• Title/Summary/Keyword: 화학성분 분석

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Influence of Reaction Temperature on the Pyrolytic Product of Rice Straw by Fast Pyrolysis using a Fluidized Bed (볏짚의 급속 열분해 생성물에 대한 반응온도의 영향)

  • Kang, Bo-Sung;Park, Young-Kwon;Kim, Joo-Sik
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.47-58
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    • 2005
  • Rice straw is one of the main renewable energy sources in Korea, and bio-oil is produced from rice straw with a lab. scale plant equipped mainly with a fluidized bed and a char removal system. We investigated how the reaction temperature affected the production of bio-oil and the efficiency of a char removal system. To elucidate how the temperature depended on the production of bio-oil, experiment were conducted between $450^{\circ}C\;and\;600^{\circ}C$ with a feed rate of about 300g/h. The mass balance was established in each experiment, and the produced gas and oil were analyzed with the aid of GCs and a GC-MS system. The char removal system is composed of a cyclone and a hot filter. In the experiments, we observed that the optimum reaction temperature range for the production of bio-oil is between $450^{\circ}C\;and\;500^{\circ}C$.

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담자균류의 약효 성분의 개발에 관한 연구

  • 김병각;권지연;복진우;최응칠
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1992.05a
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    • pp.24-24
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    • 1992
  • 담자균류인 말징버섯 Calvatia craniformis의 성분을 연구하기 위하여 그 균사체를 액내 배양하여 열수 추출한 후 ethanol로 침전시켜 단백 결합 다당체를 분리하였다. 이 성분을 DEAE-cellulose ion exchange, Sepharose CL-4B gel filtration 그리고 Concanavalin A Sepharose 4B affinity chromatography를 실시하여 총 6가지 분획(Fr. A~F)으로 정제하였다. 이들을 각각 10또는 20mg/kg/day의 용량으로 마우스의 복강에 투여하였을때, 육종 180 고형암에 디하여 41.7~74.1%의 종양억제율을 나타내었고 $\beta$-형 다당체인 Fr. F가 종양 억제율이 가장 높았다. 화학 분석에 의해, 이 성분은 4기의 단당 mannose, xylose, galactose, glucose로 구성된 87.2% polysaccharide와 1.9%의 Protein 및 1.3%의 hexosamine 함유하고 있고 이 성분의 분자량은 5.5 $\times$ $10^4$ dalton이었다. 이 성분을 calvatan이라 명명 하였다.

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Composition and Cytotoxicity of Essential Oil from Korean rhododendron (Rhododendon mucronulatum Turcz. var. ciliatum Nakai) (털진달래(Rhododendon mucronulatum Turcz. var. ciliatum Nakai) 정유의 성분분석과 독성평가)

  • Park, Yu-Hwa;Kim, Song-Mun
    • Applied Biological Chemistry
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    • v.51 no.3
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    • pp.233-237
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    • 2008
  • The essential oil was obtained from the aerial part of Rhododendon mucronulatum Turcz. var. ciliatum Nakai by steam distillation, samples were collected by headspace (HS) and solid-phase microextraction (SPME) methods, and the compositions of the oil were analyzed by gas chromatography-mass spectrometry (GC-MS). Nineteen constituents were identified from the essential oil: 15 carbohydrates, 3 alcohols, and 1 acetates. Major constituents were 2-${\beta}$-pinene (16.1%), camphene (11.9%), ${\delta}$-3-carene (11.4%), d,l-limonene (9.5%), and ${\gamma}$-terpinene (9.5%). By SPME extraction, seventeen constituents were identified: 13 hydrocarbons, 1 alcohol, 1 nitrogen-containing compound, 1 acetate, and 1 amine. Major constituents of the SPME-extracted sample were cam phene (19.6%), 2-${\beta}$-pinene (18.0%), ${\delta}$-3-carene (17.4%), trimethyl hydrazine (9.7%), ${\gamma}$-terpinene (8.5%), and d,l-limonene (5.5%). By HS extraction, thirteen constituents were identified: 11 hydrocarbons, 1 alcohol, and 1 nitrogen-containing compound. Major constituents of the HS-extracted sample were camphene (25.8%), ${\delta}$-3-carene (24.8%), 2-${\beta}$-pinene (20.2%), d,l-limonene (5.4%), tricyclene (5.1%) and trimethyl hydrazine (4.6%). The fragrance of the essential oil was coniferous, balsamic, and woody, and the $IC_{50}$ value of the essential oil was 0.030 ${\mu}g/mg$ in MTT assay using UaCaT keratinocyte cell line.

Seasonal Changes in Chemical Components of the Leaves of Dendropanax morbifera Lev. (채취시기(採取時期)에 따른 황칠(黃漆)나무 잎의 화학성분(化學性分) 변화(變化))

  • Kim, Hyung-Ryang;Chung, Hee-Jong
    • Journal of Korean Society of Forest Science
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    • v.88 no.4
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    • pp.562-567
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    • 1999
  • Dendropanax morbifera Lev. leaves were collected during different seasons to analyze the chemical components. In proximate composition the leaves collected in spring had the highest moisture content and in winter had the lowest. Lipid, ash and fiber contents gradually increased from spring to winter and in winter had the highest. Protein content decreased until summer and then it increased. All of free sugars detected have gradually increased during the growing season. Unsaturated fatty acids content was higher than that of the saturated fatty acids and the major saturated and unsaturated fatty acids were arachidic acid and cis-13,16-docosadienoic acid. respectively. Fifteen free amino acids detected with arginine content being the highest regardless of season and amino acid content gradually decreased during the seasons. The highest content of mineral elements was potassium in leaves collected in spring, with calcium was the highest in leaves picked in other seasons. Vitamin C content was gradually decreased over the growing season and soluble tannin content increased notably.

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Chemical Components in Different Parts of Korean Sword Bean(Canavalia gladiata) (한국산 작두콩의 부위별 화학성분)

  • 조영수;배영일;심기환
    • Food Science and Preservation
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    • v.6 no.4
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    • pp.475-480
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    • 1999
  • The chemical components in different parts such as seed, cotyledon, hull, pod, leaf, stem and root of Korean sword bean(Canavalia gladiata) were determined in this study. The contents of total sugar and protein were relatively higher in cotyledon than other parts. The highest mineral component was K, Ca in root and leaf, respectively. In case of organic acids, relatively higher content of oxalic acid(2,556 mg%), citric acid(573 mg%) was found in leaf and pod, respectively. Among free sugars, the contents of sucrose(3.80%), fructose(2.17%) were the highest contents in hull and stem, respectively. The highest component total amino acids in cotyledon and leaf, pod, stem, and root was glutamic acid(592 mg%), glutamic acid(429 mg%), proline(497 mg%), lysine(328 mg%) and arginine(714 mg%), respectively. Among fatty acids in hull and pod, palmitic acid(32.75%, 21.93%) was high in saturated fatty acid fraction, while linoleic acid(39.15%, 43.03%) was high in polyunsaturated fatty acid fraction.

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Studies on the Activated Sludge of Food Industries for Animal Feed -Part 1. Chemical composition of Brewery's Activated Sludge- (식품공장 폐수 활성오니(活性汚泥)의 사료화에 관한 연구 -제1보 : 맥주공장 오니(汚泥)의 화학조성에 관하여-)

  • Ki, Woo-Kyung;Park, Taek-Kyu
    • Korean Journal of Food Science and Technology
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    • v.9 no.4
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    • pp.291-294
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    • 1977
  • Some chemical analysis of brewery's activated sludge were carried out in order to utilize it for animal feed. And results obtained were as follows. 1. Brewery's sludge, sun-dried for 3 days, contained 15.4% of water, 40.47 of crude protein, 4.02% of crude fiber, 13.3% crude ash and 19.4% nitrogen-free extract. 2. Total amino acid content of the brewery's sludge was 38% of its dry basis. The amounts, of all essential amino acids contained except tryptophan was enough for chicken growing and, especially, among the essential amino acids, the contents of leucine, isoleucine, phenylalanine, tyrosine, glycine and serine were two or three times as much as its need. 3. Other minerals contents except Magnesium and Cupper, were considerably low for animal feed.

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The Study of Physico-chemcal Characteristics of Municipal Solid Waste (MSW) in Gangwon Area (강원지역 도시폐기물의 물리·화학적 특성 연구)

  • Lee, Keon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.2
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    • pp.101-111
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    • 2009
  • In this study, the physico-chemical characteristics of municipal solid waste (MWS) which was treated in gangwon area were investigated. It is necessary to measure the characteristics of municipal solid waste for build a waste treatment and RDF facility and for data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $101.8{\sim}199.8kg/m^3$. This MSW was composed of 30.7% of food wastes, 36.3% of papers, 15.8% of plastics & vinyls, 1.9% of textiles, 3.2% of wood and 1.5% of rubber & leathers respectively. Most of MSW are composed of food, paper and plastic waste and the combustible waste is more than 90%. For three components, moisture is 44.6%, combustible component is 47.7% and ash is 7.7% respectively. The chemical elements are carbon, oxygen, and hydrogen on the dry basis of wastes. The low heating value of the MSW measured by calorimeter was obtained as 2,631 kcal/kg, and the high heating value of the MSW was obtained as 3,310 kcal/kg.

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The study of the Composition and Physico-chemcal Characteristics of MSW in urban and gangwon area (수도권 및 강원지역 도시고형폐기물의 조성과 물리·화학적 특성연구)

  • Lee, Keon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.3
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    • pp.65-74
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    • 2008
  • In this study, the composition and physico-chemical characteristics of municipal solid waste (MWS) which was treated in four different area were investigated. It is necessary to measure the characteristics of MSW to build a waste treatment and Refuse Derived Fuel (RDF) facility, the data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $78.15-199.8kg/m^3$. This MSW was composed of 8.87% of food wastes, 38.8% of papers, 34.12% of plastics & vinyls, 7.16% of textiles, 0.96% of wood, 1.3% of rubber & leathers and others, respectively. Most of MSW are composed of food, paper and plastic waste and more than 94% was combustible waste. For three components, moisture is 17.38%, combustible component is 69.03% and ash is 6.24%. The chemical element has the high order of carbon, oxygen, hydrogen on the dry basis of wastes. And the low heating value of the MSW which is measured by calorimeter is calculated as 2973.8 kcal/kg and high heating value of the MSW is calculated as 5209.94 kcal/kg.

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Rapid Quality Evaluation of Dried Red Pepper by Near-infrared Spectroscopy (근적외 분광분석법에 의한 건조고추의 품질측정)

  • Cho, Rae-Kwang;Hong, Jin-Hwan;Kim, Hyun-Koo;Park, Moo-Hyun
    • Korean Journal of Food Science and Technology
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    • v.22 no.6
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    • pp.675-680
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    • 1990
  • A near-infrared reflectance spectroscopic(NIRS) method which has been recently developed for a non-destructive method for measuring ingredients in foods and agricultural products especially was evaluated for the determination of capsanthin, total sugar, capsaicin and moisture contents in Korean domestic red peppers. A multiple linear regression analysis with the data obtained by standard-laboratory methods(capsaicin by GC, capsanthin by Colorimetry, total sugar by HPLC and moisture by Vacuum drying method) and NIRS method was carried out to make a calibration. The accuracy of the NIRS method was found to be adequate when the standard-laboratory values for a set of sample that were not included in the calibration, were compared. It is concluded that the NIRS method is suitable for the determination of total sugar and capsanthin.

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Petrography and Mineral Chemistry of Some Deep Sea Basaltic Rocks from the Western Caroline Ridge and Yap Trench-Arc System (서부 캐롤라인 해령과 얍 해구-열도계의 해저 현무암질암에 대한 암석 기재 및 광물화학)

  • Park Jun-Beom;Kwon Sung-Tack;Ahn Jung-Ho;Kang Jung-Keuk
    • The Journal of the Petrological Society of Korea
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    • v.1 no.1
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    • pp.71-84
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    • 1992
  • This paper reports the results about the petrography and mineral chemistry of 13 representative dredged basaltic rocks from the western Caroline Ridge (WCR) and Yap Trench-Arc system, and provides the chemical and tectonic informations based on the compositions of clinopyroxene phenocrysts. Compositions of olivine phenocrysts in some analyzed samples are Fo$_{86-80}$. Plagioclase phenocrysts have variable compositions ranging from An$_{90}$ to An$_{55}$. The compositions of clinopyroxene phenocrysts vary according to geological environments; titansalite in atoll and guyot of WCR, diopside-augite in trough and bank of WCR, and endiopside in Yap Trench-Arc system. Application of the discrimination schemes proposed by Leterrier et al. (1982) suggests: (1) the samples from atoll-guyot belong to within plate alkali basalt, implying that western CR could be the continuation of eastern CR formed by hot spot magmatism, (2) the samples from the Yap Trench-Arc system with no present-day magmatism clearly indicate the occurrence of orogenic tholeiites presumably related to early island arc magmatisms in this area, however, (3) the samples from the bank and trough do not provide definitive informations, which might indicate the complexity of their origins.

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