$5.5. TN removal efficiency showed 39.3$\sim$85.3%, 3.4$\sim$7.6% for P. chrysosporium PSBL-1 and P. chrysosporium 6147 in pH 4.5$\sim$11.5 respectively. Considered that white-rot fungi remove organism and nitrogen simultaneously, the microorganism selected white-rot fungi P. chrysosporium PSBL-1. White-rot fungi P. chrysosporium PSBL-1 attached on HBC ring surface 4,538 mg/L, 4,546 mg/L, 4,531 mg/L after 5 minutes, 4,575 mg/L, 4,573 mg/L, 4,568 mg/L after 10 minutes from initial MLSS 4,600 mg/L in pH 4, 7 and 10 respectively. Also detached biomass is negligible from right after attachment to 10 day in pH 4, 7 and 10.