• Title/Summary/Keyword: 화학수축

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Tracheal Muscle Smoothing Effect of Nobiletin Isolated from Korean Chung-pi (한국산 청피에서 분리한 Nobiletin의 기관지 평활근 이완효과)

  • Back, Soon-Ok;Han, Jong-Hyun;Chun, Hyun-Ja;Han, Doo-Seuk;Han, Sung-Soo;Kim, Il-Kwang
    • Journal of the Korean Chemical Society
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    • v.46 no.3
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    • pp.205-212
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    • 2002
  • Bioactive compounds of Chung-pi methoxy flavonoids were isolated by column chromatography and preparative chromatography, and investigated on the smoothing effect for the tracheal smooth muscle of rats. The tracheal smooth muscles of rats were treated with acetylcholine ($ED_{50}:3${\times}$10^{-6}M$) and with chromatographic fractions. We found that six-methoxylated flavonoid (nobiletin) was the most active compound fro the smoothing effect of which the contracted tracheal smooth muscle was screened with further separated ethyl acetate fraction. This result shows how nobiletin and its analogues could be using as a promising drug of bronchial asthma.

Experimental Study on the Material Characteristics of Slag Cement with Various Phosphogypsum Materials (인산부산석고의 각 형태조건에 따른 슬래그 시멘트의 품질특성에 관한 실험적 연구)

  • Park, Jong-Tak;Oh, Hong-Seob
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.729-735
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    • 2009
  • In this study, it is experimentally verified a feasibility of the wasted phosphogypsum ($CaSO_4/H_2O$) that is a byproduct from the phosphoric acid process of manufacturing fertilizers can be applied as an admixture in slag cement. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, and then chemical characteristics and mechanical properties of various slag cements containing above mentioned gypsum materials were analyzed. The test results show that the gypsum made at high temperature has better quality with decrease of water-soluble phosphoric acid ($S-P_2O_5$) which has an effect on the quality of cement. And type II anhydrite shows superior quality in terms of drying shrinkage and the compressive strength of cement paste with hemihydrate at 56 days is higher than other gypsum material.

Crosslinking Density Control and Its Carbonization Characteristics of Spherical Phenolic Resin Particles by Using Cresol as Comonomer (구형 페놀수지 입자의 크레졸을 이용한 가교조절 및 탄화물성 변화)

  • Hahn, Dongseok;Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.618-623
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    • 2020
  • Spherical phenolic resin beads were synthesized by suspension polymerization at 98 ℃ from phenol, ortho-cresol, formaldehyde, with triethylamine as a basic catalyst, and spherical phenol-cresol copolymer resin beads with relatively low crosslinking density as well. Phenol reacts with formaldehyde at two ortho- and one para- positions to form a crosslinked structure, but ortho-cresol instead of phenol reduces the crosslinking density during copolymerization due to the methyl group at a ortho- position. As a result, spherical phenol-cresol copolymer beads showed more shrinkage with decreasing apparent density compared to the spherical phenol beads when carbonized at 700 ℃ under nitrogen. As the molecular weight of the cresol oligomer increases, the pore radius of the carbonized copolymer beads decreases, which is consistent with the density and shrinkage results. It was confirmed that the characteristics such as density decrease, shrinkage, yield and so on during carbonization can be controlled by controlling the degree of crosslinking of the spherical phenolic resin particles with cresol.

Low Temperature Sintering Mg-Zn Ferrites (Mg-Zn Ferrites의 저온소결화)

  • Kwon Oh-Heung
    • Resources Recycling
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    • v.12 no.6
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    • pp.8-12
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    • 2003
  • According to the recent trend to raise the horizontal scan frequency to increase the image refinement of the High Definition TV and High Resolution Display, material with low core loss is required for the ferrite core for deflection yoke, which is secured even in the high frequency range. liking notice of the influence on the fine structure of Mg-Zn ferrite by the chemical com position and process, low temperature sintering was proceeded. Cu was added to the low loss Mg-Zn system ferrite. After select-ing MgO, ZnO, $Fe_2$$O_3$, CuO, MgO was substituted for CuO while varying the composition ratio. Then the sample was sintered for 3 hours between $980~1350^{\circ}C$ Magnetic permeability, power consumption, shrinkage rate, core loss were measured. The start-ing temperature to test the shrinkage of the sample was nearby $900^{\circ}C$, it increased according to the substitution process of Cu, and the firing temperature was lowered about $-50~-75^{\circ}C$ alongside of the process.

In Situ Shrinkage and Stress Development for $\textrm{PbTiO}_3$, Films Prepared by Sol-gel Process (Sol-gel법으로 제조된 $\textrm{PbTiO}_3$ 박막의 온도에 따른 수축 및 응력거동)

  • Park, Sang-Myeon
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.735-739
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    • 1999
  • In this study we investigated stress development and shrinkage of thickness for a single $PbTiO_3$(PT) layer prepared by sol-gel processing. Changes of microhardness for multideposited PT layers with temperatures are also monitored to understand the densification of thin films. Single PT layer shrank rapidly from room temperature to$ 220^{\circ}C$ yielding 83% of total shrinkage observed up to $500^{\circ}C$. A tensile stress of ~75MPa developed in an as-spun layer, and increased steadily beyond $130^{\circ}C$ until it reaches the maximum value of 147MPa at $250^{\circ}C$. The significant decrease of tensile stress in the film beyond $370^{\circ}C$ indicates that thermal expansion mismatch between the film and the substrate dominates the stress behavior in this temperature range. Microhardness of the multideposited coatings also increased rapidly above $300^{\circ}C$ regardless of the pyrolysis temperatures used. Large amount of perovskite phase formed in multideposited coatings after $550^{\circ}C$ may be due partly to enhanced homogeneous nucleation in the thicker coating.

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Influence of the Nozzle Contraction Angles of Gaseous Extinguishing Systems on Discharge Noise (가스계 소화시스템 노즐 수축각이 방출소음에 미치는 영향)

  • Kim, Yo-Hwan;Yoo, Han-Sol;Hwang, In-Ju;Kim, Youn-Jea
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.77-82
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    • 2019
  • Fire extinguishing systems are essential equipment in all indoor facilities to address unexpected fire scenarios, and appropriate fire extinguishing agent should be used depending on the place and object to protect. Among these, gaseous fire-extinguishing systems are used to protect electronic equipment. Therefore, inert gases that do not undergo chemical reactions are used mainly in those systems. On the other hand, recently, owing to the high integration of electronic equipment, there are some cases, in which large noise generated from gaseous systems damage the electronic equipment. In this study, numerical analysis of the discharge noise with various nozzle contraction angles was carried out to improve the gas fire extinguishing system. Numerical analysis was carried out using ANSYS FLUENT ver 18.1. The causes of the noise were elucidated using the swirl distribution. The noise level of the modified model was reduced by approximately 6 dB compared to the reference model, which is similar to the result of a previous study, confirming the validity of the method.

Effect of Properties of Fly-ashes on the Characteristics of Fly-ash Mortars (플라이애시 종류에 따른 플라이애시 모르타르의 특성에 대한 연구)

  • Kim, Joo-Hyung;Park, Byoung-Sun;Jung, Sang-Hwa;Choi, Young-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.439-445
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    • 2016
  • Recently, a large number of researches about concrete containing high volume fly-ash(HVFA) have been carried to obtain carbon dioxide reduction, resource recycle and durable option in concrete industry. The quality of fly-ash such as chemical composition and fineness has high variability due to the differences of used fuels, operation condition in power plant. The aim of this study is to investigate the performances of fly-ash cement mortar containing different type of fly-ashes. The basic analysis of fly ash such as chemical composition, SEM image analysis were performed. Many mortar specimens were fabricated to evaluate the properties (compressive strength, drying shrinkage and carbonation) of mortar with various fly ash. From the test results, the quality of each fly ash must be considered and fully weighted in fly ash concrete.

Cracking and Durability Characteristics of High-early-strength Pavement Concrete for Large Areas using Calcium Nitrate (질산칼슘 혼화재를 사용한 대단면 급속 포장 콘크리트의 균열 및 내구특성)

  • Won, Jong Pil;Lee, Si Won;Lee, Sang Woo;Park, Hae Geun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.101-108
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    • 2009
  • The performance of high-early strength pavement concrete for large areas is influenced by the physical and chemical environment during service life. Generally, penetration, diffusion, and absorption of harmful materials that exist outside the concrete cause damage to its structure. Thus, we have to use a mixture for durability to keep the required quality for the planned service life. Moreover, in using high-early-strength cement and accelerators, a high heat of hydration to create the initial strength can cause cracks. Based on evaluations from optimal mix proportions of high-early-strength pavement concrete for large areas, we conducted water permeability, abrasion resistance, freeze-thaw, plastic, drying, and autogenous shrinkage tests. Test result showed that a mix of accelerator and PVA fibers showed excellent performance.

Polymerization Behavior of Polymeric Dental Restorative Composites Filled with Si-O Bridged Silica (Si-O Bridged 실리카가 충진된 치아수복용 고분자 복합체의 중합 특성)

  • Kim, Ohyoung;Lee, Jung Soo
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.672-676
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    • 2005
  • To improve the application of polymeric dental restorative composite (PDRC) for the posterior and anterior restoration, silica bridged with siloxane unit was firstly prepared by heat-treating a silica filler at various temperatures. Degree of conversion (DC), depth of cure, and dynamic volumetric polymerization shrinkage values of PDRC filled with silica bridged with siloxane unit were investigated to study the effect of heat-treated silica on the polymerization behavior of PDRC. From the experimental result, it was found that depth of cure was decreased with an increase of heat treatment temperature. on the other hand, both DC and polymerization shrinkage values were uniformly enhanced with increasing the heat treatment temperature. This phenomenon can be explained from the study that showed decrease of average particle size of silica resulted in the increase of relative amount of resin matrix in PDRC.

Effect of Foot Reflexology on the Vital Signs, Blood Cortisol, Lymphocytes and Natural Killer Cell of Female Cancer Patients (발반사마사지가 여성암환자의 활력징후, 코티졸, 면역반응에 미치는 효과)

  • Kim, Keum-Soon;Won, Jong-Soon;Jeong, Ihn-Sook;Choi, Wan-Hee;Kang, Ji-Yeon
    • Journal of Korean Biological Nursing Science
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    • v.6 no.1
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    • pp.5-15
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    • 2004
  • 목적 : 이 연구는 항암제를 투여받는 여성암환자에서 발반사마사지가 스트레스반응(활력징후, 코티졸)과 면역반응에 미치는 효과를 평가하기 위함이다. 방법 : 11명의 여성암 환자를 임의로 표출한 후 단일군 전후실험설계로 진행하였다. 종속변수는 스트레스 반응으로 활력징후(수축기 혈압, 이완기 혈압, 맥박수, 호흡수)와 혈중 코티졸, 면역반응으로 림프구 아군(CD3, CD4, CD8, CD19)과 자연살세포(NK cells)이며, 독립변수는 발반사마사지이었다. 중재 전후 종속변수의 변화를 보기 위해 Wilcoxon signed rank test를 실시하였다. 결과 : 중재 전에 비해 중재 후 수축기 혈압, 이완기 혈압, 맥박수, 혈중 코티졸치, CD4와 CD19는 유의한 변화를 보였으나 호흡수, CD3, CD8, 그리고 자연살세포는 유의한 변화를 보이지 않았다. 결론 : 이러한 연구결과는 발반사마사지가 항암화학요법을 받는 여성암 환자의 스트레스 호르몬과 면역관련세포에 영향을 보였지만 표본수가 작고 중재가 1회에 그쳤기 때문에 이러한 단점을 보완한 추후연구를 통해 발반사마사지의 효과를 좀더 잘 규명할 수 있을 것이다.

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