• 제목/요약/키워드: 합성율

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Quantitative structure-activity relationship of N-substituted phenyl 5-chloro-1,3-dimethylpyrazol-4-carboxamides (N-치환 phenyl 5-chloro-1,3-dimethylpyrazole-4-carboxamide의 정량적구조활성상관관계)

  • Kim, Yong-Whan;Park, Chang-Kyu
    • Applied Biological Chemistry
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    • v.35 no.5
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    • pp.382-388
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    • 1992
  • Mycelial growth inhibition activity of forty-one N-substituted phenyl 5-chloro-1,3-dimethylpyrazole-4-carboxamides against Rhizoctonia solani was analysed quantitatively by multiple regression analysis using physicochemical parameters of substituents as independent variables and $pEC_{50}$ as dependent variable. As a result, a quantitative structure-activity relationship was formulated using eight physicochemical parameters, which explains 83% of variance of the fungicidal activity. The most important parameter for the biological activity was log k', as related to the penetration and transport processes in the biological system. The activity also correlated with other hydrophobic parameters$({\pi}_2,\;{\pi}_3)$, an electronic parameter$({\Sigma}{\sigma})$, and steric parameters$(STERIMOL\;parameters\;L_3,\;L_4)$.

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Extraction of Optimal Interest Points for Shape-based Image Classification (모양 기반 이미지 분류를 위한 최적의 우세점 추출)

  • 조성택;엄기현
    • Journal of KIISE:Databases
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    • v.30 no.4
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    • pp.362-371
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    • 2003
  • In this paper, we propose an optimal interest point extraction method to support shape-base image classification and indexing for image database by applying a dynamic threshold that reflects the characteristics of the shape contour. The threshold is determined dynamically by comparing the contour length ratio of the original shape and the approximated polygon while the algorithm is running. Because our algorithm considers the characteristics of the shape contour, it can minimize the number of interest points. For n points of the contour, the proposed algorithm has O(nlogn) computational cost on an average to extract the number of m optimal interest points. Experiments were performed on the 70 synthetic shapes of 7 different contour types and 1100 fish shapes. It shows the average optimization ratio up to 0.92 and has 14% improvement, compared to the fixed threshold method. The shape features extracted from our proposed method can be used for shape-based image classification, indexing, and similarity search via normalization.

Effect of $N_2$ and $O_2$ Properties of STS304 Stainless Steel Films Synthesized by Unbalanced Magnetron Sputtering Process (비대칭 마그네트론 스퍼터링법에 의해 합성된 STR304 스테인리스강 박막에서의 질소와 산소의 첨가 효가)

  • 김광석;이상율;김범석;한전건
    • Journal of the Korean institute of surface engineering
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    • v.34 no.2
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    • pp.89-96
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    • 2001
  • N- or O-doped STS304 stainless films were synthesized by an unbalanced magnetron sputtering process with various argon and reactive gas ($N_2$, $O_2$) mixtures. These films were examined by scanning electron microscopy (SEM), X-ray diffraction (XRD), Auger electron spectroscopy (AES) and Knoop microhardness tester. The Results from X-ray diffraction (XRD) analysis showed that a STS304 stainless steel film synthesized without reactive gas using a bulk STS304 stainless steel target had a ferrite bcc structure ($\alpha$ phase), while the N-doped STS304 stainless film was consisted of a nitrogen supersaturated fcc structure, which hsa a strong ${\gamma}$(200) phase. In the O-doped films, oxide Phases ($Fe_2$$O_3$ and $Cr_2$$O_3$) were observed from the films synthesized under an excess $O_2$ flow rate of 9sccm. AES analysis showed that nitrogen content in N-doped films increased as the nitrogen flow rate increased. Approximately 43 at.%N in the N-doped film was measured using a nitrogen flow rate of 8sccm. In O-doped film, approximately 15 at.%O was detected using a $O_2$ flow rate of 12sccm. the Knoop microhardness value of N-doped film using a nitrogen flow rate of 8 sccm was measured to be approximately $H_{ k}$ 1200 and this high value could be attributed to the fine grain size and increased residual stress in the N-doped film.

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A basic study on the recovery of Ni, Cu, Fe, Zn ions from wastewater with the spent catalyst (폐산화철촉매에 의한 폐수중 Ni, Cu, Fe, Zn이온 회수에 관한 기초연구)

  • Lee Hyo Sook;Oh Yeung Soon;Lee Woo Chul
    • Resources Recycling
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    • v.13 no.2
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    • pp.3-8
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    • 2004
  • A basic study on the recovery of heavy metals such as Zn, Ni, Cu and Fe ions from wastewater was carried out with the spent iron oxide catalyst, which was used in the Styrene Monomer(SM) production company. The heavy metals could be recovered more than 98% with the spent iron oxide catalyst. The alkaline components of the spent catalyst could be precipitated the metal ions of the wastewater as metal hydroxides at the higher pH 10.6 in Ni, pH 8.0 in Cu, pH 6.5 in Fe, pH 8.5 in Zn. But the metal ions are adsorbed physically on the surface of the spent catalyst in the range of the pH of the metal hydroxides and pH 3.0, which is the isoelectric point of the iron oxide catalyst.

CMP Properties of ZnO thin film deposited by RF magnetron sputtering (RF-sputtering에 의해 제작된 ZnO박막의 연마특성)

  • Choi, Gwon-Woo;Han, Sang-Jun;Lee, Woo-Sun;Park, Sung-Woo;Jung, Pan-Geom;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.166-166
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    • 2007
  • ZnO는 육방정계(wurtzite) 결정구조를 지니며 상온에서 3.37eV의 wide band gap을 갖는다. ZnO의 엑시톤 결합 에너지는 GaN에 비해 2.5배 높은 60meV로서 고효율의 광소자 적용 가능성이 높다. 또한 고품위의 박막합성이 가능하다. 이러한 특성 때문에 display소자의 투명전극, 광전소자, 바리스터, 압전소자, 가스센서 등에 폭 넓게 응용되고 있다. ZnO박막의 제조는 스퍼터링, CVD, 진공증착법, 열분해법 등이 있다. 본 논문에서는 RF 마그네트론 스퍼터에 의해 제작된 ZnO 박막에 CMP공정을 수행하여 연마율과 비균일도 특성 및 광투과 특성을 연구하였다. ZnO박막은 $2{\times}2Cm$의 Corning glass위에 증착되었다. 로터리 펌프와 유확산 펌프를 이용하여 초기진공을 $2{\times}10^{-6}$ Torr까지 도달시킨 후 Ar과 $O_2$를 주입하였다. 증착은 상온에서 이루어졌으며 공정압력은 $6{\times}10^{-2}$Torr이였다. 초기의 불안정한 상태의 풀라즈마를 안정시키기 위해 셔터를 이용하여 pre-sputtering을 하였다. CMP 공정조건은 플레이튼 속도, 슬러리 유속, 압력은 칵각 60rpm, 90ml/min, $300g/cm^2$으로 일정하게 유지하였으며 헤드속도는 20rpm에서 100rpm까지 증가시키면서 연마특성을 조사하였다. 실리카슬러리의 적합성을 알아보기 위해 DIW와 병행하여 CMP공정을 수행하고 비교 분석하였다. CMP공정 결과 광투과도는 굉탄화된 표면의 확보로 인해 향상된 특성을 보였다. 실리카 슬러리를 사용하여 CMP를 할 경우는 헤드속도는 저속으로 하여야 양호한 연마특성을 얻을 수 있었다.

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Preparation and Characterization of the $H_3PO_4$-doped Sulfonated Poly(aryl ether benzimidazole) Membrane for Polymer Electrolyte Membrane Fuel Cell (고분자전해질 연료전지용 인산 도핑 술폰화 폴리아릴에테르벤즈이미다졸 고분자전해질 막의 제조 및 특성)

  • Hong, Young-Taik;Jeong, Jin-Ju;Yoon, Kyung-Sock;Choi, Jun-Kyu;Kim, Young-Jun
    • Membrane Journal
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    • v.16 no.4
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    • pp.276-285
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    • 2006
  • Acid-doped sulfonated poly(aryl ether benzimidazole) (S-PAEBI) copolymers were synthesized by a direct polymerization technique and a doping with phosphoric acid as a dopant, and the polymer electrolyte membranes were fabricated from them by a solution casting method. To optimize the reaction condition, the degree of sulfonation and doping level were varied in the ranges of $0{\sim}60%\;and\;0.7{\sim}5.7$, respectively. Physiochemical properties of the doped membranes were investigated by AFM, TGA and the measurement of proton conductivity. It was found that proton conductivities depend on doping levels of membranes. Conductivity determined at the condition of $130^{\circ}C$ and no humidity was $7.3{\times}10^{-2}S/cm$ for the $H_3PO_4$-doped PAEBI membrane with a doping level of 5.7.

Fabrication of Porous Mullite by Reaction Sintering (반응소결을 통한 다공성 뮬라이트의 제조)

  • Gang, Jong-Bong;Jo, Beom-Rae
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.630-634
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    • 1999
  • Porous mullites were fabricated using $Al(OH)_3$ and amorphous $SiO_2$ as starting materials by reaction sintering method. The molar ratios of alumina and silica varied from stoichiometric mullite composition to silica-rich and alumina-rich compositions. $AlF_3$ of 0, 1, 5, 10 wt% wad added to each composition, and the effects of composition and the additive for the formation of mullite were examined. The temperature of mullite formation decreased as the amount of $AlF_3$ increased, and themullite phase was formed in the stoichiometric composition in addition of 5 wt% $AlF_3$ at $1250^{\circ}C$ and porous whiskered mullite were synthesized in the sample sintered at $1300^{\circ}C$ and higher temperature. The effect of temperature on the mullite formation was not observed for the sample with 5 wt% or higher content of $AlF_3$, and the body showed little contraction after sintering.

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Design & Fabrication of a Feedforward Power Amplifier for 900 MHz Band RFID Readers (900 MHz 대역 RFID 리더기용 Feedforward형 선형 전력 증폭기 설계 및 제작)

  • Jung, Byoung-Hee;Chae, Gyu-Sung;Kim, Chang-Woo
    • Journal of Advanced Navigation Technology
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    • v.8 no.2
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    • pp.184-190
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    • 2004
  • A feedforward linear power amplifier (FLPA) has been developed for UHF-band RFID reader applications. The main and error amplifiers are composed of a 2 stage so that linearity of the FLPA can be improved. The FLPA has been implemented on an FR-4 substrate (Er=4.7 and thickness=0.8 mm) with 3-dB and 10-dB hybrid couplers for input/output power divider and combiner. For 2-tone measurement (input level=-11 dBm at $f_1$=915 MHz and $f_2$=916 MHz), the FLPA exhibits a -18.52 dBm of $IMD_3$, which indicates that $IMD_3$ cancellation with feedforward loop is more than 27 dB. From 890 to 960 MHz, 1-dB gain compression output power and power gain of the FLPA are higher than 30 dBm and 40 dB, respectively.

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Discretization of Numerical Attributes and Approximate Reasoning by using Rough Membership Function) (러프 소속 함수를 이용한 수치 속성의 이산화와 근사 추론)

  • Kwon, Eun-Ah;Kim, Hong-Gi
    • Journal of KIISE:Databases
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    • v.28 no.4
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    • pp.545-557
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    • 2001
  • In this paper we propose a hierarchical classification algorithm based on rough membership function which can reason a new object approximately. We use the fuzzy reasoning method that substitutes fuzzy membership value for linguistic uncertainty and reason approximately based on the composition of membership values of conditional sttributes Here we use the rough membership function instead of the fuzzy membership function It can reduce the process that the fuzzy algorithm using fuzzy membership function produces fuzzy rules In addition, we transform the information system to the understandable minimal decision information system In order to do we, study the discretization of continuous valued attributes and propose the discretization algorithm based on the rough membership function and the entropy of the information theory The test shows a good partition that produce the smaller decision system We experimented the IRIS data etc. using our proposed algorithm The experimental results with IRIS data shows 96%~98% rate of classification.

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Antioxidant and Antimicrobial Activities of The Extracts from Native Camellia japonica in Korea (국내 자생 동백나무(Camellia japonica L.) 추출물의 항산화 및 항미생물 활성)

  • 이숙영;김선민;황은주;표병식
    • Korean Journal of Plant Resources
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    • v.17 no.3
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    • pp.314-322
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    • 2004
  • This research has been undertaken to increase availiability of native Camellia japonica leaf and flower in Korea as a edible-medicinal resource. Chemical compositions, antioxidant and antimicrobial activities in different parts of camellia were investigated. Crude protein contained the highest in young leaves(14.22%) but less than 10% in different parts. The contents of crude fat and crude ash were 60.48% in seeds and 5.16% in mature leaves, respectively. Methanol extract of young leaf, flower, and flower bud in camellia showed strong antioxidant activity compared with different parts. Also, antioxidant activity of these was higher than that of BHT, but weaker than that of VtC. Antioxidant activity of various parts in camellia were in order of young leaf > flower bud > flower > mature leaf > stem > bark. Extracts of mature leaf and bark had a remarkable antibacterial activity(0 CFU/$m\ell$) on Bacillus subtilis. The young leaf extract displayed effective growth inhibition against B. subtilis, Candida albicans, and Trichosporon beigelii.