• Title/Summary/Keyword: 화학강화유리

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화학공정의 실시간 최적화

  • 김정환;한종훈
    • ICROS
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    • v.10 no.3
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    • pp.17-20
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    • 2004
  • 정유 및 석유화학, 철강산업계는 제품수요의 변화, 에너지 및 원료단가 상승, 운전비용 상승 및 환경 규제 강화 등 다양한 주위 상황 변화로 인하여 기존 프로세스의 최적운전을 통한 비용절감이나 친환경적 운전이 매우 중요한 이슈가 되고 있다. 공정 개선을 통해서 이러한 문제를 해결하기 위한 방안으로는 새로운 설비를 도입하거나 기존 설비를 고치거나 기존의 공정 설비 및 장치를 최대한 이용할 수 있도록 조업 조건을 설정해 주는 방법 등이 있다. 그 중 비용 측면에서 유리하며 짧은 시간 내에 공정의 생산성을 향상시킬 수 있는 방법은 환경변화에 맞춰 공정이 유연하게 대처하도록 최적의 조업을 유지하는 것이다.(중략)

Characterization of $SnO_2-P_2O_5$-RO with compositions changes of RO on Glass ($SnO_2-P_2O_5$-RO계 유리에서 RO 변화에 따른 특성)

  • Ko, Young-Soo;Choi, Byung-Hyun;Jee, Mi-Jung;An, Yong-Tae;Lee, Jung-Min;Cho, Yong-Soo;Bae, Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.276-276
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    • 2007
  • 기존에 전자부품들에 사용되어 온 봉착용, 결합용, 코팅용 유리들은 타유리와 비교하여 낮은 융점을 가지고 있으면서도 열처리 전후에 물리, 화학적으로 매우 안정한 특성을 가지고 있는 PbO를 50~85% 이상 함유한 유리들이 대부분을 차지해왔다. 그러나 PbO 성분은 산성비 등의 산에 용해되어 Pb이온이 생성되면서 환경오염의 원인이 되기 때문에 유해성분으로 규정하고 있다. 최근 유해물질의 규제가 강화됨에 따라 PbO를 대체할 수 있는 $B_2O_3,\;Bi_2O_3,\;V_2O_5,\;P_2O_5$ 등의 새로운 조성의 유리에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 봉착용으로 사용되는 인산계 유리에서 RO계 첨가에 따른 TMA와 고온현미경, 필테스트를 통하여 접합성 및 열적특성 등의 변화에 대하여 조사하였다.

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Preparation and Properties of Glass Fiber-Reinforced Poly(olefin ketone) Composites (유리섬유 강화 폴리올레핀케톤 복합재료의 제조 및 특성에 대한 연구)

  • Cho, Hae-Souk;Chung, Jae-Seung;Baek, Seung-Jo;Choi, Won Jae;Kim, Jin-joo;Yoon, Sung Kyun;Lee, Jong-Chan
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.339-343
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    • 2012
  • Poly(olefin ketone) terpolymer having excellent mechanical properties was synthesized and composite materials of poly(olefin ketone) containing polyurethane/amino silane functionalized glass fibers were prepared. The compatibilities between the functionalized glass fiber and the polymer were characterized by observing the fracture surfaces of the composites using scanning electron microscopy (SEM). Mechanical properties of composites with different contents, diameters, lengths, and binders of glass fibers were also studied using universal testing machine (UTM). The introduction of suitably functionalized glass fiber into the poly(olefin ketone) produces composite materials having excellent mechanical properties and they are very promising alternative materials for the engineering plastic applications.

A Study For The Simple Method In Dividing The Layers of Fiber-reinforced Plastic (폐 FRP선박의 재활용공정에서 용이한 면포추출공정을 위한 화학적 처리 방법에 관한 연구)

  • Lee, Seung-Hee;Kim, Yong-Seop;Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.1
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    • pp.43-46
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    • 2010
  • As one of the methods for recycling the FRP used for the small and medium-sized waste ships, separation of the roving layer from the mat has some merit in a sense of the recycling energy and the environmental effects. Similar characteristics between the roving and the mat make the mechanically automatic differentiation difficult. They, however, contain different ratio of the resin and the glass and the thickness. In this study photo physical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer and (2) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring the FRP sample with water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The implementation of HF treatment has been successfully tested in this study.

The Adhesion Promotion of Glass Fiber Reinforced Composite Using Methacrylate Functional Silanes (메타아크릴레이트 실란을 이용한 유리섬유 강화복합재료의 물성향상)

  • Jang, Jyong-Sik
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.133-139
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    • 1990
  • Methacrylate functional silanes with different methylene spacer groups have been synthesized and the orientation effect and absorption behavior of these silane coupling agent were investigated by Fourier transform infrared spectroscopy(FT-IR). The mechanical properties of glass bead/polyester composites are found to be dependent on the spacer group of treated silane coupling agent. The absorption rate of the silane coupling agent onto the fumed silica surface decreases with increasing the number of the methylene spacer in methacrylate functional silanes. Silane molecules containing long spacer groups are adsorbed onto silica slightly bowed with respect to the substrate surface. The relationship between silane molecular structure and mechanical properties of polymer composites is also investigated in order to improve hot/wet properties of glass fiber/polyester composites.

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DGEBA-MDA-SN-Hydroxyl Group System and Composites : 2. Fracture Energy of Fiber Reinforced Composites (DGEBA-MDA-SN-Hydroxyl Group System의 합성 및 복합재료 제조 : 2. 섬유강화 복합재료의 파괴에너지)

  • Lee, Jae-Young;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.737-742
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    • 1994
  • The fracture energy of glass fiber/carbon fiber/epoxy resin hybrid composite system was investigated in the aspect of fracture mechanism. Epoxy resin matrix was DGEBA-MDA-SN-HQ system. On the interface of glass fiber and matrix, post debone friction energy provided a major contribution to the fracture energy, and debonding energy and pull-out energy were of the similar value. In the case of fracture on the interface of carbon fiber and matrix, pull-out energy was the major contributor.

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A Study on the Growth of Carbon Nanotube by ICPHFCVD and their I-V Properties (ICPHFCVD법에 의한 탄소나노튜브의 생장 및 I-V 특성에 관한 연구)

  • 김광식;류호진;장건익;장호정
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.158-164
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    • 2002
  • 본 연구에서는 탄소나노튜브를 직류 바이어스가 인가된 유도결합형 플라즈마 열선 화학기상증착 장치를 이용하여 58$0^{\circ}C$ 이하의 저온에서 유리기판의 변형 없이 수직 배향 시켰다. 탄소나노튜브의 성장을 위해 강화유리기판 위에 전도층으로 Cr을 증착하였고, 그 위에 촉매 층으로 Ni을 순차적으로 RF magnetron cputtering 장치를 이용하여 증착 시켰다. 성장 시 탄소나노튜브의 저온에서의 좋은 특성을 위해 높은 온도에서의 열분해를 목적으로 텅스텐 필라멘트를 이용하였으며, 수직 배향 시키기 위해서 직류 바이어스를 이용하였다. 성장된 탄소나노튜브는 수직적으로 잘 배향 되었으며, 저온에서 좋은 특성을 보였다. 탄소나노튜브의 특성화에는 SEM, TEM을 관찰하였으며, Raman spectroscopy를 이용하여 흑연화도를 측정하였고, 전계방츨 특성은 전류 전압 특성곡선과 Fowler-Nordheim plots를 이용하였다.

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Mechanical Properties of Three-dimensional Glass Fabric-reinforced Vinyl Ester Matrix Composites (삼차원 유리직물 강화 비닐에스테르 복합재의 기계적 특성)

  • Park, Won-Bae;Park, Soo-Jin;Lee, Jae-Rock
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.715-718
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    • 1998
  • In this work, bisphenol type vinyl ester was impregnated into the three-dimensional glass fabrics fabricated from different thickness changes. Their mechanical properties of the specimens have been investigated by three-point bending and flatwise compression tests. Also, interlaminar shear strength (ILSS) has been determined through short-beam test for the evaluation of interfacial adhesion at interfaces between fibers and matrix of the composites. The effect of thickness changes in three-dimensional glass fabric-reinforced composites have been described in this work.

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Recycle of the Glass Fiber Obtained from the Roving Cloth of FRP I: Study for the Physical Properties of Fiber-reinforced Mortar (폐 FRP 선박의 로빙층에서 분리한 유리섬유의 재활용 I: 섬유강화 모르타르의 물성에 관한 연구)

  • Yoon, Koo-Young;Kim, Yong-Seop;Lee, Seung-Hee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.2
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    • pp.102-106
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    • 2007
  • While the effort has been made in recycling the FRP (Fiber Reinforced Plastic) used for the medium-to-small size ships, researchers try to find out the methods more favorable for the environments and more value-added. In respect to the fact that the FRP consists of two types of layers, roving and mat, differentiated by the 2-dimensional structure, our group was able to separate the layers of FRP instead of grinding it. The roving cloth was cut to the long glass fibers (about 50 mm long; calling it 'F-fiber' afterwards). F-fiber showed increasing tensile strength and chemical-resistance possibly due to the remained resin (about 25% by weight). In this experiment fiber-reinforced mortars are made of the F-fiber as a recycling method of FRP. The mortar containing 2% (v/v) F-fiber results in 34.6% increment of bending strength from the standard after 28 day curing. The resulting strength is similar to that of the mortar with imported polyvinyl fiber P-54. These results imply that F-fiber can be applied to the 'fiber reinforced mortar' and furthermore may be a substitute for the imported fibers.

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