• Title/Summary/Keyword: 합체점

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SPIN REORIENTATION TRANSIT10N OF ULTRATHIN Co FILMS ON ARTIFICIALLY ROUGHENED Pd(111) SINGLE CRYSTAL (블록 공중합체를 이용한 CoCrPt 나노점 배열의 자기적 성질 연구)

  • Jeong, Jong-Ryul;Park, Yong-Sung;Kim, Jong-Hyun;Lee, Jeong-Won;Shin, Sung-Chul
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.78-79
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    • 2002
  • It is well known that surface and interface roughnesses greatly affect the magnetic properties such as magnetic domain structure, magnetization reversal, magnetoresistance, and spin reorientation transition (SRT) of ultrathin magnetic films. Therefore, recent studies focus on artificially roughened surface, since it could be possible to systematically understand the effect of roughness on the magnetic properties as well as to obtain the desirable magnetic properties by artificially creating the surface structure and morphology. (omitted)

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Fabrication of Tungsten Nano Dot by Using Block Copolymer Thin Film (블록 공중합체 박막을 이용한 텅스텐 나노점의 형성)

  • Kang, Gil-Bum;Kim, Seong-Il;Kim, Yeung-Hwan;Park, Min-Chul;Kim, Yong-Tae;Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.13-17
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    • 2006
  • Dense and periodic arrays of holes and tungsten none dots were fabricated on silicon oxide and silicon. The holes were approximately 25 nm wide, 40 nm deep, and 60 nm apart. To obtain nano-size patterns, self-assembling resists were used to produce layer of hexagonally ordered parallel cylinders of polymethylmethacrylate(PMMA) in polystyrene(PS) matrix. The PMMA cylinders were degraded and removed with acetic acid rinse to produce a PS mask for pattern transfer. The silicon oxide was removed by fluorine-based reactive ion etching(RIE). Selectively deposited tungsten nano dots were formed inside nano-sized trench by using a low pressure chemical vapor deposition(LPCVD) method. Tungsten nano dot and trenched silicon sizes were 26 nm and 30 nm, respectively.

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Phase Behavior of Poly(ethylene-co-vinyl alcohol)-Solvent System at High Pressure (고압에서 폴리(에틸렌/비닐 알코올) 공중합체-용매계의 상거동에 관한 연구)

  • Byun, Hun-Soo;Kim, Chong-Bae
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.424-429
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    • 1998
  • Cloud-point data at $230^{\circ}C$ and 1,800 bar are presented for two poly(ethylene-co-vinyl alcohol)(PEVA) copolymers[9.9mol% and 17.8mol% vinyl alcohol(VA)] in ethylene, propane, propylene, n-butane, 1-butene, dimethyl ether(DME), and chlorodifluromethane(CDFM). The static type experimental apparatus with a view cell has been used for the experiment at the high pressure and temperature. The pressure-temperature (P-T) loops of PEVA(9.9mol% VA) copolymer-DME mixtures are presented at copolymer concentrations of 1.4wt% to 20.0wt%. Also, we presented the phase behavior of PEVA(17.8mol% VA) copolymer-DME system at copolymer concentration of 1.9wt% to 6.8wt%. The cloud-point curves for the PEVA copolymers in dimethyl ether showed single phase above 480 bar as a result of the hydrogen bonding between the vinyl alcohol unit and dimethyl ether. The pressure-concentration(P-x) isotherm loops of PEVA(9.9mol% and 17.8mol% VA)-DME system are obtained. The cloud-point curves for PEVA(9.9mol% and 17.8 mol% VA) copolymers andthe ethylene, propane, propylene, n-butane, 1-butene, and CDFM all show negative slopes of phase behavior and are located at pressures below 1,800 bar. For PEVA copolymer-DME system(9.9mol% VA), cloud-point curves show positive slopes that decrease in pressures with decrease in temperature in the temperature range of $80^{\circ}C$ to $160^{\circ}C$.

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Adhesive Properties of Starch-Derived Maltose-Acryl Copolymer (전분 유래 엿당-아크릴 공중합체의 접착물성에 관한 연구)

  • Park, Sung Il;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.135-142
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    • 2020
  • Recently, people's interest in eco-friendly plastics derived from nature to replace petroleum-based plastics is increasing due to environmental problems such as microplastics. In line with this trend, eco-friendly adhesives using natural materials and processes are also being developed in the adhesive field. Among them, maltose is a natural substance derived from starch and is the main component of starch syrup used as a food additive. Due to its lower molecular weight than starch, it is easily soluble in water, and above all, there is a possibility that it can be copolymerized with other monomers through solution polymerization. However, researches related to the application of maltose to adhesives are very rare. In this study, after modifying maltose using acrylic anhydride, the product was analyzed through FT-IR and H-NMR. And the modified maltose was copolymerized with two kinds of acrylic monomers. The synthesized adhesive was applied on the wood and the adhesive performance were investigated.

Fabrication of Si Nano Dots by Using Diblock Copolymer Thin Film (블록 공중합체 박막을 이용한 실리콘 나노점의 형성)

  • Kang, Gil-Bum;Kim, Seong-Il;Kim, Young-Hwan;Park, Min-Chul;Kim, Yong-Tae;Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.2 s.43
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    • pp.17-21
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    • 2007
  • Dense and periodic arrays of holes and Si nano dots were fabricated on silicon substrate. The nanopatterned holes were approximately $15{\sim}40nm$ wide, 40 nm deep and $40{\sim}80\;nm$ apart. To obtain nano-size patterns, self?assembling diblock copolymer were used to produce layer of hexagonaly ordered parallel cylinders of polymethylmethacrylate (PMMA) in polystyrene(PS) matrix. The PMMA cylinders were degraded and removed with acetic acid rinse to produce a PS. $100\;{\AA}-thick$ Au thin film was deposited by using e-beam evaporator. PS template was removed by lift-off process. Arrays of Au nano dots were transferred by using Fluorine-based reactive ion etching(RE). Au nano dots were removed by sulfuric acid. Si nano dots size and height were $30{\sim}70\;nm$ and $10{\sim}20\;nm$ respectively.

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Synthesis and Their Properties of PP Graft Copolymers by E-beam Radiation and Vapor Phase Reaction (전자선 조사 기상 반응에 의한 PP 기재 공중합체의 합성과 특성)

  • 황택성;박진원;이재천
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.287-292
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    • 2002
  • Graft copolymerization of styrene and glycidyl methacrylate (GMA) to the peroxidized polypropylene (PP) fabric with E-beam in $O_2$ atmosphere was carried out in vapor phase with benzoyl peroxide (BPO) as an initiator. The degree of grafting of copolymers was increased with the increase of the reaction temperature and the highest degree of grafting was obtained at $70^{\circ}C$ with styrene, and at $80^{\circ}C$ with GMA. The highest degree of grafting of styrene grafted PP according to reaction time was higher than that of GMA grafted PP. In vapor phase graft polymerization, the degree of grafting of copolymers according to water composition in monomer mixture was effected by the boiling temperature of monomers.

Effect of Nation binder with different equivalent weight on cell performance (이온당량(EW)이 다른 Nafion binder가 고분자 전해질 연료전지의 성능에 미치는 영향)

  • Kim, Kun-Ho;Kim, Hyoung-Juhn;Lim, Tae-Hoon;Lee, Kwan-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.129-132
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    • 2007
  • 고분자 전해질 연료전지의 성능에 영향을 주는 많은 인자들 중에서도 촉매층의 조성과 구조의 최적화는 성능변화에 큰 요인으로 작용 된다. 촉매층내 반응 활성점인 삼상계면을 형성시키기 위해 함침하는 Nafion binder를 anode와 cathode의 두 전극에 이온당량(Equivalent weight, EW)이 동일하게 함침시켜 그 성능을 확인하였다. 그 결과를 토대로 anode와 cathode에 이온당량을 각기 다르게 하여 각각의 전극마다 이온당량이 미치는 영향에 대해서도 살펴보았다. Anode와 cathode의 이온당량을 동일하게 EW1100, EW1000, EW900으로 변화 시켜주었을 경우 이온당량의 물성치가 상대적으로 향상된 EW900의 단위 전지 성능이 가장 우수하였으며, 이온당량이 EW900이었을 때 최적의 Nafion binder 함침량은 EW1100의 Nafion binder 함침량과 동일하였다. Anode와 cathode에 함침하는 Nafion binder의 이온당량을 각각 EW1100과 EW900, EW900과 EW1100으로 MEA를 제조하여 전극에 따라 이용당량이 미치는 영향을 살펴보았다.

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Preparation and Their Properties of Hot-Melt Adhesive using Styrene Block Copolymer and Petroleum Resin (스타이렌 블록 공중합체(SBC)와 석유수지를 이용하여 제조한 핫멜트 접착제의 제조 및 특성)

  • Jeong, Booyoung;Cheon, Jungmi;Yoo, Chongsun;Chun, Jeahwan
    • Journal of Adhesion and Interface
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    • v.9 no.4
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    • pp.12-16
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    • 2008
  • Hot-melt adhesive was solid phase in room temperature as 100% solid contents. So it has advantage which attach to substrate with the low pressure heat, fast adhesion speed and environment friendly. In this study, We studied about the effect of a kind of SBS resin and petroleum resin as a tackifier resin and their ratio for hot-melt adhesive on properties. The styrene and $C_9$ resin contents in hot-melt adhesive was increased with increasing viscosity, tensile strength, peel strength and thermal resistance.

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Development of In-Core Fuel Management Scoping Tools for PWR (가압경수로의 노심내 핵연료관리용 탐색도구의 개발)

  • Kim, Chang-Hyo;Kim, Teak-Kyum
    • Nuclear Engineering and Technology
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    • v.25 no.1
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    • pp.20-27
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    • 1993
  • This paper concerns with developing a simplified in-core fuel management scoping tool for PWR. For this purpose the point reactivity model is put into a fuel cycling decision code, FCYPRM. Modified Borresen's coarse-mesh diffusion theory and nodal expansion method are utilized to form a spatial neutron analysis code, CMSNAP. Numerical experiments are per- formed to determine a set of empirical shuffling rules for working out an automated fuel loading pattern search code, ALPS. The numerical examples are presented for verifying effectiveness and applicability of individual codes. By structuring and applying three codes for reload core design problem of a PWR, it is demonstrated that these codes provide an effective in-core fuel management scoping tool for PWR.

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Effect of Monomer on Crosslinking Properties of Acrylic Pressure-Sensitive Adhesives (아크릴계 점착제의 제조와 가교물성에 대한 모노머의 영향)

  • Kim, Pan Soo;Lee, Won-Ki
    • Journal of Adhesion and Interface
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    • v.17 no.2
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    • pp.56-61
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    • 2016
  • This study was to investigate the effect of main monomer, butyl acrylate instead of 2-ethylhexyl acrylate, of acrylic PSAs on adhesive properties. The copolymers of butyl acrylate, acrylic acid and 2-hydroxyethyl acrylate were synthesized and their adhesive properties were investigated after crosslinking with two different agents. Comparing to 2-hydroxyethyl acrylate-based one which has branch-like side groups, butyl acrylate-based PSA with linear side groups show poor adhesive properties. In case of crosslinking agent, epoxy-typed agent than isocyanate-typed one showed better properties than isocyanate-typed one because epoxy-typed agent has more crosslinking sites and produces more flexible bonds, ester and ether, than isocynate-typed one. Most adhesive properties of PSAs were increased with acid content.