• Title/Summary/Keyword: 화계

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Feasibility Evaluation of Glass-ceramic Sealant for SOFC (SOFC용 결정화계 밀봉재 특성평가 및 단전지 실증평가)

  • Lee, InSung;Kim, YeongWoo;Park, YoungMin;Bae, HongYoul;Ahn, JinSoo;Kim, InTae
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.88.1-88.1
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    • 2011
  • SOFC는 사용되는 셀의 디자인에 따라 튜브형, 평판형으로 구분되어진다. 평판형의 경우에는 전해질 지지형(ESC), Anode 지지형(ASC) 및 금속 지지형(MSC)로 크게 나눌 수 있다. SOFC 스택은 이와 같은 셀과 밀봉재, 집전체, 분리판의 구성요소를 여러 장으로 적층하여 이루어진다. SOFC 발전시스템은 SOFC 스택과 EBOP, MBOP로 구성되는데, SOFC 발전시스템의 상용화를 위해 선행되어야 할 것은 스택의 안정적 출력 및 신뢰성 확보이다. 즉, 셀, 밀봉재, 분리판 및 집전체로 대변되는 구성요소들이 스택에 장착되었을 때 그 기능을 최대한 발휘하면서도 점진적 또는 급격한 품질저하가 발생되지 말아야 한다. 특히, 밀봉재의 경우 SOFC에 사용되는 연료와 공기의 혼합(Cross-over)을 방지하는 중요한 기능을 담당하고 있으며 여러 장 적층된 분리판의 전기적 단락을 방지해야 한다. 또한 SOFC의 특성상 $700^{\circ}C$ 이상의 고온에서 다른 구성요소와 화학적 반응이 없어야하고 열싸이클(Thermal cycle)을 견딜 수 있도록 충분한 기계적 강도가 보장되어야 하는 등 요구되는 품질기준이 엄격하다. SOFC의 밀봉재는 접합형(Brazing), 압착형(Compressive), 용융-고정형(Glass-ceramic)이 대표적으로 적용되고 있다. 이 중에서 Brazing 물질과 방법은 현재 활발히 연구가 수행 중에 있지만 범용적으로 사용되고 있지는 않은 상태이고 Compressive 밀봉재와 Glass-ceramic 밀봉재가 대면적 SOFC 스택에 사용되어 적용 가능성을 평가받고 있다. 본 연구에서는 SOFC 구성요소의 국산화를 추진하는 지경부과제의 결과물 중 (주)써모텍에서 개발한 Glass-ceramic 밀봉재(RC1) 단품에 대한 특성평가와 실제 단전지 평가를 통해 SOFC 스택 적용 가능성을 평가하였다. 밀봉재 단품에 대한 특성평가는 용융특성, 상분석, 열팽창계수 등의 물리적, 화학적 평가 외에 가스 누설 정도를 평가하는 기밀도 평가와 SOFC의 작동 온도인 $700^{\circ}C$와 상온 분위기를 주기적으로 인가하는 Thermal cycle 특성을 평가하였다. 셀을 한 장 사용하는 단전지(Unit cell) 평가는 RIST에서 자체 제작한 $100{\times}100mm^2$ 평판형 ASC 셀을 사용하여 수행하였으며, 밀봉재는 Dispensing 공정을 통해 구성되었다.

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Effect of Surfactant Micelles on Lipid Oxidation in Oil-in-water Emulsion Containing Soybean Oil (Surfactant micelle이 수중유적형 유화계내의 대두유 산화에 미치는 영향)

  • Cho, Young-Je;Chun, Sung-Sook;Decker, Eric A.
    • Korean Journal of Food Science and Technology
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    • v.34 no.5
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    • pp.770-774
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    • 2002
  • Effect of surfactant micelles on lipid oxidation was determined in soybean oil-in-water (O/W) emulsions. The concentration of ferric irons to continuous phase in the O/W emulsions was measured as a function of various Brij type and concentrations. The concentration of ferric iron in the continuous phase increased with increasing surfactant micelles concentration $(0.5{\sim}2.0%)$ and storage time $(1{\sim}7\;days)$. At pH 3.0, the concentration of continuous phase iron was higher than at pH 7.0. Lipid oxidation rates, as determined by the formation of lipid hydroperoxides and headspace hexanal, in the O/W emulsions containing ferric iron decreased with increasing surfactant micelle concentration $(0.5{\sim}2.0%)$. These results indicate that surfactant micelles concentration could alter the physical location and prooxidant activity of iron in soybean O/W emulsions.

Strength and Deformation Characteristics of Lightweight Foamed Soil Using In-situ Soil (현장발생토를 활용한 경량기포흔합토(LWFS)의 강도 및 변형특성)

  • Yoon Gil-Lim;You Seung-Kyong
    • Journal of the Korean Geotechnical Society
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    • v.20 no.9
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    • pp.125-131
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    • 2004
  • A series of unconfined compression tests were carried out firstly to investigate mechanical behaviors of Lightweight Foamed Soil (LWFS) which is composed of dredged soils, cement and air foam. And secondly, to compare the difference of mechanical characteristic of LWFS with previous research conclusions (Yoon & Kim,2004) by using different dredged soils sampled at Joong-Ma in Gwangyang harbor area. Based on numberous laboratory experiments, it was found that deformation coefficient $(E_{50})$ of LWFS increases with increasing cement contents but decreases with increasing initial water contents of dredged soils. Appropriate regression formula (normalizing factor scheme) which considers relationship between LWFS composing elements, initial water contents of dredged soils, cement, air foam, and uniaxial compression strength or LWFS is proposed for practical applications. Finally, it was clear that, to apply LWFS method to practical projects, certain laboratory test would be necessary to take considerations of soil locality because mechanical charac-teristics of LWFS were surely dependent upon their sampled locations and properties.

Predictive System for Unconfined Compressive Strength of Lightweight Treated Soil(LTS) using Deep Learning (딥러닝을 이용한 경량혼합토의 일축압축강도 예측 시스템)

  • Park, Bohyun;Kim, Dookie;Park, Dae-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.18-25
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    • 2020
  • The unconfined compressive strength of lightweight treated soils strongly depends on mixing ratio. To characterize the relation between various LTS components and the unconfined compressive strength of LTS, extensive studies have been conducted, proposing normalized factor using regression models based on their experimental results. However, these results obtained from laboratory experiments do not expect consistent prediction accuracy due to complicated relation between materials and mix proportions. In this study, deep neural network model(Deep-LTS), which was based on experimental test results performed on various mixing conditions, was applied to predict the unconfined compressive strength. It was found that the unconfined compressive strength LTS at a given mixing ratio could be resonable estimated using proposed Deep-LTS.

The Effects of NCS Education and Education Transition on Practical Results (국가직무능력표준 교육과 교육전이가 실무성과에 미치는 영향)

  • Choi, Soo Ho
    • Journal of Convergence for Information Technology
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    • v.9 no.3
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    • pp.82-89
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    • 2019
  • The reason why NCS education is conducted in college is because students are expected to improve their skills through practical education. In addition, NCS education is expected to have a positive impact on job competence and competitiveness. The purpose of this study is to explain the necessity of NCS education, and to analyze whether the education transition and practical performance are manifested. For this purpose, the research model was composed of "NCS Education ${\Rightarrow}$ Educational Transition ${\Rightarrow}$ Practical Results" and surveyed about 300 college students in the metropolitan area. If NCS education is necessary in practice, colleges and other educational institutions should plan to make NCS education operate efficiently. As a analysis result, it was confirmed that the internal consistency was secured and both the intensive validity & discriminant validity were confirmed in the validity. As a result of using the structural equation model, this research model was found to be suitable. As a result of the hypothesis test, it is analyzed that the standardization coefficient of the research hypothesis is above the appropriate level and the correlation is highly formed.

The Effect of Selection Motivation of Security-related Department Students on NCS Curriculum and Career Decision (경호관련학과 학생들의 선택 동기가 NCS교육과정 및 진로결정에 미치는 영향 분석)

  • Choi, Jeong-Il;Jang, Ye-Jin
    • Convergence Security Journal
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    • v.18 no.2
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    • pp.159-166
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    • 2018
  • The purpose of this study is to investigate the effect of selection motivation on the NCS curriculum and career decision of the students in security related department. The contents of the questionnaire consisted of "First, Motivation to select major, Second, NCS curriculum, Third, Career decision". In this study, Chronbach's Alpha coefficients were presented to analyze the reliability of variables and exploratory factors, and the Berimax method was performed. The AVE and CR values of the items were calculated to be 0.5 and 0.7, respectively. Therefore, it was analyzed that the Intensive feasibility of items were well-focused. As a result of the hypothesis test, the standardized coefficients were calculated as follows: 'Selective motivation ⇨ NCS curriculum' is 0.563, 'NCS curriculum ⇨ career decision' is 1.339. The relationship between the two hypotheses was found to be positive (+). In order to improve the career decision of students in security related departments, it seems necessary to raise the motivation of selection and to improve the satisfaction of NCS curriculum.

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A Study on the Relation Between Martial Arts Training and Job Performance of Security Personnel (보안요원의 무도수련과 직무수행 관계에 관한 연구)

  • Choi, Jeong-Il;Jang, Ye-Jin
    • Convergence Security Journal
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    • v.17 no.5
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    • pp.179-186
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    • 2017
  • The purpose of this study is to analyze the relation of security officers' martial arts training and job performance. To this end, we conducted surveys on security practitioners. The questionnaire consisted of three variables, "necessity of martial arts training, application to practical security work, improvement of job satisfaction". In this study for reliability analysis, Chronbach's Alpha coefficient was calculated. In order to verify the validity of the measured variables, exploratory factors were analyzed using the Berimax method. Both AVE and CR values of the measured variables were above the reference value of 0.5, indicating that the convergence validity was good. As a result of the hypothesis test, the standardization coefficient is 0.636 for "need for training in martial arts training${\Rightarrow}$practical security work", 0.986 for "practical security work${\Rightarrow}$job satisfaction improving", and the relationship between the two hypotheses is positive(+). In order to improve the job satisfaction of security-related practitioners, it seems necessary to raise the need for martial arts training.

Durability Evaluation of High-Performance, Low-Heat Self-Compacting Concrete for Foundation of Tall Buildings (초고층 건축물 매트 기초용 고성능 콘크리트 내구성 평가)

  • Kim, Young-Bong;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.5
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    • pp.425-430
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    • 2022
  • Concrete used for the foundation of high-rise buildings is often placed through in an integrated pouring to ensure construction efficiency and quality. However, if concrete is placed integrally, there is a high risk of temperature cracking during the hydration reaction, and it is necessary to determine the optimal mixing design of high-performance, high-durable concrete through the replacement of the admixture. In this study, experiments on salt damage, carbonation, and sulfate were conducted on the specimen manufactured from the optimal high-performance low-heating concrete combination determined in the author's previous study. The resistance of the cement matrix to chlorine ion diffusion coefficient, carbonation coefficient, and sulfate was quantitatively evaluated. In the terms of compression strength, it was measured as 141% compared to the structural design standard of KCI at 91 days. Excellent durability was expressed in carbonation and chlorine ion diffusivity performance evaluation. In particular, the chlorine ion diffusion coefficient, which should be considered the most strictly in the marine environment, was measured at a value of 4.09×E-12m2/y(1.2898×E-10m2/s), and is expected to be used as a material property value in salt damage durability analysis. These results confirmed that the latent hydroponics were due to mixing of the admixture and high resistance was due to the pozzolane reaction.

A Study on Categorizing Researcher Types Considering the Characteristics of Research Collaboration (공동연구 특성을 고려한 연구자 유형 구분에 대한 연구)

  • Jae Yun Lee
    • Journal of the Korean Society for information Management
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    • v.40 no.2
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    • pp.59-80
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    • 2023
  • Traditional models for categorizing researcher types have mostly utilized research output metrics. This study proposes a new model that classifies researchers based on the characteristics of research collaboration. The model uses only research collaboration indicators and does not rely on citation data, taking into account that citation impact is related to collaborative research. The model categorizes researchers into four types based on their collaborative research pattern and scope: Sparse & Wide (SW) type, Dense & Wide (DW) type, Dense & Narrow (DN) type, Sparse & Narrow (SN) type. When applied to the quantum metrology field, the proposed model was statistically verified to show differences in citation indicators and co-author network indicators according to the classified researcher types. The proposed researcher type classification model does not require citation information. Therefore, it is expected to be widely used in research management policies and research support services.

Perfluorosulfonic Acid Composite Membranes Containing Antioxidant Grafted Graphene Oxide for Polymer Electrolyte Membrane Fuel Cell Applications (산화방지 작용기를 함유한 산화 그래핀이 도입된 과불소화계 복합 막의 고분자 전해질 막 연료전지로의 응용)

  • Inhyeok Hwang;Kihyun Kim
    • Membrane Journal
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    • v.33 no.6
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    • pp.416-426
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    • 2023
  • In this study, hindered amine-grafted graphene oxide (HA-GO) with antioxidant properties was prepared and incorporated into Nafion-based composite membranes as an effective filler material for polymer electrolyte membrane fuel cell applications. HA-GO was synthesized via a ring-opening reaction between amine groups in 4-amino-2, 2, 6, 6-tetramethyl piperidine and epoxy groups on the surface of GO. Nafion-based composite membranes containing different weight contents of HA-GO were fabricated to compare the polymer electrolyte membrane properties with those of the pure Nafion membrane. The composite membranes with HA-GO were found to have better mechanical properties, chemical stability, and proton conductivity than the pure Nafion membrane. In particular, the conductivity retention behavior confirmed by the decrease in proton conductivity after Fenton's test of the composite membranes was better than that of the pure Nafion membrane due to the incorporation of HA-GO with effective antioxidant properties.