• Title/Summary/Keyword: 화학농약

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집중조명 - 저항성 잡초의 화학적 관리방안 - 최적 살포시스템 구축 저항성잡초 출현빈도 줄여야

  • Jeong, Chang-Guk
    • Life and Agrochemicals
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    • s.263
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    • pp.22-25
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    • 2010
  • 농약회사, 대학 및 연구소, 농업기관 농업인으로 HRAC조직을 구성하여, 저항성잡초의 발생원인 규명, 저항성잡초에 대한 대책방안 제시, 저항성잡초관리요령의 대농민 홍보 및 교육, 조기진단 시스템구축, 최적의 농약살포 방법 모색 및 시행 등으로 구성원간의 상호 연계하여 필요시에는 역할을 분담하여 효율적으로 운영할 필요가 있다.

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통계정보(2) - 2010세계 농약시장 어떠했나?(II) -선두 11개사 매출변동 극히 적어 실적 18%부터 -14.9%까지 다양

  • 한국작물보호협회
    • Life and Agrochemicals
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    • s.268
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    • pp.26-30
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    • 2011
  • 선두 11개사의 순위 변동은 극히 적었다. 신젠타는 2위 바이엘과의 매출 격차를 늘려 농약산업계를 선도하였다. 몬산토는 연속 두 자리 수 하락의 부진을 보였다. 스미토모화학이 뉴팜 지분의 20%를, 캠차이나가 막테심-아간 지분 60%매입한 인수합병이 주목할 만하다. 선도회사별 현황을 알아본다.

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Studies on Simultaneous Analysis of Organophosphorus Pesticide Residues in Crops by Gas-Liquid Chromatography (I) Extraction and Cleanup (기체-액체 크로마토그래피에 의한 농작물 중 유기인제 잔류 농약의 동시 분석에 관한 연구 (제 1 보). 용매추출 및 방해성분의 분리 제거)

  • Taek-Jae Kim;Yun-Woo Eo;Young Sang Kim
    • Journal of the Korean Chemical Society
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    • v.30 no.5
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    • pp.465-474
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    • 1986
  • The solvent extraction and cleanup processes for the simultaneous gas-liquid chromatographic determination of 11 kinds of organophosphorous pesticide residues in crops were investigated. The extracts dissolved with acetone were partitioned with petroleum ether after adding saturated NaCl solution. Evaporated the partitioning solvent, the residue was dissolved in methylene chloride and eluted through mixed adsorbent (1 : 2 : 4 of activated carbon, magnesia and diatomaceous earth) with methylene chloride as an eluent. The pesticides recovered were 82∼105% and the impurities were effectively removed.

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A Study on the Simultaneous Analysis of Regulated Pesticides Residues from Rice and Soy Bean (쌀과 콩 중 규제잔류 농약의 동시분석에 관한 연구)

  • Taek-Jae Kim;Yun-Woo Eo;Jae-Seong Rhee
    • Journal of the Korean Chemical Society
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    • v.35 no.5
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    • pp.560-568
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    • 1991
  • The simultaneous determination method which simply determined regulated pesticides was investigated. Sample was extracted with acetone-methanol and partitioned with methylene chloride after addition of saturated NaCl solution. Entract was purified by Bio-Beads S-X3 column using cyclohexane-methylene chloride (1 : 1) as eluate. The determination of pesticides was performed by BP-1 capillary column gas chromatography using ECD and NPD. The average recoveries of pesticides in rice and soy fbean were over 83% and 81%, respectively. It was possible to detect pesticides in rice up to 0.002 ppm by $\alpha-BHC$ and up to 0.05 ppm by carbaryl and in soy bean up to 0.01 ppm by ${\alpha}$-BHC and up to 0.3 ppm by carbaryl.

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Studies on the Simultaneous Analysis of Organochlorine Pesticide Residues by Gas-Liquid Chromatography (II). Determination of Pesticides by GLC (기체-액체 크로마토그래피에 의한 잔류 유기염소제 농약들의 동시 분석에 관한 연구 (제2보). GLC에 의한 농약의 정량)

  • Taek-Jae Kim;Song-Ja Park;Young-Sang Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.5
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    • pp.503-509
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    • 1985
  • Sixteen organochlorine pesticides extracted out from the crops and cleaned by solvent-solvent partitioning and Florisil column chromatography were determined by gas-liquid chromatography. The majority of the pesticides were well separated by being eluted through 5% QF-1 column and some of them through 3% OV-17 column and 2.596 DC-200/2.5% QF-1 column, and the eluted pesticides were detected by $^{63}Ni$ electron capture detector. The linear calibration curves were obtained for the most of pesticides while some curves were slightly deviated from the linearity. In the determination of 16 pesticides added to thirteen kinds of crops, the recoveries were showed over 85% for the most cases and the relative standard deviations of 5 analyses were less than 12.1%. The results were within the criteria of the AOAC method.

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Environmental Direct Payments and Water Emissions (친환경직불제에 따른 농작 선택과 수질오염)

  • Kim, Ho-Seok
    • Journal of Environmental Policy
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    • v.6 no.1
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    • pp.61-81
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    • 2007
  • Types of agricultural policy can be catagorized into two general cases: price and income supports. Income supports are any government program designed to provide farmers with higher incomes than they would receive otherwise. These direct cash payments to farmers are known as "deficiency payment" or "direct payment" because they compensate the farmer for the failure of the market to provide farmers with adequate prices. The direct payment to environment-friendly agriculture is a form of income supports for the agriculture production using less pesticides and chemical fertilizers. Because no significant regulation exists on the use of fertilizers substituting chemical fertilizers for crop, the role of the payment on reducing environmental impacts of agriculture is not entirely clear. This uncertainty is likely to be particularly severe in the case that farmers with low-quality land showing greater demand for fertiliser have an incentive to transition to environment-friendly agriculture. The paper shows the case of the current payment system in Korea.

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A study on removal effect of Endosulfan in soil and aquatic system (수질 및 토양 중 Endosulfan 제거효과에 관한 연구)

  • An, Jung-Hyeok;Lee, Seog-Jong;Lee, Woan;Kim, Joon-Bum;Lee, Gwang-Chun;Kwon, Young-Du;Jeon, Choong;Park, Kwang-Ha
    • Analytical Science and Technology
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    • v.19 no.2
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    • pp.155-162
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    • 2006
  • In this study, a series of experiments were conducted using a standard solution containing ${\alpha}$ and ${\beta}$-endosulfan to follow the removal effect of residual pesticides on soil and aqueous solution. An analytical method for residual pesticides was established by a gas chromatography equipped Ultra II[$(30m{\times}0.25mm(ID){\times}0.25{\mu}m$] capillary column and a ${\mu}$-electron capture detector(${\mu}$-ECD). Recovery rates of residual pesticides for soil samples were 96-100%. The amount of ${\alpha}$ and ${\beta}$-endosulfan that was spread in the soil was checked for various period of time. It indicated that the amount was reduced to 73 and 61%, respectively. When the water spread amount increased from 10 to 100 mL, ${\alpha}$-endosulfan was eliminated from 45 to 85% and while ${\beta}$-endosulfan from 44 to 88%. Removal rates of ${\alpha}$-endosulfan and ${\beta}$-endosulfan were 99% and 98% respectively within 30 minutes. It was assumed that the organic salts and strong alkali elements contained in the pesticide degradator hydrolyzed the residual pesticide.

Estimate of pesticide residues in tomato varieties using ratio of surface area to weight (비표면적을 이용한 토마토의 과종별 농약 잔류량 예측)

  • Kwon, Hye-Young;Kim, Jin-Bae;Lee, Hee-Dong;Ihm, Yang-Bin;Kyung, Kee-Sung;Park, In-Hee;Choi, Jung
    • The Korean Journal of Pesticide Science
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    • v.8 no.1
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    • pp.30-37
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    • 2004
  • This study estimated the correlation between surface area/weight ratios and pesticide residues in two varieties of tomato, mini tomato and tomato. The ratios of surface area/weight of mini tomato and tomato were $2.15cm^2g^{-1}$ and $1.00cm^2g^{-1}$ respectively. Pesticide residues were measured with four kinds of pesticide, chlorothalonil WP, chlorothalonil SC, oxadixyl WP, thiophanate-methyl WP. Ie residue amount of mini tomato was $1.4\sim2.4$ times higher than those in tomato regardless of the application date and frequency. The ratios of surface area/weight on tomato varieties played a key role for determining pesticide residue.

Correlation between physicochemical properties and biological half-life of triazole fungicides in perilla leaf (들깻잎에서 Triazole계 살균제의 생물학적 반감기와 물리화학적 특성과의 상관관계)

  • Lee, Sang-Hyeob;Kwak, Se-Yeon;Hwang, Jeong-In;Kim, Hyo-Jung;Kim, Tae-Hwa;Kim, Jang-Eok
    • Journal of Applied Biological Chemistry
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    • v.62 no.4
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    • pp.407-415
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    • 2019
  • The biological half-life of pesticides applied on crops is the key indicator for ensuring the safety of agricultural products. The biological half-life is affected by the several factors like growing conditions of the crop, climate, application method, and physicochemical properties of pesticides. In this study, the biological half-life was calculated and the degradation rates of six triazole fungicides sprayed on perilla leaves were evaluated. Moreover, the statistical analysis confirmed the correlation between the biological half-life and physicochemical properties of six triazole pesticides. The recoveries of the six pesticides were between 84.8-104.9%, which satisfied the residual pesticide analysis criteria. The biological half-life of six pesticides sprayed on perilla leaves, calculated using the first-order kinetics model, ranged between 6.4-15.1 days. When the biological half-life and the physicochemical properties were correlated using the principal component analysis: pKa and Log P, the biological half-life was found to be affected by PC1. The correlation coefficient between biological half-life and physicochemical properties (pKa), calculated by Spearman rank-order correlation, was R2 = -0.928 (p <0.01). Biological half-life has been shown to correlate with pKa. In conclusion, it can be used as a database for the relationship between biological half-life and physicochemical properties and will contribute to ensure safe supply of agricultural products.

Necessity and Introduction Plan for Agrochemical Pharmacist System to Strengthen Expertise in Pest Diagnosis and Prescription (병해충 진단 및 처방의 전문성 강화를 위한 식물의약사(식물위생전문가) 제도의 필요성과 도입방안)

  • Jae Su Kim;Deok Ho Kwon;Se Jin Lee;Sueyeon Lee
    • Korean journal of applied entomology
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    • v.62 no.2
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    • pp.69-78
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    • 2023
  • The currently implemented Positive List System, sales manager training, and pesticide sales record systems focus on the safety of determined pesticide use, but the proposed agrochemical pharmacist (AP) system aims accurate diagnosis and reasonable prescription. In this study, 81% of famers claimed expert assistance for purchasing and applying pesticides, and 42~86% of sales managers insisted on the strengthening expertise in diagnosis and prescription. In the institutionalization of AP, a special implementation guideline is essential to embrace the present sales managers with long experience. Sales managers of commercial and agricultural cooperatives recognize the qualifications of agrochemical pharmacists as a strategy to differentiate themselves from competitors, and increase sales through market positioning of "pesticides prescribed by trustworthy agrochemical pharmacists", not sales managers anymore.