• Journal of the korean Society of Automotive Engineers
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• v.6 no.2
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• pp.14-19
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• 1984

종래에 많이 사용된 각양의 계측 방법을 일일이 설명하는 것은 본 해설의 목적이 아니기 때문에 개략적으로 분류하여 설명하면 다음과 같다. 1) 시간 평균유속은 주로 프로브(probe)를 경유하여 동압과 정압의 측정에 의하여 수행되어 왔다. 연소반응이 있으면 밀도의 변화가 있게 되는데 밀도는 후술하는 농도의 계측과 온도의 계측에 의하여 정해져 동압과 정압으로부터 유속으로 변환된다. 시간분해능이 높은 비접촉식(직접 프 로브를 측정부에 삽입하지 않는 방법) 유속측정이 가능한 방법으로는 레이저 도플러 유속계 (Laser Doppler Velocimetry, 이하 LDV로 표현)를 들 수 있다. LDV는 압력측정에 의한 유속 산출법에서와 같은 온도 및 농도 등의 부수적인 계측이 필요없이, 직접 유속을 검출할 수 있으며 또한 검정이 필요없는 절대유속 측정이 가능하며 현재 연소반응이 있는 흐름에 대한 대부분의 연구에 적용되고 있는 실정이다. 2) 시간평균 화학종 농도측정에 가장 많이 쓰이는 방법은, 연소가스를 채취하여 가스 크로마토 그라프(Gas Chromatograph)로 분석하는 것을 들 수 있다. 한편, 시간 분해능이 높은 화학종 농 도의 계측은 레이저를 사용하여 각 화학종의 발광, 산란 및 흡수성을 이용, 측정한다. 3) 온도측정은 대부분 열전대를 사용하고 있다. 그러나 이 방법은 직접 프로브를 삽입해야 하므로 사용한계의 범위가 지극히 좁으며, 연소반응이 일어나므로 프로브 자체의 촉매반응 및 복사 열전달에 의한 보정 등이 사용상 큰 문제로 제기된다. 그러나 최근 레이저 이용기술의 발달로 (2)항에서의 농도 계측과 같이 반응기체의 온도 및 성분의 동시측정이 가능한 방법도 점차 현 실화 되어가고 있다. 그 대표적인 예로 CARS법(Coherent Anti-Stokes Raman Spectroscopy)을 들 수 있다. 이상으로부터 연소반응이 일어나는 흐름에서의 각종 계측에서는, 비접촉 측정의 가능성과 시간 공간 분해능의 특징으로 미루어 앞으로는 레이저를 이용한 계측 방법이 그 주류를 이룰 것으로 사료된다. 우선 본 해설은 기체의 온도 및 농도의 광학적 측정방법중 Raman산란광 검출법에 대하여 실제로 측정하는 입장에서 간단히 소개한다.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.560-568
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• 2007

The aim of this study is to investigate the terminology of chemically unclear ‘heavy metals' which were expressed in the Korean secondary science textbook in terms of the definition, the type and the meaning. Initial results showed that six of ‘Chemistry I' textbooks among these texts defined a heavy metal with the density and described it as a metal which is hazardous and continuously accumulated in the human body. Specifically, cadmium, lead and mercury were presented as examples of the hazardous metal in all of the eight textbooks but non-metals such as arsenic and absolutely essential metals including chrome, manganese, iron, cobalt, nickel and copper were also given in the texts. Most of the texts described the hazardousness and toxicity of the metal too simple to understand the mechanism of its intoxication despite considering all of the factors including its oxidation state, residual amount and reactivity with biomolecules of the human body. Such an ambiguous definition and explanation may excluded in the textbook because the chemically undefined chemical vocabulary leads students to cause an alternative conception of the heavy metal, which means that the metal could be identical with toxins.

• Applied Biological Chemistry
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• v.51 no.3
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• pp.233-237
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• 2008

The essential oil was obtained from the aerial part of Rhododendon mucronulatum Turcz. var. ciliatum Nakai by steam distillation, samples were collected by headspace (HS) and solid-phase microextraction (SPME) methods, and the compositions of the oil were analyzed by gas chromatography-mass spectrometry (GC-MS). Nineteen constituents were identified from the essential oil: 15 carbohydrates, 3 alcohols, and 1 acetates. Major constituents were 2-${\beta}$-pinene (16.1%), camphene (11.9%), ${\delta}$-3-carene (11.4%), d,l-limonene (9.5%), and ${\gamma}$-terpinene (9.5%). By SPME extraction, seventeen constituents were identified: 13 hydrocarbons, 1 alcohol, 1 nitrogen-containing compound, 1 acetate, and 1 amine. Major constituents of the SPME-extracted sample were cam phene (19.6%), 2-${\beta}$-pinene (18.0%), ${\delta}$-3-carene (17.4%), trimethyl hydrazine (9.7%), ${\gamma}$-terpinene (8.5%), and d,l-limonene (5.5%). By HS extraction, thirteen constituents were identified: 11 hydrocarbons, 1 alcohol, and 1 nitrogen-containing compound. Major constituents of the HS-extracted sample were camphene (25.8%), ${\delta}$-3-carene (24.8%), 2-${\beta}$-pinene (20.2%), d,l-limonene (5.4%), tricyclene (5.1%) and trimethyl hydrazine (4.6%). The fragrance of the essential oil was coniferous, balsamic, and woody, and the $IC_{50}$ value of the essential oil was 0.030 ${\mu}g/mg$ in MTT assay using UaCaT keratinocyte cell line.

• Journal of the Korean Chemical Society
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• v.28 no.6
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• pp.355-360
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• 1984

A new absorption spectrum observed from dilute aqueous solutions of methylene blue$(MB^+)$ and tetraphenylborate(TPB$^-$) ions was investigated by spectrophotometry. The species responsible for the spectrum can be a charge-transfer complex formed between the two, univalent, and poorly hydrated ions in order to minimize the disturbance to the water structure. However, as the absorption band of MB$^+$ is split into two bands with exciton splitting of about 2,000 cm$^{-1}$, the formation of double ion-pair, (MB-TPB)$_2$ appears to be more favorable than the charge transfer complex.

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.576-583
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• 2023

This study aimed to investigate the impact of enhancing the electrode conductivity and mitigating the production of hydrogen peroxide - a by-product arising from lactate oxidation - on the performance of lactate electrodes. The electrical conductivity of the electrode was improved by modifying the surface of carbon paper with single-walled carbon nanotubes. Catalase was introduced to effectively eliminate the hydrogen peroxide produced during the lactate oxidation reaction. The carbon paper electrode, with simultaneous immobilization of both lactate oxidase and catalase, yielded a current 1.7 times greater than the electrode where only lactate oxidase was immobilized. The electrode in which lactate oxidase and catalase were co-immobilized on the surface of carbon paper modified with single-walled carbon nanotubes, produced a current of 171 µA, which was more than twice as much current as the carbon paper with only lactate oxidase immobilized. The optimized electrode showed a linear response up to lactate concentration of 20 mM, confirming that it can be used as a sensor electrode.

• 비료회보
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• s.49
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• pp.25-31
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• 1977

• 월간산업보건
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• s.362
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• pp.76-76
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• 2018

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.2
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• pp.109-114
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• 2009

Absorption spectra for a quantitative analysis of actinide elements such as U(VI) and Pu(V) were measured by using a liquid waveguide capillary cell (LWCC) which has an optical path length of 1.0 meter. In order to investigate radioactive elements, a LWCC is installed in a glove box and is coupled to a spectrophotometer with optical fibers. Limits of detection (LOD) for the system were determined as 0.74 and 0.35 M with molar absorption coefficients of 8.14${\pm}$0.07 (414 nm) and 17.00${\pm}$0.16 (569 nm) $M^{-1}cm^{-1}$ for U(VI) and Pu(V) ions, respectively. The measured LOD values are about 30 times more sensitive when compared to those achievable by using a conventional quartz cell with an optical path length of 1.0 cm. As an application with an enhanced sensitivity, a quantitative analysis for micromolar concentrations of Pu(V) has been performed to decrease the uncertainty in the formation constant of the Pu(VI)-OH complex.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.438-449
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• 2020

This study is to improve the method of calculating the risk of liability that arise from release and dispersion of chemicals outside the plant in process industries such as chemical and petrochemical plants. To achieve this goal, the correlation factors with the risk of chemical release accident is derived by simulating release and dispersion of substances (14 types) designated by Ministry of Environment as preparation for accident, analyzing the cases of chemical release and effects of plant life damage. The method of calculating chemical liability risk was modified and supplemented based on the results obtained from the study. The correlation coefficient between the probit value of 14 chemical types and the liability risk by EURAM (European Union Risk Ranking Method) was -0.526, while the correlation coefficient with the modified chemical release accident risk was 0.319. Thus, the value from modified method shows that they appear to be correlated. According to modified calculating methodology, the correlation between ERPG-2 value and liability risk of 97 chemical types was -0.494 which is 19 times higher than existing liability risk correlation as absolute value. And the correlation coefficient of corrosion risk was 0.91. The standardized regression coefficients (β) value of correlation factors that affected the increase and decrease of risk were derived in order of Corrosion Index(0.713), ERPG-2 (0.400) and NFPA Health Index (0.0680) by values. It is expected that these findings this study result will also enable the calculation of reasonable chemical release liability risk for existing and new chemical, and will help use them as quantitative liability risk management indicators for chemical plant site.

• Analytical Science and Technology
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• v.13 no.1
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• pp.108-120
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• 2000

To perform an effective screening for toxic materials of forensic interest detected in high profile criminal case in biological and environmental samples, we tried to construct a searchable computerized database using HPTLC(High Performance Thin Layer Chromatography) and GC/MS. Retardation factor($R_f$) values and UV spectral data of HPTLC were investigated for 160 pesticides, 34 chemicals and 39 explosives of standard grade. The data were compiled in a library. We also analyzed 112 pesticides, 31 chemicals and 17 explosives and 57 volatile organic compounds(VOCs) by GC/MS. The data for RT and characteristic mass ions were also compiled in a library.