• Title/Summary/Keyword: 혼성제

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Experimental Study for Toe Stability of Composite Structure under Oblique Incident Waves Conditions(Head of Breakwater) (경사입사파 조건에서 혼성제 근고부 안정성 실험(제두부))

  • Lim, Ho Seok;Kim, Yeon Il;Lee, Jong In
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.303-303
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    • 2020
  • 국내의 주요 외곽시설은 대수심화 및 설계외력의 증대 등으로 경제성 및 안정성 등의 확보를 위해 혼성제 형식의 구조물을 적용하는 사례가 주를 이루고 있다. 혼성제 근고부 안정성과 관련해서는, 설계파에 대한 안정적인 피복재 중량을 구하는 것이 설계상 중요하다. 기존의 직각 입사파에 대한 연구는 많이 수행되어 왔으나, 경사 입사파 조건에 대한 검토 사례는 미미한 실정이다. 또한 직각입사 뿐만 아니라 경사 입사파에 대한 근고부 중량산정식으로 확장된 Tanimoto식을 적용하고 있으나, 수리실험과 중량산정식에 대한 오차가 발생하고 있어 수리실험을 통해 기존의 산정식에 대한 검토가 필요하다. 따라서 본 연구에서는 경사입사파 조건에 따른 혼성제 제두부 구간의 피복재 안정성에 대하여 실험을 수행하였다. 설치수심은 0.3m 수심으로 고정하고, 입사각도를 0°, 30°, 45°, 60° 및 75°로 변화시켜 실험을 수행하였다. 전체 연장 10m의 모형에서 종점부 1m 구간을 실험구간으로 설정하고, 피복재의 종류는 피복석(50g), 콘크리트 피복블록(Tetrapod, Tripod)를 사용하였으며, 파랑조건은 불규칙파를 적용하였다. 주기 및 파고를 변화시켜 수리실험을 수행하였다. 실험결과는 제두부 구간에 피복된 피복재의 구간별 피해율을 분석하기 위해 구역분할도 적용하였으며, 확장된 Tanimoto식과 비교분석하여 중량산정식의 타당성을 검토하였다.

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Evaluation of Partial Safety Factors on Sliding of Monolithic Vertical Caisson of Composite Breakwaters (혼성제 직립 케이슨의 활동에 대한 부분안전계수 산정)

  • Lee, Cheol-Eung;Park, Dong-Heon;Kwon, Hyuk-Jae;Lee, Sun-Yong
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.21 no.4
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    • pp.267-277
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    • 2009
  • Partial safety factors of the load, resistance, and reliability function are evaluated according to the target probability of failure on sliding mode of monolithical vertical caisson of composite breakwaters. After reliability function is formulated for sliding failure mode of caisson of composite breakwaters regarding bias of wave force, uncertainties of random variables related to loads, strengths are analyzed. Reliability analysis for the various conditions of water depth, geometric, and wave conditions is performed using Level II AFDA model for the sliding failure. Furthermore, the reliability model is also applied to the real caisson of composite breakwaters of Daesan, Dong- hae, and Pohang harbor. By comparing the required width of caisson of composite breakwater according to target probability of failure with the other results, the partial safety factors evaluated in this study are calibrated straightforwardly. Even though showing a little difference on the 1% of target probability, it may be found that the present results agree well with the other results in every other target probability of failure.

Experimental Study on Hydraulic Characteristics of Wave Dissipating New Armor Unit (새로운 소파블록의 수리특성에 관한 실험적 연구)

  • 김인철;박영우;유철희;권혁민
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2003.08a
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    • pp.87-97
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    • 2003
  • 외해로부터 내습하는 파랑을 차단하므로서 해안의 세굴, 침식 등을 방지하고 항내의 정온을 유지하고 항만시설물을 보호하기 위하여 축조되는 방파제, 호안 등의 구조물 형식에는 경사제, 직립제, 혼성제 등 여러 가지가 있다 이 중 경사제는 표면을 파력에 충분히 대항할 수 있는 크기의 사석이나 콘크리트 블록을 쌓아 파랑을 경사면에서 쇄파시켜 에너지를 소멸시킴으로서 소파기능을 발휘한다. (중략)

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Probability of Failure on Sliding of Monolithic Vertical Caisson of Composite Breakwaters (혼성제 직립 케이슨의 활동에 대한 파괴확률)

  • 이철응
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.2
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    • pp.95-107
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    • 2002
  • A reliability analysis on sliding of monolithic vertical caisson of composite breakwaters is extensively carried out in order to make the basis for the applicability of reliability-based design method. The required width of caisson of composite breakwaters is determined by the deterministic design method including the effect of impulsive breaking waves as a function of water depth, also studied interactively with the results of reliability analyses. It is found that the safety factor applied in current design may be a little over-weighted magnitude for the sliding of caisson. The reliability index/failure probability is also seen to slowly decrease as the water depth increases for a given wave condition and a safety factor. In addition, optimal safety factor can roughly be evaluated by using the concept of target reliability index for several incident waves. The variations of optimal safety factor may be resulted from the different wave conditions. Finally, it may be concluded from the sensitivity studies that the reliability index may be more depended on the incident wave angles and the wave periodsrather than on the bottom slopes and the thickness of rubble mound.

Determination of cross section of composite breakwaters with multiple failure modes and system reliability analysis (다중 파괴모드에 의한 혼성제 케이슨의 단면 산정 및 제체에 대한 시스템 신뢰성 해석)

  • Lee, Cheol-Eung;Kim, Sang-Ug;Park, Dong-Heon
    • Journal of Korea Water Resources Association
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    • v.51 no.9
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    • pp.827-837
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    • 2018
  • The stabilities of sliding and overturning of caisson and bearing capacity of mound against eccentric and inclined loads, which possibly happen to a composite caisson breakwaters, have been analyzed by using the technique of multiple failure modes. In deterministic approach, mathematical functions have been first derived from the ultimate limit state equations. Using those functions, the minimum cross section of caisson can straightforwardly be evaluated. By taking a look into some various deterministic analyses, it has been found that the conflict between failure modes can be occurred, such that the stability of bearing capacity of mound decreased as the stability of sliding increased. Therefore, the multiple failure modes for the composite caisson breakwaters should be taken into account simultaneously even in the process of deterministically evaluating the design cross section of caisson. Meanwhile, the reliability analyses on multiple failure modes have been implemented to the cross section determined by the sliding failure mode. It has been shown that the system failure probabilities of the composite breakwater are very behaved differently according to the variation of incident waves. The failure probabilities of system tend also to increase as the crest freeboards of caisson are heightening. The similar behaviors are taken place in cases that the water depths above mound are deepening. Finally, the results of the first-order modal are quite coincided with those of the second-order modal in all conditions of numerical tests performed in this paper. However, the second-order modal have had higher accuracy than the first-order modal. This is mainly due to that some correlations between failure modes can be properly incorporated in the second-order modal. Nevertheless, the first-order modal can also be easily used only when one of failure probabilities among multiple failure modes is extremely larger than others.

Synthesis and Charaterization of Poly(styrene-b-methyl Methacrylate) by Free Radical Telomerization (Ⅰ) (자유라디칼 Telomerization 에 의한 스티렌메타크릴산메틸 Block 혼성중합체의 합성 및 분석 (제1보))

  • Jung Hag Park;Gil Soo Sur;Sam Kwon Choi
    • Journal of the Korean Chemical Society
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    • v.24 no.3
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    • pp.259-265
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    • 1980
  • Poly (styrene-b-methyl methacrylate) (PS-b-PMMA) was synthesized by free radical telomerization: the telomerization of styrene with $CCI_4$ by using AIBN as initiator followed by a second telomerization of methyl methacrylate using $CCI_3$ end group of the resulting polymer as the macrotelogen, with AIBN initiation, gave the styrene-methyl methacrylate block copolymer. The effects of the concentration of the macrotelogen, the concentration of monomer, the molecular weight of the macrotelogen, the reaction temperature and the concentration of the solvent on the formation of the block copolymer were investigated. Block copolymers containing up to 10 weight percent PMMA were obtained by adjusting the reaction conditions.

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Comparative analysis of caisson sections of composite breakwaters evaluated by Level I reliability-based design method (Level I 신뢰성 기반 설계법에 의해 산정된 혼성제 케이슨 단면의 비교 분석)

  • Lee, Cheol-Eung;Park, Dong Heon;Kim, Sang Ug
    • Journal of Korea Water Resources Association
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    • v.51 no.7
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    • pp.543-554
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    • 2018
  • A methodology has been presented for evaluating the partial safety factors on the sliding failure mode of vertical caissons of composite breakwaters and for determining the cross sections of those by Level I reliability-based design method. Especially, a mathematical model has been suggested for the sake of a consistency of code format as well as convenience of application in practical design, for which the uncertainties associated with buoyancy and its own weight can be taken into account straightforwardly. Furthermore, design criteria equation has been derived by considering accurately the effect of uplift pressure, so that the cross sections of caissons can be assessed which must be safe against the sliding failure. It has been found that cross sections estimated from partial safety factors proposed in this paper are in very good agreement with the results of Level II AFDA and Level III MCS under the same target probability of failure. However, partial safety factors of the Technical Standards and Commentaries for Port and Harbour Facilities in Japan and Coastal Engineering Manual in USA tend to estimate much bigger or smaller cross sections in comparison to the present results. Finally, many reliability re-analyses have been performed in order to conform whether the stability level of cross section estimated by Level I reliability-based design method is satisfied with the target probability of failure of partial safety factors or not.

The Urban Spaces and Politics of Hybridity: Repoliticizing the Depoliticized Ethnicity in Los Angeles Koreatown (혼성성의 도시 공간과 정치 : 로스앤젤레스 한인타운에서의 탈정치화된 민족성의 재정치화)

  • Park, Kyong-Hwan
    • Journal of the Korean Geographical Society
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    • v.40 no.5 s.110
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    • pp.473-490
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    • 2005
  • The term hybridity has recently emerged as one of the most popularized leitmotivs in contemporary diasporic and transnational problematics on migrants' nomadic experiences. Especially, in postcolonial politics, hybridity is argued to provide a critical 'third space' on which to challenge discursive boundaries and redescribe power-embedded history However, this paper suggests that the hybrid subject position can be easily articulated in producing new cultural discourse and empowering hegemonic subjects in certain spates. Based on distinguishing the intentional, conscious hybridity from the organic, lived hybridity, this research Intends to investigate the Janus-faced, double-edged nature of the postcolonial politics of hybridity in the case of Los Angeles Koreatown. First, I discuss how a place of organic hybridity in Koreatown can lead to challenging invented and depoliticized ethnicity. At the second half of this paper, 1 focus on understanding the ways in which new Korean American professionals and elites employ the discourse of '1.5 generation' as an intentional hybridity for empowering their own political position at a local scale. I conclusively suggest that hybridity should be a deconstructive strategy to unlearn dominant socio-spatial boundaries rather than bring about the third space as a reterritorialized political position.

Copolymerization of Diethyl ${\alpha}$-Phenylvinyl Phosphate with Acrylonitrile and Maleic Anhydride (디에틸 ${\alpha}$-페닐비닐인산과 아크릴로니트릴 및 말레산무수물의 자유라디칼 혼성중합)

  • Jung-Il Jin;Hong-Ku Shim;Soo-Min Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.287-293
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    • 1983
  • Free radical-initiated copolymerizations of diethyl ${\alpha}$-phenylvinyl phospbate (DEPVP) with acrylonitrile (AN) and maleic anhydride (MAnh) were studied. The monomer reactivity ratios for AN/DEPVP pair, determined at $70^{\circ}C$ in bulk using benzoyl peroxide as an initiator, were;$ r_1(AN) = 0.77, r_2(DEPVP) = 0.002$. The values of the Alfrey-Price constants, Q and e, for DEPVP were calculated to be 0.012 and -1.35, respectively. Free radical-initiated copolymerization of MAnh/DEPVP pair in chloroform at $70^{\circ}C$ produced 1 : 1 alternating copolymers regardless monomer feed composition with the highest copolymerization rate at the molar ratio of MAnh : DEPVP = 7 : 3. The equilibrium constant of a charge-transfer complex between DEPVP and MAnh in deutrated chloroform, determinated at room temperature by transformed Benesi-Hildebrand NMR method, was 0.085 l/mol. The reduced viscosity of copolymers of AN/DEPVP pair decreased as the content of DEPVP units increased, while that of MAnh/DEPVP pair remained more or less constant.

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Preparations and Interfacial Phenomena of Hybrid Composites (Hycom) Containing Wasted Stone Powders and Tire Chips (폐석분과 폐타이어 칩을 충진제로 한 혼성복합재(Hycom)의 제조 및 계면현상 연구)

  • Hwang, Teak-Sung;Cha, Ki-Sik
    • Journal of Adhesion and Interface
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    • v.2 no.1
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    • pp.1-8
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    • 2001
  • In this study, wasted stone powders (WSP) obtained from sludge and Wasted Tire Chips (WTC) as fillers have been used to formulate polymer hybrid composites based on Unsaturated Polyester (UPE) resin. To further enhance not only the interfacial bond between the inorganic filler and the polymer matrix, but also the filler dispersion by wetting the particulate surfaces to uniformly spread the resin during the mixing, silane coupling agent[${\gamma}$-methacryloxy propyl trimethoxy silane (${\gamma}$-MPS)] was used. The influences of organic recycled fillers contents and the concentrations of coupling agent in polymer hybrid composite formulations have been investigated from a mechanical and microstructural point o view through Mercury Porosimeter and SEM.

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