• Title/Summary/Keyword: 확장계수

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Theoretical Study on Antitumor Activity of trans-Platinum(Ⅱ) Complexes with Planar Ligands (Ⅱ) (평면형리간드가 배위된 trans-백금(Ⅱ) 착물의 항암활성에 관한 이론적 연구 (제2보))

  • Song, Young Dae;Kim, Jung Sung;Park, Byung Kak
    • Journal of the Korean Chemical Society
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    • v.41 no.6
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    • pp.277-283
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    • 1997
  • Platinum(II) complexes(where, $[Pt(L)_2X_2]$; L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl,5-phenylisoxazole(3-Me,5-Phisox), and 4-amino-3,5-dimethylisoxazole(4-ADI); X=Cl, Br) with planar ligands are investigated on antitumor activity by MM2 and EHMO calculations. It was found that, the net atomic charges of the halogen atoms in all of cis-, trans-isomers are greater than that of the nitrogen with planar form, indicating that ionic character of Pt-X bond is greater than that of Pt-N. Also, the ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of the interaction between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of X found to be higher than that of between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of N about all the complexes. It is found that bond strength of between Pt and X atom is weaker than that of between Pt and N atom. The ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of trans- complexes found to be higher than that of cis- complexes, as a result of bond strength of Pt-X in cis- and trans-complexes, for all the complexes. The degree of dissociation of X atom in Pt-X bond for trans-complexes are related to antitumor activity and the logIA value of inhibitory activity coefficient(IA).

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The Causal Relationship Test between Marine Business Cycle and Shipping Market Using Heterogeneous Mixed Panel Framework (해운경기변동과 선박시장에 대한 다차원 혼합 패널 인과성 분석)

  • Kim, Hyun-Sok;Chang, Myung-Hee
    • Journal of Korea Port Economic Association
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    • v.36 no.2
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    • pp.109-124
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    • 2020
  • Using panel data on freight rates and ship prices in the dry freighter market from January 2015 to December 2019, this study investigates the characteristics of shipping industry fluctuations. The analysis aims at two aspects of academic contribution. First, this study analyzes the relationship between shipping indicators and ship price based on separate dry-bulk ships, while the previous research considered the overall shipping index and weighted average ship prices. Second, the VAR model for the causality test is extended to a heterogeneous mixed panel model capable of limiting coefficients. There is a peak estimated by removing the cross-correlation problem, which is mainly raised in panel data analysis, using bootstrap estimation and solving the problem of information loss due to differences in non-stationary data. An empirical investigation of the causal relationship between economic fluctuations and ship price shows that the effect on the ship price from the freight is significant at the 1% level. This implies that there is a one-way relationship with demand in the shipping industry rather than a bilateral relationship.

Geological and Geophysical Characteristics of the New Hebrides Basin (뉴헤브리디스 해분의 지질.지구물리학적 특징에 관한 연구)

  • Park, Chung-Hwa
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.559-564
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    • 1997
  • The New Hebrides Basin is an inactive non back-arc basin located at the convergent boundary of the Pacific and Info-Australian plates. This basin was formed from 46 Ma to 60 Ma. The basin has two spreading episodes with rates of 34 mm/a for 42 to 47 Ma and 17 mm/a for 47 to 60 Ma. The sediments covered in the basin has uniform thickness of 0.65 sec. The age-depth correlation curve of the New Hebrides Basin can be represented by the following equation: $Depth(m)=2689+312\sqrt{Age}(Ma)$ The coefficient of 312 in this equation is close to that for major oceans, 350. This suggests that the cooling processes of the lithospheres in the New Hebrides Basin and major oceans are similar to each other. Free-air gravity anomalies of the basin varying from -22.3 mgal to +59.0 mgal. The mean value is +30.2 mgal higher than those of the normal oceans. Moderately large free-air gravity anomalies in the New Hebrides Basin are presumably owing to its location on a marginal swell along the New Hebrides Trench. It is generally observed that the ocean floor is very gently uplifted in a zone about 200 km oceanward of the trench axis. Positive free-air gravity anomalies amounting to $50{\sim}60$ mgal are usually observed on the crest of the swell. This topography is presumably by bending of the oceanic lithosphere so as to dynamically maintain nonisostatic states for some duration.

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Image Compression with using Wavelet Conversion Coefficients of Zerotree (웨이블렛 변환 계수의 제로트리를 이용한 영상압축)

  • Seo, Han-Seog;Park, Se-Won;Yim, Hwa-Young
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.11 no.3
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    • pp.55-62
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    • 2012
  • EZW, also known as Embedded Zerotree Wavelet, is a technique that allows transforming original images into wavelet, then again compressing images using the transformed data. This algorithm demonstrates a simple structure and remarkable effectiveness. This paper has reformed the EZW to improve a compression efficiency. Fundamentally, EZW evaluates the priority level of wavelet-transformed data and stores them into four different categories considering the priority level of the data as well as their location information. The four categories are represented as the symbols P, N, Z, and T. Here, P and N correspond to the volume of data and the priority level whereas Z and T show the location information of data. Each letter is stored through the process of dominant pass. However, here is when the data of Z and T are stored redundantly which lead to unnecessary increase of data volume. In this paper, we propose a modified version of Embedded Zerotree Wavelet algorithm, which is designed to efficiently reduce the volume of redundantly stored data using four additionally inserted symbols. We name it EEZW, Extended Embedded Zerotree Wavelet. The proposed algorithm demonstrates the efficiency verified by a number of image and confirms an outstanding result through the PSNR(Peak Signal To Noise Rate) values, which measure their quality of images.

Strut-and-Tie Model for Shear Strength of Reinforced Concrete Squat Shear Walls (저층형 철근콘크리트 전단벽의 전단강도 평가를 위한 스트럿-타이 모델)

  • Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.27 no.6
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    • pp.615-623
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    • 2015
  • The previous strut-and-tie models (STMs) to evaluate the shear strength of squat shear walls with aspect ratio less than 2.0 do not consider the axial load transfer of concrete strut and individual shear transfer contribution of horizontal and vertical shear reinforcing bars in the web. To overcome the limitation of the existing models, a simple STM was established based on the crack band theory of concrete fracture mechanics. The equivalent effective width of concrete strut having a stress relief strip was determined from the neutral axis depth and effective factor of concrete strength. The shear transfer mechanism of shear reinforcement at the extended crack band zone was calculated from an internally statically indeterminate truss system. The shear transfer capacity of concrete strut and shear reinforcement was then driven using the energy equilibrium in the stress relief strip and crack band zone. The shear strength predictions of squat shear walls evaluated from the current models are in better agreement with 150 test results than those determined from STMs proposed by Siao and Hwang et al. Furthermore, the proposed STM gives consistent agreement with the observed trend of the shear strength of shear walls against different parameters.

Time-series Mapping and Uncertainty Modeling of Environmental Variables: A Case Study of PM10 Concentration Mapping (시계열 환경변수 분포도 작성 및 불확실성 모델링: 미세먼지(PM10) 농도 분포도 작성 사례연구)

  • Park, No-Wook
    • Journal of the Korean earth science society
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    • v.32 no.3
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    • pp.249-264
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    • 2011
  • A multi-Gaussian kriging approach extended to space-time domain is presented for uncertainty modeling as well as time-series mapping of environmental variables. Within a multi-Gaussian framework, normal score transformed environmental variables are first decomposed into deterministic trend and stochastic residual components. After local temporal trend models are constructed, the parameters of the models are estimated and interpolated in space. Space-time correlation structures of stationary residual components are quantified using a product-sum space-time variogram model. The ccdf is modeled at all grid locations using this space-time variogram model and space-time kriging. Finally, e-type estimates and conditional variances are computed from the ccdf models for spatial mapping and uncertainty analysis, respectively. The proposed approach is illustrated through a case of time-series Particulate Matter 10 ($PM_{10}$) concentration mapping in Incheon Metropolitan city using monthly $PM_{10}$ concentrations at 13 stations for 3 years. It is shown that the proposed approach would generate reliable time-series $PM_{10}$ concentration maps with less mean bias and better prediction capability, compared to conventional spatial-only ordinary kriging. It is also demonstrated that the conditional variances and the probability exceeding a certain thresholding value would be useful information sources for interpretation.

The Effects of GyeongIn Ara Waterway on the Regional Property Value (경인아라뱃길이 지역 부동산 가격에 미친 영향 분석)

  • Lee, Hee-Chan;Cha, Joo-Young;Park, Doo-Ho
    • Journal of Korea Water Resources Association
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    • v.46 no.3
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    • pp.277-285
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    • 2013
  • The purpose of this research is to evaluate the scenic value of the Gyungin Ara waterway in real estate prices. Apart from the multi-functionality such as transportation of passengers and freight, prevention of floods, and provision of leisure areas, the Ara waterway possesses a scenic function which offers people esthetic value through unique and beautiful scenery. This scenic function is an externality for apartment residents living nearby. The applied methodology for this research is the Hedonic Price Model (HPM) which creates a cause and effect model between real estate prices and attributes. Variables such as apartment sale prices, complex characteristics, location characteristics, timely characteristics have been deduced through data collected from a total of 4,207 households that have experienced actual transactions during the same period, all located within the scenic benefit boundaries of the waterway. Landscape variable has been derived from algorithm designed by a combination of digital map and Google Mapview. The scenic value of the waterway estimated through the application of HPM on these variables is 165,000 Won per area (pyeong). The regional asset enhancing effect caused by the landscape view of the waterway is estimated to be 89.1 billion won.

An Adaptive Decision-Feedback Equalizer Architecture using RB Complex-Number Filter and chip-set design (RB 복소수 필터를 이용한 적응 결정귀환 등화기 구조 및 칩셋 설계)

  • Kim, Ho Ha;An, Byeong Gyu;Sin, Gyeong Uk
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.12A
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    • pp.2015-2024
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    • 1999
  • Presented in this paper are a new complex-umber filter architecture, which is suitable for an efficient implementation of baseband signal processing of digital communication systems, and a chip-set design of adaptive decision-feedback equalizer (ADFE) employing the proposed structure. The basic concept behind the approach proposed in this paper is to apply redundant binary (RB) arithmetic instead of conventional 2’s complement arithmetic in order to achieve an efficient realization of complex-number multiplication and accumulation. With the proposed way, an N-tap complex-number filter can be realized using 2N RB multipliers and 2N-2 RB adders, and each filter tap has its critical delay of $T_{m.RB}+T_{a.RB}$ (where $T_{m.RB}, T_{a.RB}$are delays of a RB multiplier and a RB adder, respectively), making the filter structure simple, as well as resulting in enhanced speed by means of reduced arithmetic operations. To demonstrate the proposed idea, a prototype ADFE chip-set, FFEM (Feed-Forward Equalizer Module) and DFEM (Decision-Feedback Equalizer Module) that can be cascaded to implement longer filter taps, has been designed. Each module is composed of two complex-number filter taps with their LMS coefficient update circuits, and contains about 26,000 gates. The chip-set was modeled and verified using COSSAP and VHDL, and synthesized using 0.8- μm SOG (Sea-Of-Gate) cell library.

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A Study on the Performance Improvement of Bar Code Reader for the Automatic Processing of the Mail Items (우편물 자동처리를 위한 바코드 판독기 성능개선에 관한 연구)

  • Park, Moon-Sung;Nam, Yun-Seok;Kim, Hey-Kyu
    • Annual Conference of KIPS
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    • 2001.04b
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    • pp.731-734
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    • 2001
  • 우편물을 집배원이 배달하는 순서로 자동구분 처리하기 위한 요소기술 줌에서 4-state 바코드 시스템이 개발되고 있으며 우편번호, 배달순서코드, 고객정보 등이 적용될 예정이다. 기존의 고객 바코드 판독 시스템은 우편물상의 바코드 심볼로지가 존재하는 판독대상 영역의 기울기가 ${\pm}4.47^{\circ}$ 이하이고, 심볼의 훼손과 잡영이 없을 경우에 $79{\sim}100msec(35,000{\sim}45,000$통/시간)의 속도로 자동 구분 정보가 판독된다. 본 논문에서는 판독범위 및 판독성능을 개선을 위하여 CCD(Charge Coupled Device) 센서로부터 획득된 이미지상에서 존재하는 심볼로지 정보의 고속판독 방법을 제시한 것이다. 이 판독방법은 그레이(gray) 이미지 바탕면의 경계값(threshold) 기울기 분포를 기준으로 2개의 경계값을 설정하여 판독대상 정보를 획득하였다. 또한, 4-state 바코드 심볼로지의 존재 가능성 영역만을 탐색하고, 판독대상 영역에서 트래커(tracker)를 탐색하여 심볼로지의 기울기값, 심볼로지 경계값, 심볼위치 좌표값을 생성한 후 심볼값이 판독한 것이다. 판독시험 결과는 판독대상 영역의 심볼로지가 ${\pm}45^{\circ}$ 기울어지고, 잡영이 존재할 경우에도 $30{\sim}60msec(58,000{\sim}l16,000$통/시간) 이내에 판독되었다. 우편물 자동구분용 바코드 판독기로써 적용될 경우에 판독속도가 평균 57.25% 이상 개선되고, 판독범위의 확장으로 0.2%의 기계적인 오류(이송과정예서의 Jam 발생 비율)를 제외할 경우에 거의 99.8% 우편물을 판독하여 자동구분 처리할 수 있게 될 것으로 기대된다.onebook 엑세스 모들(Server Phonebook Access Module)로 구성되어 있다.외 보다 높았다(I/O ratio 2.5). BTEX의 상대적 함량도 실내가 실외보다 높아 실내에도 발생원이 있음을 암시하고 있다. 자료 분석결과 유치원 실내의 벤젠은 실외로부터 유입되고 있었고, 톨루엔, 에틸벤젠, 크실렌은 실외뿐 아니라 실내에서도 발생하고 있었다. 정량한 8개 화합물 각각과 총 휘발성 유기화합물의 스피어만 상관계수는 벤젠을 제외하고는 모두 유의하였다. 이중 톨루엔과 크실렌은 총 휘발성 유기화합물과 좋은 상관성 (톨루엔 0.76, 크실렌, 0.87)을 나타내었다. 이 연구는 톨루엔과 크실렌이 총 휘발성 유기화합물의 좋은 지표를 사용될 있고, 톨루엔, 에틸벤젠, 크실렌 등 많은 휘발성 유기화합물의 발생원은 실외뿐 아니라 실내에도 있음을 나타내고 있다.>10)의 $[^{18}F]F_2$를 얻었다. 결론: $^{18}O(p,n)^{18}F$ 핵반응을 이용하여 친전자성 방사성동위원소 $[^{18}F]F_2$를 생산하였다. 표적 챔버는 알루미늄으로 제작하였으며 본 연구에서 연구된 $[^{18}F]F_2$가스는 친핵성 치환반응으로 방사성동위원소를 도입하기 어려운 다양한 방사성의 약품개발에 유용하게 이용될 수 있을 것이다.었으나 움직임 보정 후 영상을 이용하여 비교한 경우, 결합능 변화가 선조체 영역에서 국한되어 나타나며 그 유의성이 움직임 보정 전에 비하여 낮음을 알 수 있었다. 결론: 뇌활성화 과제 수행시에 동반되는 피험자의 머리 움직임에 의하여 도파민 유리가 과대평가되었으며 이는 이 연구에서 제안한 영상정합을 이용한 움직임 보정기법에 의해서 개선되었다. 답이 없는 문제, 문제 만

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A Study on GA-based Optimized Polynomial Neural Networks and Its Application to Nonlinear Process (유전자 알고리즘 기반 최적 다항식 뉴럴네트워크 연구 및 비선형 공정으로의 응용)

  • Kim Wan-Su;Lee In-Tae;Oh Sung-Kwun;Kim Hyun-Ki
    • Journal of the Korean Institute of Intelligent Systems
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    • v.15 no.7
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    • pp.846-851
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    • 2005
  • In this paper, we propose Genetic Algorithms(GAs)-based Optimized Polynomial Neural Networks(PNN). The proposed algorithm is based on Group Method of Data Handling(GMDH) method and its structure is similar to feedforward Neural Networks. But the structure of PNN is not fixed like in conventional neural networks and can be generated in a dynamic manner. As each node of PNN structure, we use several types of high-order polynomial such as linear, quadratic and modified quadratic, and it is connected as various kinds of multi-variable inputs. The conventional PNN depends on the experience of a designer that select the number of input variables, input variable and polynomial type. Therefore it is very difficult to organize optimized network. The proposed algorithm leads to identify and select the number of input variables, input variable and polynomial type by using Genetic Algorithms(GAs). The aggregate performance index with weighting factor is proposed as well. The study is illustrated with tile NOx omission process data of gas turbine power plant for application to nonlinear process. In the sequel the proposed model shows not only superb predictability but also high accuracy in comparison to the existing intelligent models.