• Membrane Journal
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• v.26 no.5
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• pp.381-390
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• 2016

In this study, the natural mordenite (MOR) zeolite seeds were used for the synthesis of high purity mordenite crystals. The effect of seed concentration and crystallization time on the phase purity and surface morphology of MOR crystals has also been reported. The diffraction, elemental and scanning analysis of MOR zeolite particles obtained from 100 g hydrothermal solution batch containing 3 g natural seed, hydrothermally treated at $140^{\circ}C$ for 72 h reveal the high phase-purity of as-synthesized sample having crystals of uniform size ($1-2{\mu}m$). Moreover, high seed concentration leads to the production of mesoporous MOR particles composed of needle shape primary nano crystallites. The gases adsorption performances of as-synthesized MOR particle were carried out at $25^{\circ}C$ and 0-1 bar. Surprisingly, MOR particles show good adsorption potential for $CO_2$ (97.19 mg/g) compared to other gases. Thus it confirms that high purity MOR particles can be synthesized without using any organic template which gives an advantage of separation performance at lower price.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.7
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• pp.603-610
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• 2016

This paper describes experimental results about emission and NOx reduction of dilution effect (Nitrogen and carbon dioxide) about various fuel compositions of synthetic natural gas (SNG). Combustion experiment was performed to investigate the combustion characteristics for SNG with various hydrogen ratio in SNG, heat input and equivalence ratio in a partially premixed model gas turbine combustor. NOx emission was similar to each hydrogen ratio and flame characteristics was investigated from OH chemiluminescence images. There was a singularity of CO emission in stoichiometric condition and it can be identified using OH chemiluminescence intensity. In addition, dilution effect was studied in using nitrogen and carbon dioxide as diluent to reduce the NOx emission. Carbon dioxide diluent was more effective to NOx reduction than nitrogen diluent because of its high diluent specific heat and its heat capacity.

• Journal of the Korean Institute of Gas
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• v.18 no.3
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• pp.60-66
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• 2014

In this study, the overseas failure frequency data of the high-pressure gas pipeline were investigated to apply QRA of high-pressure gas pipeline. The typical overseas failure frequency data of high-pressure gas pipeline are DOT of United States, EGIG of Europe, and UKOPA of United Kingdom (UK). Comparative analysis of these data was shown that EGIG data was suitable for the situation in Korea. In order to apply QRA of high-pressure gas pipeline, non-linear regression analysis using the failure frequency data in the report of EGIG 8th was performed. In the future, intensive researches are required for the external interference because about 50% of the failure frequency of all incidents is the external interference, and for combining of domestic and overseas data.

• Journal of Conservation Science
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• v.31 no.4
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• pp.443-455
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• 2015

To verifying the stability of Natural pigments for Dancheong which is available on the market was carried out as light resistance and gas corrosion test. In this particular case, we will confirm the characteristics of the only pigments except of Dancheong technique and influence of substance. Medium using for coloring are animal glue and synthetic resin that widely used for Dancheong in currently. Selected to artificial light source is a xenon arc lamp, contaminated gas is nitrogen dioxide gas in experiment. Degree of degradation of pigment were compared by measuring the degree of color change. The result of light resistance test, mineral pigments were good; color is green and blue type, soil pigments also good; color is yellow ocher, white clay, red clay etc. Gamboge, unghwang, cinnabar, red lead were confirmed not good. The result of gas corrosion test, most of the natural pigments were good condition except the red lead. Generally, animal glue samples had better than a synthetic resin samples.

• Journal of the Korean Institute of Gas
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• v.16 no.5
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• pp.66-75
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• 2012

Polyurethane foams were synthesized by substituting a portion of petroleum base polyether polyol with castor oil-derived polyol(COP). Contact angle tester and surface tensionmeter were used to examine the compatibility of petroleum base polyether polyol and COP. To investigate the optimum content of COP and surfactant, the content of COP has been changed from 0 wt% to 80 wt%. From the results of polyurethane foams synthesized by surfactant L-580K, DC-5950 and BF-2470, the best mechanical properties was observed when the content of COP was 30wt% and surfactant BF-2470.

• Journal of Hydrogen and New Energy
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• v.22 no.2
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• pp.249-256
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• 2011

In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~$350^{\circ}C$, $H_2$/CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 $ml/g_{-cat{\cdot}}{\cdot}h$. It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of $NiAl_2O_4$ structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of $Ni_3C$ during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1086-1092
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• 2012

In this study, kinetic studies and analysis of the produced syngas were conducted for low rank coal gasification under $CO_2$ atmosphere. 6 coals were analyzed to measure amount of sulfur and ash by proximate and ultimate analyses. And then they were analyzed to select suitable sample by using Thermogravimetric analyzer (TGA). Selected coal sample Samhwa was mixed with catalysts. Mixed samples with catalysts were used to get activation energy under $CO_2$ atmosphere by using Kissinger's method and shrinking core model (SCM). Also, analysis of produced syngas was performed by Gas Chromatography (GC). In this experiment, activation of the $K_2CO_3$ was the best performance, and result of the analysis of the syngas showed similar trend with result of the activation energy.

• Journal of Hydrogen and New Energy
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• v.25 no.3
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• pp.247-254
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.3
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• pp.15-21
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• 2011

With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

• Clean Technology
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• v.19 no.2
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• pp.156-164
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• 2013

In this study, we analyzed the operational characteristics of a 0.25 MW methanation pilot plant. Isothermal reactor controled the heat released from methanation reaction by saturated water in shell side. Methanation process consisting of isothermal reactor and adiabatic reactor had advantages with no recycle compressor and more less reactors compared with methanation process with only adiabatic reactors. In case that $H_2$/CO ratio of syngas was under 3, carbon deposition occurred on catalyst in tube side of isothermal reactor and the pressure of reactors increased. In case that $H_2$/CO ratio was maintained around 3, no carbon deposition on catalyst in tube side of isothermal reactor was found by monitoring the differential pressure of reactors and by measuring the differential pressure of several of tubes filled with catalyst before and after operating. It was shown that CO conversion and $CH_4$selectivity were over 99, 97%, respectively, and the maximum $CH_4$productivity was $695ml/h{\cdot}g-cat$.