• Journal of the Korean Chemical Society
• /
• v.13 no.1
• /
• pp.16-24
• /
• 1969

Ni, Co, Zn, Cd, Mn, Mg, Ca, Sr, Ba 등의2가 금속과 U(VI) 및 V(IV)의 이온이 만드는 $MCup_2$ 조성의 cupferrates 착화합물에 관하여, 그 용해도가 좋은 dioxane-$H_2O$, methanol-$H_2O$, ethanol-$H_2O$ 및 2-propanol-$H_2O$의 혼합용매를 사용하여, 그들의 몰분율을 변화시키면서 제 1, 제 2 및 전체의 열역학적인 안정도상수를 전위차적정법에 의하여 측정하고, 안정도 상수와 유기용매의 몰분율에 관한 실험식을 얻었다. 한편 분광광전법에 의하여 가능한 cupferrates의 전체 안정도 상수를 측적하여 이들과 비교하였다. 2가 금속 cupferrates의 안정도상수는 위에 적은 금속의 순서로 감소하고, 이들의 log $K_1$은 log $K_2$보다 크지만, U(VI)과 V(IV)의 cupferrates는 log $K_1$$K_2$여서 1:1과 1:2 착화합물 사이에 구조 변화가 있는듯하다. 몰분율이 영인 점에서의 안정도상수는 금속 cupferrates의 수용액에서의 용해반응의 평형상수에 해당하며, 금속의 착화합물의 안정도상수와 용해도와는 무관하고, K<$10^5$인 cupferrates에 관해서는 분광전법을 적용하기 어렵다.

• Journal of Power System Engineering
• /
• v.15 no.5
• /
• pp.77-82
• /
• 2011

SiC particulate reinforced Al matrix composites with different SiC volume fractions were fabricated by thermal spray process. And the dry sliding wear test were performed on these composites using the applied load of 10 N, rotational speed of 30 rpm, radius of rotation 15 mm. Wear tracks on the Al/SiC composites were investigated using scanning electron microscope(SEM) and energy dispersive spectroscopy (EDS). It was observed that wear behavior of Al/SiC composites and formation of MML was changed dramatically according to reinforcement volume fraction.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.25 no.6
• /
• pp.988-995
• /
• 2001

Functionally graded materials(FGMs) are highlighted to be suitable for high temperature engineering due to their continuous distribution of material properties. In this paper, an optimal design is executed for determining the optimal material volume distribution pattern that minimizes the steady-state thermal stress of FGM heat-resisting composites. The interior penalty function method and the golden section method are employed as optimization techniques while the finite element method is used for thermal stress analysis. Through numerical simulations we suggest the volume fraction distributions that considerably improve initial thermal stress distributions.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.15 no.5
• /
• pp.1763-1773
• /
• 1991

본 연구에서는 포화수증기와 공기의 혼합기내에서 분무수적으로의 열 및 질량 전달률을 계산하기 위하여 수적의 부분혼합모형과 비혼합모형에 대하여 수적내 과도온 도분포의 해석해를 적용성이 보장되면서도 계산상의 어려움이 수반되지 않는 형태로 구하기 위하여 수적내부의 열전도해석에 있어서 적분법을 적용하였다. 적분법으로 얻어지는 과도온도분포의 해는 유한차의 다항식으로 표시되어 비혼합모형인 경우 각시 간 구간의 경계에서의 온도분포가 연속성을 유지하면서 물성치들의 온도에 대한 종속 성이 쉽게 고려되고 계산도 용이한 형태이다. 본 보에서 제시하는 해석결과의 적용 성을 조사하기 위하여 완전혼합모형을 포함하는 세가지 수적모형들에 대한 계산결과들 로부터 얻어진 시간변화에 따른 수적의 무차원 체적평균온도변동을 유효한 실험결과들 과 비교, 검토하였으며, 부분혼합모형에 대하여 혼합기의 압력, 수적의 초기온도, 혼 합기 속에 포함되어 있는 수증기의 체적분율, 수적의 초기크기, 수적의 초기속도 및 분사각도가 주위혼합기로부터 수적으로 전달되는 열 및 질량전달에 미치는 영향을 조] 사하고 도출된 대표적인 검토 결과를 제시하였다.

• Korean Journal of Materials Research
• /
• v.6 no.8
• /
• pp.841-851
• /
• 1996

In a recent investigation, the formation of bainite phase in direct-quenched low carbon non heat-treated steel was reported. In this study the effects of bainite phase on the mechanical properties of direct-quenched microalloying steels were investigated. By isothermal transformation at $480^{\circ}C$ for 7 sec., volume fraction of bainite lath was 15~20%, and the UTS and impact energy were increased. In this case $B_{ll}$ and $B_{lll}$ type bainite was observed and the fractography of impact test specimen showed a ductile fracture tendency. Isothermal transformation for 100sec., yielded 30% volume fraction of granular bainite and the mechanical properties were decreased. The f ractography of impact test specimen showed a brittle fracture tendency. The addition of Mo was more effective than B for improving impact energy because amounts of boron aditions were restricted to considerably lower levels, typically 10~ 30ppm. From this study, it is predicted that 15~20% volume fraction of lath bainite on the direct quenching process is procduced by addition of Mo up to 1.2wt. % and controlling the finish forging proc¬ess at $1000^{\circ}C$ and using oil as direct quenching media. This will improve mechanical properties of the direct- quenched steel.

• Journal of the Korean Chemical Society
• /
• v.25 no.3
• /
• pp.152-159
• /
• 1981

The rates of solvolysis for p-nitrobenzyl chloride have been measured by the electric conductivity method in aqueous ethanol from 0.0 to 0. 5 mole fraction of ethanol under various pressures up to 1200bar at 50 and $60{\circ}C$. The activation parameters, ${\Delta}V_\0^{\neq},\ {\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ are evaluated from the rate constants. The results indicated that ${\Delta}V_\0^{\neq}$ exhibits an extremum behaviors near 0.3 mole fraction of ethanol and ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ near 0.1 mole fraction of ethanol. This behaviors are discussed in terms of solvent structure variation and the pressure dependences of ${\Delta}H^{\neq},\ {\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ are also discussed individually. The signs of the pressure dependence of ${\Delta}H^{\neq}$${\Delta}S^{\neq}$ are shown to be consistent with those required by the Maxwell relationships for classical thermodynamic systems.

• Korean Chemical Engineering Research
• /
• v.53 no.2
• /
• pp.193-198
• /
• 2015

The high-pressure phase behavior of a polycaprolactone (Mw=56,145 g/mol, polydispersity 1.2), dichloromethane, and carbon dioxide ternary system was measured using a variable-volume view cell. The experimental temperatures and pressures ranged from 313.15 K to 353.15 K and up to 300 bar as functions of the $CO_2$/dichloromethane mass ratio and temperature, at poly(D-lactic acid) weight fractions of 1.0, 2.0, and 3.0%. The correlation results were obtained from the hybrid equation of state (Peng-Robinson equation of state + SAFT equation of state) for the $CO_2$-polymer system using the van der Waals one-fluid mixing rule. The three binary interaction parameters were optimized by the simplex method algorithm.

• Journal of the Korean Society of Combustion
• /
• v.6 no.1
• /
• pp.7-13
• /
• 2001

Propagation characteristics of tribrachial flames have been studied numerically in a two-dimensional fuel/oxidizer mixing layer. A flame is initiated by imposing a high temperature ignition source. Subsequent propagation of a tribrachial flame is traced. The flow redirection effect at the leading edge of a tribrachial flame increases the propagation speed beyond the corresponding stoichiometric laminar burning velocity. The effect of mixture fraction gradient on the propagation speed of a tribrachial flame is analyzed in a mixing layer considering that mixture fraction gradient increases as a tribrachial flame propagates toward upstream. As the flame curvature at the leading edge increases with decreasing mixture fraction gradient, the flow redirection effect becomes more pronounced on the flame propagation speed. As a result, the propagation speed of a tribrachial flame increases with decreasing mixture fraction gradient.

• Journal of Power System Engineering
• /
• v.16 no.5
• /
• pp.5-12
• /
• 2012

희박예혼합기의 급속연소에 관한 연구를 위하여 2-실린더 가솔린 엔진을 부실 타입의 압축천연가스(CNG) 분사 엔진으로 개조하였다. 본 연구에서는 부실의 최적설계에 관심을 두고 두 종류의 부실을 적용하여 실험을 실시하였고, 부실의 체적과 홀 개수는 1.5cc와 6개로 각각 동일하게 하고, 홀 직경을 0.8mm 및 1.1mm로 달리하였다. CNG연료는 포트연료분사(Port fuel injection; PFI)와 부실분사(Sub-chamber injection; SCI)에 의해 엔진에 독립적으로 공급되고, 그 실험결과로 구한 연소압력, 평균유효압력(IMEP), 질량연소분율과 사이클변동계수(COV) 등을 서로 비교하였다. 본 연구의 대표적 실험연구결과로서 PFI 타입의 엔진연소특성은 희박예혼합기의 경우를 제외하고 모든 조건에 있어서 기존의 가솔린 엔진과 비슷하였고, SCI 타입의 엔진연소특성으로 평균유효압력은 부실 내에 불완전 예혼합기형성으로 PFI 타입보다 낮았으며, COV는 SCI 타입이 희박가연한계가 확대됨으로 인하여, 특히 높은 공기과잉률 범위에서 PFI 타입과 비교해 보다 좋은 결과를 나타내었다.

• Journal of agricultural medicine and community health
• /
• v.31 no.3
• /
• pp.275-284
• /
• 2006

Objectives: This investigation was carried out to understand the status of the urinary incontinence (UI) and overactive bladder (OABs) syndrome of women in a rural region. Methods: The authors conducted a questionnaire survey among the 322 females who voluntarily participated in a health examination, from 16 to 18 August 2001. Using by definition of UI and OABs, we calculated the proportion of UI, OABs I, and OABs II. The data collected was evaluated using the SPSS 12.0 statistical package, and the differences of symptoms and problems related to daily life between UI, OABs patients and the others were analyzed using a Chi-square test or Fisher's exact test. Results: The overall proportion of UI was 35.4%, and stress UI (32.9%) is more common than urgency UI (17.4%) and mixed UI (14.9%). The proportion of OABs I and OABs II were respectively 36.0%, 14.0%. Symptoms related to UI or OABs were nocturia (35.1%), frequency (23.9%), urgency (21.4%) etc. Of the incontinence cases, 27.2% had experienced UI for a period of one to three years. The proportion of OABs increased significantly by age (p<0.05), UI didn't. The most frequent symptoms in UI and OABs were respectively 'slow stream', 'urgency'. The most frequent problem of daily life in UI and OABs was 'seeking toilet firstly at stranger place'. Conclusions: The proportion of UI and OABs in our study were respectively 35.4%, 14.0%. UI and OABs must be very significant health problems in women, especially rural region. Systemic and profound interventions for UI and OABs need to administer to women in Korea.