• Journal of the Korean Institute of Gas
• /
• v.19 no.6
• /
• pp.8-14
• /
• 2015

Synthetic natural gas(SNG), acquired from coal, is regarded as an alternative to natural gas since a rise in natural gas due to high oil price can be coped with it. In the present study, 11-liter heavy duty compressed natural gas(CNG) engine was employed in order to examine the combustion and emission characteristics of SNG. The simulated SNG, made up 90.95% of methane, 6.05% propane and 3% hydrogen was used in the experiment. Power output, thermal efficiency, combustion stability and emission characteristics were compared to those with CNG at the same engine operating conditions. Knocking phenomenon was also analyzed at 1260 rpm, full load condition. Combustion with SNG was more stable than CNG. Nitrogen oxides emissions increased while Carbon dioxides emissions decreased. Anti-knocking characteristics were improved with SNG.

• Clean Technology
• /
• v.19 no.1
• /
• pp.59-64
• /
• 2013

Pt/carbon Electrode catalysts for PEMFC were synthesized using colloidal method. PSA (platinum sulfite acid) was used as a Pt precursor and CPA (chloroplatinic acid) was also used to replace relatively expensive PSA. Electrode catalysts prepared using PSA showed Pt particle size less than 3.5 nm and Pt yield higher than 90% in 10~40 wt% Pt loading. Electrode catalysts prepared using CPA also showed Pt particle size less than 4.4 nm and Pt yield higher than 80% in 10~40 wt% Pt loading. The MEA (membrane electrode assembly) using 20 wt% Pt/VXC72 showed equivalent I-V curve comparing with commercial electrode catalyst in single cell test.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.05a
• /
• pp.202-205
• /
• 2006

Some advanced nations have already developed and utilized high performance carbocyclic compounds as liquid fuel components. The common point of these compounds includes polycycles. We synthesized some promising compounds which include multiplex ring form. According to three kinds of cyclopropanation method, we could synthesize five target materials and measure their physical properties.

• Applied Chemistry for Engineering
• /
• v.17 no.2
• /
• pp.125-131
• /
• 2006

Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, biomass and spent plastic. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. Therefore, it is considered as an excellent substitute fuel for LPG, fuel cells, power plant, and especially diesel and is expected to be the alternative fuel by 2010. The experimental study of the direct synthesis of DME was investigated under various conditions over a temperature range of $220{\sim}280^{\circ}C$, syngas ratio 1.2~3.0. All experiments were carried out with a hybrid catalyst, composed of a methanol synthesis catalyst ($Cu/ZnO/Al_2O_3$) and a dehydration catalyst (${\gamma}-Al_2O_3$). The observed reaction rate follows qualitatively a Langmiur-Hinshellwood model as the reaction mechanism. Such a mechanism is considered with three reactions; methanol synthesis, methanol dehydration and water gas shift reaction. From a surface reaction with dissociative adsorption of hydrogen, methanol, and water, individual reaction rate was determined.

• Membrane Journal
• /
• v.33 no.3
• /
• pp.137-147
• /
• 2023

In this study, Br-PPO was developed by applying additive organic particles through a suspension polymerization synthesis method. The anion exchange membrane fuel cell system performance was evaluated using it to an anion exchange membrane. To improve the performance, organic ion exchange particles were prepared and added to the anion exchange membrane. Chemical structure analysis and synthesis were determined through FT-IR and NMR, and tensile strength and thermal stability were measured through TGA and UTM to determine whether it could be driven. Before the anion exchange membrane fuel cell test, the performance was evaluated by measuring the ion conductivity and ion exchange capacity. Finally, the Br-PPO-TMA-SDV (0.7%) anion exchange membrane with excellent ion conductivity and ion exchange capacity was introduced into the fuel cell system. Its performance was compared with FAA-3-50, a commercial membrane, to determine whether it could be introduced into a fuel cell system.

• Clean Technology
• /
• v.26 no.4
• /
• pp.329-335
• /
• 2020

Methanol synthesized from renewable hydrogen and captured CO2 has recently attracted great interest as a sustainable energy carrier for large-scale renewable energy storage. In this study, molten carbonate fuel cell's performance was investigated with the direct conversion of methanol into syngas inside the anode chamber of the cell. The internal reforming of methanol may significantly improve system efficiency since the heat generated from the electrochemical reaction can be used directly for the endothermic reforming reaction. The porous Ni-10 wt%Cr anode was sufficient for the methanol steam reforming reaction under the fuel cell operating condition. The direct supply of methanol into the anode chamber resulted in somewhat lower cell performance, especially at high current density. Recycling of the product gas into the anode gas inlet significantly improved the cell performance. The analysis based on material balance revealed that, with increasing current density and gas recycling ratio, the methanol steam reforming reaction rate likewise increased. A methanol conversion more significant than 90% was achieved with gas recycling. The results showed the feasibility of electricity and syngas co-production using the molten carbonate fuel cell. Further research is needed to optimize the fuel cell operating conditions for simultaneous production of electricity and syngas, considering both material and energy balances in the fuel cell.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1994.05a
• /
• pp.78-85
• /
• 1994

ASPEN(Advanced System Process ENgineering) 코드를 이용하여 오리멀젼(orimulsion)을 이용한 가스화기의 성능을 예측하고, 발전 연료로서의 적합성 등을 살펴보았다. 오리멀젼은 역청(bitumen)에 물을 섞은 연료로 중유와 석탄의 중간 정도의 성질을 가지고 있다. 본 연구에서는 오리멀젼 가스화기의 운전 특성을 파악하고 주입되는 산화제 양을 변화시켜 산화제의 가스화기 운전온도에 미치는 영향과 생성되는 주요 합성가스 성분에 미치는 영향 등을 예측하고 새로운 연료로서의 타당성 여부를 검토하였다.

• The Journal of Engineering Research
• /
• v.2 no.1
• /
• pp.133-138
• /
• 1997

The conventional process in synthesizing mullite powder required high temperature ($1300^{\circ}C$) and long chemical reaction time. Thus the combustion process was used to synthesize the mullite powder in order to reduce the reaction time and temperature. The mixture of metal nitrate, fine silica, and fuel was used as the redox compounds under various experimental conditions. The combustion fire in hot plate experiment in rich, lean and stoichiometry fuel does not produce mullite. However, the obvious mullite, small amount of alumina and cristobalite was observed in the $500^{\circ}C$ pre-heat treatment furnace experiment. The components such as silica, urea, aluminm nitrate should be stoichiometry in order to make a perfect mullite crystal.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.143-143
• /
• 2010

GTL(Gas-to-Liquids)공정 중 합성가스 제조공정(Reforming Process)인 ATR(Auto-Thermal Reforming), SCR(Steam Carbon Reforming), POx(Partial Oxidation)의 시뮬레이션 연구를 수행하였다. Reforming 공정에서 생산된 합성가스는 GTL 합성유 제조공정인 FT(Fischer-Thropsch) 반응기로 주입되며, 합성유 생산에 최적의 효율을 보이는 H2/CO 비(합성가스에 포함된 반응물비)는 2.0으로 알려져 있다. FT공정은 합성가스를 원료로 고온 및 고압 반응을 거쳐 GTL 공정의 최종 생산품인 FT합성유를 제조하는 공정이다. 본 연구에서는 FT공정 효율 극대화를 위해 reforming 공정에서 생성되는 합성가스 내 H2/CO의 비를 2로 수렴토록 모사조건을 설정하였으며, 상기 조건을 만족하는 reforming 공정들의 운전 온도 및 feed 조성을 분석하고 비교하고자 한다. 현재 GTL 플랜트관련 산업계에 적용 혹은 주 연구대상인 reforming 공정으로는 ATR, SCR, POx 공정이 있다. ATR 공정은 $850{\sim}1100^{\circ}C$에서 메탄, 스팀 및 산소를 원료로 활용하여 H2 및 CO를 생산하는 공정으로 발열/흡열 반응이 상존하여 에너지 비용이 낮지만 공정구조 상 열회수설비 및 ASU(Air Separation Unit)이 필요하기에 CAPEX(초기설비 설치비용)가 높은 편이다. SCR공정은 CH4, Steam 및 CO2를 연료로 하기에 이산화탄소가 일정부분 포함된 가스전에도 적용이 가능하나 공정 운전 중 지속적으로 외부에서 열을 공급해야 하기에 에너지 투입비용이 높은편이며, 탄소침적의 문제가 있어 대용량 플랜트에는 적합하지 않다. POx공정은 약 $1,500^{\circ}C$의 고온에서 CH4가 O2에 의해 부분 산화되는 방식으로 촉매가 필요없어 설비비가 타 공정에 비해 저렴하나 생산가스의 H2/CO비가 다소 낮아 전체적인 GTL 공정효율이 저하되는 단점이 있다. 상기 세 공정은 GTL 산업계에서 실증 및 효율증대를 위해 주로 연구되는 공정이기에 본 연구의 분석대상으로 설정하였다. 본 연구에서는 상용공정모사기인 Aspen Plus를 활용하여 reforming 공정별로 FT합성공정의 최적 조건(H2/CO=2)을 만족하는 합성가스 생산조건 분석 및 비교를 수행할 예정이다. 운전조건인 공정 운전온도 및 feed 가스조성 등을 모사하기 위해 합성가스 reforming 공정을 모델링하고 공급유량 및 압력 등의 운전변수는 GTL국책과제 1단계 연구수행 결과를 토대로 선정하고자 한다. GTL공정의 경우, 설비의 운전조건이나 연료가스의 구성 및 유량에 따라 적합한 reforming 공정이 다르기에 본 시뮬레이션 결과를 향후 GTL 플랜트 공정모델 설계시 reforming 공정선정에 참고자료로 활용하고자 한다.

• Proceedings of the KSME Conference
• /
• 2008.11b
• /
• pp.2964-2964
• /
• 2008