• Solar Energy
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• v.15 no.3
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• pp.75-90
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• 1995

This paper is concerned about alternative refrigerants for HCFC22 used in room air conditioners and heat pumps. Computer simulation of residential air conditioners using refrigerant mixtures is carried out. Following refrigerants are selected as the pure refrigerants constituting the mixtures studied: R32, R124, R125, R134, R134a, R143a and R152a. Simulation results are presented fur the following mixtures: R32/R134a, R32/R152a, R32/R134, R32/R124, R143a/R134a, R143a/R152a, R143a/R124, R125/R134a, R125/R152a, R125/R124, R32/R152a/R134a, R32/R152a/R134, R32/R152a/R124. The best fluid is found to be the ternary mixture of R32/R152a/R124. For that mixture, the coefficient of performance(COP) and volumetric capacity for refrigeration(VCR) are 13.7% larger and 23% smaller than the respective values for HCFC22. R32/R124 mixture is the best binary fluid pair whose COP and VCR are 13.4% larger and 9.6% smaller than those for HCFC22.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.589-599
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• 1995

The frictional pressure drop of a capillary tube flow is experimentally investigated for pure refrigerants such as R32, R125, and R134a and refrigerant mixtures such as R32/R134a(30/70 by mass percent), R32/R125(60/40), R125/R134a(30/70), and R32/R125/R134a(23/25/52). The binary interaction parameters for the calculation of viscosities of refrigerant mixtures are found based upon the data in the open literature. Several homogeneous flow models predicting the viscosity of two-phase region are compared to select the best model. Cicchitti's equation is known to be the most adequate for the prediction of the viscosity for refrigerant mixtures, which is used in the analysis of adiabatic capillary flows. A model for the prediction of the frictional pressure drop of single and two-phase flow is developed for refrigerant mixtures in this study. This model may be used to design and analyze the performance of a capillary tube in the refrigerating system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.12
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• pp.791-798
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• 2011

In this study, performance of R410A(50%R32/50%R125) and HFC32/HFC125 mixture is measured to examine the effect of composition shift of R410A used for various air-conditioners and heat pumps. The composition of HFC32/HFC125 mixture varies from the reference composition of R410A ${\pm}10%$ with 5% interval. Tests carried out in a heat pump bench tester at the evaporation and condensation temperatures of $7/45^{\circ}C$ and $-7/41^{\circ}C$ for summer and winter conditions, respectively. Test results show that both the coefficient of performance (COP) and compressor power of the HFC32/HFC125 mixture have the maximum difference of 2.0% as compared to those of R410A. Compressor discharge temperatures of HFC32/HFC125 mixture are increased up to $6.7^{\circ}C$ as compared to that of R410A. The amount of charge for HFC32/HFC125 mixture vary within 5.6% as compared to that of R410A. Overall, performance of R410A is not appreciably affected by the composition shift of ${\pm}10%$ of R32 under both air-conditioning and heat pumping conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.3
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• pp.292-302
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• 1998

In this study, 14 refrigerant mixtures composed of R32, R125, R134a, R143a, R152a, and R1270(Propylene) were tested in a breadboard heat pump in an attempt to replace R22 used in most of the residential air conditioners and heat pumps. The heat pump was of 1 ton capacity and water was employed as the secondary heat transfer fluids. All tests were conducted under ARI test A condition. Ternary mixtures composed of R32, R125, and R134a were shown to have 4∼5% higher COP and capacity than R22 and hence they seem to be very promising candidates to replace R22. On the other hand, ternary mixtures containing R125, R134a, and R152a have lower COP and capacity than R22. R32/R134a binary mixtures show a 7% increase in COP and have the similar capacity to that of R22 and hence they are also good candidates to replace R22. Special care must be exercised when a suction line heat exchanger is used with these mixtures in air conditioners. Finally, the compressor discharge temperatures of all mixtures tested were lower than those of R22 by 15.g∼34.7t, which indicates that these mixtures would offer better system reliability and longer life time than R22.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.730-740
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• 1996

Boiling heat transfer coefficients of pure refrigerants (R22, R32, R134a, R125, R290, and R600a) and refrigerant mixtures (R32/Rl34a, R290/ R600a, and R32/R125) are measured experimentally and compared with Chen's correlation. The test section is a seamless stainless steel tube with inner diameter of 7.7mm and uniformly heated by applying electric current directly to the tube. Heat fluxes range from 10 to 30kW$^2$. Mass fluxes are set to 424 ~ 742kg/m$^{2}$s for R22, R32, R134a, R32/R134a, and R32/Rl25 ; 265 ~ 583kg/m$^{2}$s for R290, R600a, and R290/R600a. Heat transfer coefficients depend strongly on heat flux at a low quality region and become independent as quality increases. Convective boiling term in the Chen's correlation predicts experimental data of the pure refrigerants fairly well (relative error of 12.1% for the data of quality over 0.2). The correlation for pure substances overpredicts the heat transfer coefficients for nonazeotropic refrigerant mixtures.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.3
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• pp.423-436
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• 1996

Thermodynamic performance of eight zeotropic R-22 alternative refrigerant mixtures selected by AREP(R-22 Alternative Refrigerants Evaluation Program) and R-32/R-125/R-134a(23%/25%/52%), namely R-407C were evaluated by the "drop-in" simulation method. An existing air conditioner was selected and its design data were used for the simulation. "ARI Test A" air conditions were applied. The degree of vapor superheat at the compressor inlet fixed at $5^{\circ}C$ for all the mixtures. The results of the simulation were compared with those of R-22. COPs of all mixtures except for R-32/R-227ea(35%/65%) and R-32/R-125/R-134a(10%/70%/20%), were higher than that of R-22 by 2%~8%, while the capacities were all lower than that of R-22 by 13%~27%. COP of R-32/R-134a(40%/60%) was 2.4% higher but the capacity was 15% lower than those of R-22. In the case of R-32/R-134a(30%/70%), COP and capacity were 5.5% higher and 15% lower than those of R-22, respectively. Among the ternary mixtures, R-407C and R-32/R-125/R-134a(30%/10%/60%) showed the best performance. COP of R-407C was 2.4% higher than those of R-22 but the capacity was 15% lower.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.3
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• pp.276-283
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• 1997

The nucleate boiling heat transfer experiments are performed using a ternary refrigerant R407C which is a candidate of alternatives of HCFC 22. The boiling phenomena for R-32, R-125, and R-134a which are the constituent refrigerants of R407C are also investigated to give the foundation of theoretical research for the mixture component boiling. The nucleate boiling heat transfer coefficients of R407C is less than those of HCFC 22 which has the similar physical and transport properties. Since the experimental results show the deterioration of boiling heat transfer coefficients of ternary mixture refrigerants R407C, the boiling heat transfer coefficients of R407C cannot be obtained by the linear combination of boiling heat transfer coefficients from its constituent components R-32, R125, and R134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.6
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• pp.468-476
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• 2002

This paper deals with heat and mass transfer characteristics and performance evaluation of a counter flow double-tube condenser for a multi-component refrigerant mixture. The local heat and mass transfer characteristics of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a are evaluated for a counter flow double-tube condenser cooled by water. Then, the local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, heat flux and condensation mass flux are obtained. The heat exchange performance for ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a on the total pressure drop and the heat transfer characteristics are also compared with those for R404A, R410A, R502, R22, R32, Rl23 and R134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.1
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• pp.45-54
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• 1996

An experimental investigation on the two-phase flow through tube orifices was performed with the refrigerant mixture of R32/125/134a(30/10/60). A series of tests were conducted to generate wide range of data at varying operation conditions with four short tubes. The tests include both single and two-phase flow conditions at the inlet of the short tube with different oil concentrations. Experimental data were presented as a function of major operating parameters and short tube diameter. Based on test results and data analysis, a semi-empirical flow model was developed to predict the mass flow rate through short tube orifices with a given set of conditions. The flow model was formed to cover both single and two-phase flow at the inlet of short tube with considering the effects of oil concentration.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.177-186
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• 1996

The characteristics of the flow of pure HFC refrigerants(R32, R125, and R134a) and their mixtures through capillary tubes were investigated experimentally. Two capillary tubes with 1.2mm and 1.6mm inner diameter and 1.5m length were adopted as test sections. Mass flow rates and temperatures and pressures were measured for several condensing temperatures and degrees of subcooling at capillary tube inlet. The effects of the condensing temperature, inner diameter of capillary tube, and subcooling on the mass flow rate of refrigerants were discussed, and the mass flow rates of HFC refrigerants were compared with that of R22. The pressure and temperature distributions along the capillary tube compared with that of R22. The pressure and temperature distributions along the capillary tube show that there is a metastable equilibrium state in the flow through the tube. Underpressure for vaporization increases as refrigerant mass flux increases and inlet subcooling decreases. Empirical correlation was suggested to predict underpressure for vaporization of the HFC refrigerants.