• Title/Summary/Keyword: 화학성분 분석

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지충이 추출물의 항산화 효과

  • 김순영;최선영;조현소;성낙주
    • Proceedings of the Korean Journal of Food and Nutrition Conference
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    • 2004.07a
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    • pp.43-43
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    • 2004
  • 해조류는 비타민과 무기질 함량이 풍부하고 저칼로리 다당류의 독특한 구조적인 특성으로 인해 생리활성이 강하여 최근 건강식품으로 각광 받고 있다. 그러나 생리활성과 이용에 체계적이고 학술적인 연구는 의외로 적다. 본 실험에서는 갈조류의 모자반과에 속하는 지충이를 용매별로 추출하여 화학성분을 분석하였고 또, 총페놀 함량, 전자공여작용, Superoxide dismutase(SOD) 유사활성 및 Thiobarbituric acid reaction substances(TBARS)등의 항산화 효과와 free radical 소거작용을 실험하였다. (중략)

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농업용 폐비닐 열분해 파생물질의 조성분석과 유해성 평가

  • 신혜순;강주연;김미경;정기화;심성훈
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.151-151
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    • 2003
  • 토양에 방치된 농업용 폐비닐은 거의 분해가 되지 않으며, 수분과 공기의 유통을 차단하고 토양 내 미생물들의 흐름을 막아 토양을 더욱 황폐화시키게 된다. 불법적인 소각 때는 산불의 위험에다 다이옥신, 염소 및 염화수소가스 등을 배출해 대기오염을 유발시킨다. 폐비닐을 열분해과정으로 처리하여 아주 작은 입자로 미분쇄하고 겔상태로 용융된 원료물질속으로 완전히 균일하게 혼합하여 골재로 활용하는 과정에서 가스상과 액상의 여러 가지 중간생성물질이 발생하게 되며, 농약의 살포에 의한 잔류농약 둥 인체에 유해가능한 요소들이 있을 수 있다. 본 연구에서는 개발공정이나 제품에서 인체에 영향을 미칠 수 있는 물질에 대하여 유해성을 평가하고 용응 겔 및 가스와 오일에 함유된 화학성분을 분석하였기에 보고하고자 한다 시험동물의 혈액생화학적 검사에서는 농업용 폐비닐물질 및 열분해 파생물질의 혈청 Cholesterol, 혈청 Alanine aminotranseferse와 Aspartate aminotransferse, Albumin 수치, LDH, Glucose, Uric acid, A/C 비 등의 생화학적 활성도를 측정한 결과들에서는 농업용 폐비닐물질을 투여한 시험군에서 나타난 결과와 비교하여 열분해 파생물질을 투여한 시험군에서 나타난 결과가 감소된 통계결과를 보였다. 이 결과들은 농업용 폐비닐물질을 투여한 시험군보다 열분해 파생물질을 투여한 시험군의 외부독성물질 투여에 의한 생체독성의 영향과 생체에 가해진 스트레스강도가 작았음을 의미하는 것이다. 잔류농약분석에서는 시료로부터 농약을 추출하는 용매추출과정, 시료추출물 중 공존하는 방해성분을 제거하는 정제과정, 폐비닐물질 및 열분해 파생물질 성분을 100mg/kg 이상군의 투여 후 시험동물의 부검시 모든 투여군에서 독성소견이 인정되지 않았다. 이와 같은 결과로 열분해 및 연소과정에서 발생하는 파생물질의 분석결과를 응용하여 대기오염을 방지하고 인체 유해물질을 차단하는 공해 방지 설계의 기초자료를 제안하고자 한다.

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Effect of Grinding Method and Grinding Rate on the Dry Beneficiation of Kaolin Mineral (분쇄방식 및 분쇄율이 고령토 광물의 건식 정제에 미치는 영향)

  • Kim, Sang-Bae;Choi, Young-Yoon;Cho, Sung-Baek;Kim, Wan-Tae
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.2
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    • pp.129-138
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    • 2008
  • The characteristics of beneficiating kaolin mineral by liberation (selective grinding) and air classification have been investigated, comparing the grinding rates of ball mill and impact mill. The ore was ground using a ball mill and a impact mill to evaluate the grindability of the two grinding methods based on the constant production amount of fine particles in size less than 325 mesh. Then, the fine product was further separated into two fractions using an air-classifier and each fraction was chemically analyzed to compare the beneficiation efficiency of the two grinding methods. The chemical grade of kaolin mineral decreased as increasing the grinding rate of both the mills. particularly in the case of ball mill because of overgrinding impurities such as quartz and feldspar. In the case of the ball milling, the fine fraction less than 325 mesh was air-classified at a cutting point of $43\;{\mu}m$. The production rate of the air-classified concentrate was found to be 66.2 wt%, removing 5.3% of $Fe_2O_3$ and 34.6% of CaO. Under the same conditions mentioned above with the impact mill, the production rate of the air-classified concentrate was 64.4 wt%, removing 34.2% of $Fe_2O_3$, 67.6% of CaO and 25.0% of $TiO_2$. Therefore, our results indicate that impact mill is superior to ball mill in terms of impurity removal.

Studies on the Nutritional Components and Physicochemical Characteristics of Various Flax(Linum usitatissimum) Seeds and Oils (아마인과 아마인유의 영양성분과 물리화학적 특성)

  • Nam, Jin-Sik
    • The Korean Journal of Food And Nutrition
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    • v.23 no.4
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    • pp.516-525
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    • 2010
  • Flaxseed has recently gained attention as a functional food. In this paper, physicochemical analyses of flaxseed and its oil were performed. Crude fat content ranged from 37~43%, moisture 0.2~6.8%, carbohydrate 30~35%, crude protein 18~23%, and crude ash 3~4%. Flaxseed is also an important source of dietary fiber. The TDF(total dietary fiber) contents of the flaxseed samples were 28~31%, and the SDF(souble dietary fiber) content of roasted flaxseeds was higher than that of raw flaxseeds. The major minerals found in flaxseed were calcium, potassium, magnesium, and phosphate. The flaxseeds were rich in ${\gamma}$-tocopherol with 234.3 mg/kg in raw brown flaxseed and 134.1 mg/kg in raw gold flaxseed, respectively. Roasted flaxseeds showed slightly lower vitamin and amino acid contents than those of the raw samples. The iodine, saponification, and acid values of brown flaxseed oil were 204.1 g/100 g, 193.6 mg/g, and 1.59 mg/g, and for gold flaxseed oil were 203.0 g/100 g, 189.9 mg/g, and 2.35 mg/g, respectively. ${\alpha}$-Linolenic acid(ALA, C18:3n-3) was highly concentrated in the flaxseed oil, which constituted about 55.5~56.1% of total fatty acids. Thus, flaxseed oil is a good source of omega-3 fatty acids and beneficial for the heart. Flaxseed contains high levels of dietary fiber including lignans, as well as minerals and vitamins, which may have antioxidant actions and help protect against certain cancers.

Theoretical Proposal for the Mix Design of Recycled Cement Utilizing Inorganic Construction Wastes (무기계 건설폐기물을 이용한 재생시멘트 배합설계에 관한 이론적 제안)

  • Kim, Ji-Hoon;Tae, Sung-Ho;Song, Hun;Shin, Hyeon-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.250-258
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    • 2016
  • Until now, the construction material industry has been recognized as a typical environmental destruction industry. However, recently, in order to reduce $CO_2$ emission, the main cause of environmental problems, lots of studies have been done about recycling industrial by-products and construction wastes. Therefore, the purpose of this study is to confirm whether it is possible to use as an alternative material in cement production process as a part of the development of recycled cement using an inorganic construction waste. For this study, the inorganic construction wastes was collected and analyzed each chemical component by XRF(X-ray Fluorescene). Also, the inorganic construction wastes were combined based on the chemical component of the cement, to perform this analysis. As a result, when the inorganic construction wastes was properly combined, it is possible to consider the development of the recycled cement used the inorganic construction wastes.

Identification of the impurities in the technical product of Atonic (Atonic 원제의 부성분 구조 확인)

  • Kyung, Kee-Sung;Chung, Chang-Kook;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.129-136
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    • 2004
  • In order to determine the amounts of impurities and to identify the chemical structures of the impurities in the technical product of the plant growth regulator Atonic, the extracts of diethyl ether and dichloromethane were analyzed with GC-FID and GC-MSD. resulting in detection of five impurities and identification of their chemical structures. The amount of the active ingredient atonic in the technical product was about 84% and those of the impurities ranged from 0.24 to 10.74%. The identified impurities in this technical product are 2-methoxyphenol (guaiacol, m/z 124), 2-chloro-6-methoxyphenol and/or 4-chloro-6-methoxyphenol (m/z 158), 1,2-dimethoxy-4-nitrobenzene (m/z 183), and 2,6-bis(1,1-dimethylethyl)-4-methylphenol (m/z 220), suggesting that they are not hazardous impurities.

Analysis of the Changes of composition of Hardened Cement at High Temperature by X-Ray Diffraction (X-선 회절 분석을 통한 고온 피해 시멘트 경화체의 성분 변화 분석)

  • Ji, Woo-Ram;Park, Ji-Woong;Shin, Ki-Don;Lee, Gun-Cheol;Heo, Young-Sun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.113-114
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    • 2017
  • In this study, the change of composition of cement hardened at high temperature through XRD was observed. The specimen was made of cement paste and the heating rate condition was applied at rapid thermal annealing (10.0℃ / min). The decrease of calcium hydroxide was not confirmed, but the calcium carbonate tended to be impossible or decreased after 800℃. Calcium silicate and larnite were observed to increase with increasing temperature. It is considered that silicic acid, which is a stable structure due to the decomposition of calcium silicate, is changed into a phase such as lime.

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Liquefaction Characteristics of Polyethylene-Polypropylene Mixture by Pyrolysis at Low Temperature (Polyethylene-Polypropylene 혼합물의 저온 열분해에 의한 액화특성)

  • Cho, Sung-Hyun;Choi, Hong-Jun;Na, Byung-Ki;Lee, Bong-Hee
    • Clean Technology
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    • v.15 no.2
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    • pp.109-115
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    • 2009
  • The low temperature pyrolysis of polyethylene (PE), polypropylene (PP) and polyethylene-polypropylene (PE-PP) mixture in a batch reactor at the atmospheric pressure and $450^{\circ}C$ was carried out to investigate the synergy effect of PE-PP mixture. The pyrolysis time was from 20 to 80 mins. The products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Korea Institute of Petroleum Quality. The analysis of the product oils by GC/MS showed that no new component was detected and no synergy effect was made by mixing of PE and PP. Conversions and yields of PE-PP mixtures were linearly dependent on the mixing ratio of samples.

The Effect of Developed SCB Liquid Fertilizer on the Growth of Kentucky Bluegrass (성분이 추가된 SCB저농도액비가 켄터키블루그래스의 생육에 미치는 효과)

  • Ham, Suon-Kyu;Kim, Young-Sun;Lim, Hye-Jung
    • Asian Journal of Turfgrass Science
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    • v.25 no.1
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    • pp.73-78
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    • 2011
  • This study was conducted to evaluate the effect of developed SCB (DSCB) liquid fertilizer produced by adding N, P and K at SCB liquid fertilizer on the growth of kentucky bluegrass. Two different N sources used in DSCB were ammonium sulfate (DSCB-A) and urea (DSCB-U), respectively. Fertilizer treatments were designed as follows; non-fertilizer (NF), control (CF; chemical fertilizer), DSCB-A1 ($200\;ml{\cdot}m^{-2}$DSCB-A), OSCB-A2 ($250\;ml{\cdot}m^{-2}$DSCB-A), OSCB-U ($250\;ml{\cdot}m^{-2}$DSCB-U) and CF+SCB (CF+$250\;ml{\cdot}m^{-2}$SCB). Every treatment was arranged in a randomized complete block design with three replications. In kentucky bluegrass, turf color index, chlorophyll index, dry weight and nutrient contents were measured. Results were as follows; It was hardly affected by DSCB and SCB application in investigation of chemical properties of soil. Turf color index and chlorophyll index in DSCB and SCB treatments were increased by 1~2% and 19~24% than NF, respectively and similar to CF. As applied with DSCB and SCB, dry weight of DSCB-U and CF+SCB was increased by 36% and 10% than CF, respectively, but similar to that of OSCB-A1 and DSCB-A2. Evaluated with turf quality and growth, DSCB-U was the best in all treatment and OSCB-A1 the most efficient. These results indicated that applications of OSCB and SCB promoted turf quality and growth of kentucky bluegrass or similar to CF, so that they were expected to replace chemical fertilizers.

Use of Multivariate Statistical Approaches for Decoding Chemical Evolution of Groundwater near Underground Storage Caverns (다변량통계기법을 이용한 지하저장시설 주변의 지하수질 변동에 관한 연구)

  • Lee, Jeonghoon
    • Journal of the Korean earth science society
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    • v.35 no.4
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    • pp.225-236
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    • 2014
  • Multivariate statistical analyses have been extensively applied to hydrochemical measurements to analyze and interpret the data. This study examines anthropogenic factors obtained from applications of correspondence analysis (CA) and principal component analysis (PCA) to a hydrogeochemical data set. The goal was to synthesize the hydrogeochemical information using these multivariate statistical techniques by incorporating hydrogeochemical speciation results calculated by the program, commonly used, WATEQ4F included in the NETPATH. The selected case study was LPG underground storage caverns, which is located in the southeastern Korea. The highly alkaline groundwaters at this study area are an analogue for the repository system. High pH, speciation of Al and possible precipitation of calcite characterize these groundwaters. Available groundwater quality monitoring data were used to confirm these statistical models. The present study focused on understanding the hydrogeochemical attributes and establishing the changes of phase when two anthropogenic effects (i.e., disinfection activity and cement pore water) in the study area have been introduced. Comparisons made between two statistical results presented and the findings of previous investigations highlight the descriptive capabilities of PCA using calculated saturation index and CA as exploratory tools in hydrogeochemical research.