• Title/Summary/Keyword: 혼합 산화제

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Propellant utilization system on liquid-fuelled rocket (액체추진 발사체의 추진제 소진시스템)

  • Cho, Kie-Joo;Lim, Seok-Hee;Jung, Young-Suk;Oh, Seung-Hyub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.203-206
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    • 2006
  • We have studied, for maximizing the total impulse of liquid propulsion system, Propellant Utilization System (PUS) to minimize outage of propellant. Propellant outage is mainly influenced by propellant mixture ratio during flight and real quantity of loaded propellant. If one employs cryogenic propellant, the variation of propellant density due to the temperature change has major effect on outage control. Feedback control of propellant level of each tank during flight could deplete both tanks simultaneously. To introduce this system, however, the mixture ratio control system of rocket engine is necessary.

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초임계 조건 분사기 난류유동

  • Park, Tae-Seon
    • Journal of the KSME
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    • v.56 no.9
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    • pp.38-43
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    • 2016
  • 초임계 난류유동이 활용되고 있는 가장 대표적인 시스템은 액체로켓연소기이다. 액체로켓엔진은 목적하는 임무에 따라 추력이 결정되고 엔진의 추력이 결정된다. 이러한 추력을 결정하는 핵심부품이 분사기(injector)이다. 실용 인공위성을 발사하기 위한 액체로켓엔진의 연소기는 수백 개의 분사기를 통해 연료와 산화제가 혼합되는 구조를 가지고 있다. 따라서 로켓연소기의 연소특성 및 성능은 분사기의 혼합특성에 좌우된다. 그러므로 단일 분사기의 연료/산화제 혼합특성에 대한 많은 실험과 해석연구가 진행되고 있다. 그런데 초임계압력에서는 액체의 표면장력이 사라지게 되어 독특한 혼합특성을 가지고 있기 때문에 성능을 높여주기 위하여 초임계 압력을 선택할 경우 분사기에 대한 연구가 선행되어야 한다. 이 글에서는 이러한 초임계 작동압력에서 분사기에 대한 연구들을 소개하고자 한다.

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Effect of Epoxy Mixed with Nafion Solution as an Anode Binder on the Performance of Microbial Fuel Cell (산화전극 결합제로서 나피온용액에 혼합된 에폭시가 미생물연료전지의 성능에 미치는 영향)

  • Song, Young-Chae;Kim, Dae-Seop;Woo, Jung-Hui
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.1
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    • pp.1-6
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    • 2014
  • The composite anodes of exfoliated graphite (EG) and multiwall carbon nanotube (MWCNT) were fabricated by using the binders with different content of epoxy in Nafion solution. The influence of the epoxy content in the anode binder on the performance of microbial fuel cell (MFC) was examined in a batch reactor. With the increase in the epoxy content in the anode binder, increase in physical binding force was observed, but at the same time an increase in the internal resistance of MFC was also observed. This was due to the increase in activation and ohmic resistance. For the anode binder without epoxy, the maximum power density was $1,892mW/m^2$, but a decrease in maximum power density was observed with the increase in the epoxy content in the anode binder. With the epoxy content of 50% in the anode binder, a decrease in the maximum power density to $1,425mW/m^2$ was observed, which about 75.3% of the anode binder without epoxy is. However, the material consisting of the same amount of epoxy and Nafion solution is a good alternative for anode binder in terms of durability and economics of MFC.

An experimental study for the prediction of combustion performance of the Unlike Impinging Quadlet Injector (충돌형 Quadlet 인젝터의 연소성능 예측에 관한 실험적 연구)

  • Kim, J.W.;Park, H.H.;Han, J.S.;Kim, S.J.;Kim, Y.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.4
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    • pp.44-50
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    • 1999
  • For the prediction of combustion performance of the Unlike Impinging Quadlet Injector (OOOF type), mixing efficiency, mixing characteristic velocity, and efficiency of mixing characteristic velocity were obtained from the cold test. Water/kerosene were used for simulants, The momentum ratio of oxidizer and fuel were mixing correlating parameter. Orifice discharge coefficient, spray pattern and mass distribution were measured. As a result, invasion-depth had strong effect on mixing efficiency, mixing characteristic velocity, and efficiency of mixing characteristic velocity. Mixing efficiency and efficiency of mixing characteristic velocity showed maximum value for momentum ratio 1.67(TMR = 2.5), and fuel rich state showed larger decreasing ratio than oxidizer rich state.

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Improvement of Anodic Performance by Using CTP Binder Containg Nickel (니켈을 함유한 콜타르 피치 결합제를 이용한 미생물연료전지 산화전극 성능개선)

  • Yoon, Hyung-Sun;Song, Young-Chae;Choi, Tae-Seon
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.9
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    • pp.499-504
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    • 2015
  • The composite anodes of expanded graphite (EG) and multiwall carbon nanotube (MWCNT) for microbial fuel cells were fabricated by using coal tar pitch (CTP) binder containing nickel (Ni), and the effect of the anodes with the binders on the performance of the MFCs were examined in a batch reactor. During the start-up of the MFCs, quick increase in voltage was observed after a short lag phase time, indicating that the CTP binder is biocompatible. The biomass attatched on the anode surface was more at higher Ni content in the binder, as well as at smaller amount of CTP binder for the fabrication of the anode. The internal resistance of the MFC was smaller for the anode with more biomass. Based on the results, the ideal combination of CTP and Ni for the CTP binder for anode was 2 g and 0.2 g, respectively. The maximum power density was $731.8mW/m^2$, which was higher 23.7% than the anode with Nafion binder as control. The CTP binder containing Ni for the fabrication of anode is a good alternative in terms of performance and economics of MFCs.

Synthesis and Characterization of Soluble Polypyrrole with High Conductivity (높은 전기 전도성을 갖는 가용성 폴리피롤 합성 및 특성)

  • Hong, Jang-Hoo;Jang, Kwan-Sik
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.234-238
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    • 2007
  • Highly conducting Polypyrroles soluble in organic solvents were synthesized using functional doping agents, such as mixed dopants [sodium di(2-ethylhexyl)sulfosuccinate (DEHSNa) Naphthalenesulfonic acid (NSA), DEHSNa Toluenesulfonic acid (TSA), DEHSNa Dodecylbenzensulfonic acid (DBSA)] and mixed oxidants [$(NH_4)_2S_2O_8{\cdot}FeCl_3$, $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$]. Ppy-DEHS powder using an oxidant, such as $(NH_4)_2S_2O_8$ (10 wt%/vol.) showed higher solubility than the mixed dopant (DEHSNa NSA, 3 wt%/vol.) and mixed oxidant [$(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$, 4 wt%/vol.] in DMF solvent. But Ppy-DEHS free standing film using a mixed dopant, such as DEHSNa NSA (16 S/cm) and a mixed oxidant, such as $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$ (13 S/cm) cast from DMF solvent showed higher electrical conductivity than $(NH_4)_2S_2O_8$ (2 S/cm). For the Ppy-DEHS films using various condition cast from DMF solvent, three dimensional various range hopping model (3D VRH ; $\{{\sigma}_{dc}(T)={\sigma}_oexp[-(T_o/T)^{1/4}]\}$) provided fit to the results of temperature dependence of electrical conductivity measurement.

Experimental Study on High Temperature Oxidation of Ultra-lean Mixture and Heat Recovery (초 희박혼합기의 고온산화와 폐열회수에 관한 실험적 연구)

  • 이강주;정영식;이창언;김문철;임장순
    • Journal of Energy Engineering
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    • v.9 no.4
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    • pp.319-327
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    • 2000
  • 산업분야의 여러공정에서 배출되는 휘발성 유기화합물은 1차적인 작업자에 대한 유해성뿐만이 아니라 대기중에 배출시의 제 2차 오염물질의 생성 때문에 최근 들어 이러한 물질의 처리에 큰 관심이 집중되고 있다. 본 연구에서는 휘발성 유기화합물로서 프로판을 사용하여 이러한 초 희박 혼합기의 제거를 위해 재생열산화법이 제안되었다. 실험장치에는 중앙에 연소실과 전기적 열량공급장치를 장착하였다. 초 희박 혼합기의 연소실에서의 산화과정과 열사화 장치의 폐열회수 특성을 연구하기 위하여 혼합기의 농도, 유속 및 연소실 최대온도와 같은 다양한 작동조건을 고려하였다. 그 결과. 재생열산화장치가 초 희박 혼합기의 산화에 적절하게 사용될 수 있음을 알았으며 최대 96%의 제거효율 얻을 수 있었다. 산화과정중에 발생하여 배출되는 CO는 운전조건을 변화시킴으로써 그 농도를 낮출 수 있었으며 열적 NOx는 배출되지 않았다. 페열회수효율은 전 운전영역에서 높게 나타났으며 그 값이 최대 98%에 이르렀다.

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Development of Environmental-friendly Cleaning Agents Utilizing Organic Acids for Removal of Scale on the Wall of Cleaning Beds and Distribution Reservoirs in the Waterworks (유기산을 이용한 상수도 정수장 및 배수지 벽면 스케일 세척용 친환경 세정제 개발)

  • Lee, Jae-Ryoung;Yoon, Hee-Keun;Bae, Jae-Heum;Shin, Hyun-Duk
    • Clean Technology
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    • v.18 no.3
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    • pp.272-279
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    • 2012
  • In this study, an environmental-friendly cleaning agent utilizing organic acids and various additives has been developed and applied to the field for removal of scale deposited on the cleaning beds or distribution reservoirs of the waterworks. As an analytical result of scale on the cleaning beds, we found that it consists of mainly metallic oxides such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, and MnO. Malic acid, malonic acid, and citric acid showed relatively better solvency on $Al_2O_3$, $Fe_2O_3$, and MnO except $SiO_2$ among various organic acids. Mixed organic acid solutions of malic acid, malonic acid, and citric acid were prepared with certain weight ratios and their solvencies on mixed metal oxides of $Al_2O_3$, $Fe_2O_3$, and MnO were investigated. The experimental results showed that an 10% mixed organic acid solution prepared with weight ratio of malic acid : malonic acid : citric acid = 6 : 2 : 2 were found to have best scale solvency power of about 29%. The formulated cleaning agents with a small amount of nonionic surfactant showed much better solvency on mixed oxides than mixed organic solution alone. Especially, the formulated cleaning agent with 0.2 wt% LA-7 surfactant appeared to have best scale removal efficiency of about 35%. However, the formulated cleaning agent with disinfectants such as NaClO, $H_2O_2$ and $Ca(ClO)_2$ showed poor solvency on mixed oxides. It is inferred that surfactants are able to improve scale removal efficiency due to their capability of emulsification, and disinfectants cause to degrade scale solvency in water because of their oxidation. Based on these basic experimental results, formulated cleaning agents have been prepared with mixed organic acid solution, nonionic surfactants, and disinfectants and successfully applied to removal of scales on the cleaning beds and distribution reservoir at city D waterworks.

Oxidative Stability of Deep-Fried Instant Noodle Prepared with Ricebran Oil Fortified by Adding Antioxidants or by Blending with Palm Oil (항산화제 또는 팜유로 보강된 미강유를 이용한 라면의 산화안정성)

  • Kang, Dong-Ho;Park, Hye-Kyung;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.21 no.3
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    • pp.409-418
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    • 1989
  • The oxidative stability of the ramyon prepared with ricebran oil fortified with ${\alpha}-tocopherol$, BHA, TBHQ, and ascorbyl palmitate+citric acid or blended with palm oil was studied to assess the suitability of the oil as the frying oil. The antioxidants were added to a ricebran oil at 0.02% level, respectively, while blended oils were prepared by adding a palm oil to the ricebran oil at ratios of 3:7, 5:5, and 7:3. Ramyon samples were prepared by frying steamed noodel with the oils. They were stored in dark at $35.0{\pm}0^{\circ}C$. for 90 days. Peroxide, acid, iodine values, dielectric constant, and fatty acid composition of the oils extracted from the samples were determined regularly. The oxidative stability of the extracted oils and storage stability of the samples were estimated from the results of the determinations. ${\alpha}-tocopherol$ did not exert any appreciable antioxidant effect on the extracted oil while BHA demonstrated some effect. Ascorbyl palmitate with citric acid and especially TBHQ exerted a considerable effect. The storage stability of the samples fried with the oil fortified with TBHQ was as good as that of the samples prepared with the palm oil. The stability of the samples improved as the palm oil content In the frying oil increased. The stability of the samples fried with the blended oil containing 70f) palm oil was comparable to that of the samples prepared with the pure palm oil

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Reactive Fields Analysis of Hybrid Combustor Under Different Arrangements of Oxidizer Injectors (하이브리드 연소기의 산화제 주입기 배열 특성에 따른 반응유동장 해석)

  • Cho Sung-Chan;Kim Soo-Jong;Lee Seung-Chul;Kim Jin-Kon;Koo Ja-Yae;Moon Hee-Jang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.2
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    • pp.78-88
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    • 2005
  • The combustion characteristics of End-Burning hybrid combustor using different types of injector system are numerically investigated to visualize the temperature fields in the combustion chamber The basic characteristics of combustion with different O/F ratio is also analyzed in order to capture the main behavior of diffusion flame inside the swirl induced hybrid combustion chamber It was found that the arrangement of oxidizer injectors give strong effect on the temperature field dominating mixing between fuel and oxidizer. The results show that among five different oxidizer injectors arrangement, the counter flow injector has the highest mixing efficiency. However, the observed high wall temperature presence near the oxidizer injectors remains to be solved.