• Title/Summary/Keyword: 한국 수화

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The Properties of Internal Temperature of Paste and Concrete according to Component Ratio Variation of Ternary System Cement (3성분계 시멘트의 구성비 변화에 따른 페이스트 및 콘크리트의 내부온도 특성)

  • Kim, Yeon-Seung;Kim, Dong-Hyeok;Jee, Nam-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.797-807
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    • 2008
  • For this study, the semi-adiabatic temperature rising test is accomplished by using ternary system cement (OPC, BFS, FA) reducing temperature crack. Two tests are conducted; one is for the paste test, and the other is for the concrete test. As the results of paste tests, using fly ash is better to reduce hydration temperature than doing blast furnace slag. In the case of the paste mixed ternary system cement, the more fly ash is mixed and the less blast furnace slag is used, the lower the temperature is. The less the mixture ratio of blast furnace slag is and the more the mixture ratio of fly ash is, the later the temperature rising velocity and descending velocity are. Besides, the temperature is lower if water/binder ratio is high. The use of ternary system cement has the retardation effect of temperature rising because the time to reach the maximum temperature is in the order of OPC100, binary system cement, and ternary system cement. From the test, the maximum temperature of concrete used ternary system cement is $8{\sim}11^{\circ}C$ lower than that of concrete used OPC100. Moreover, temperatures rising velocity and descending velocity of ternary system cement range $47{\sim}51%$ and $37{\sim}42%$ compared with OPC100. The specimen of concrete shows remarkable low internal temperature and slow temperature rising velocity and descending velocity compared with the specimen of paste because it is that temperature loss of concrete is much more than paste specimen according to aggregates.

Strength Development and Hardening Mechanism of Alkali Activated Fly Ash Mortar (알카리 활성화에 의한 플라이애쉬 모르타르의 강도 발현 및 경화 메커니즘)

  • Jo, Byung-Wan;Park, Min-Seok;Park, Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.449-458
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    • 2006
  • The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

Experimental Study on the Properties of Solid Material Made by Autoclave Curing according to CaO/SiO2 Ratio and W/B (CaO/SiO2비 및 W/B 변화에 따른 오토클레이브 양생 경화체의 특성에 관한 실험적 연구)

  • Kang, Cheol;Kang, Ki-Woong;Kim, Jin-Man
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.557-563
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    • 2009
  • This study is on the properties of inorganic porous calcium silicate material made from silica powder through the autoclaving curing, the results of this study should be utilized fundamental data for the development of noise reduction porous solid material using siliceous byproduct generated by various manufacture process. For the manufacture of autoclave curing specimen, various calcareous materials used and siliceous materials used silica powder. In this study, properties in density and compressive strength according to the change of W/B and C/S ratio, microscopy for the shape of pore, SEM and XRD for the examination of hydrate after autoclave curing are carried out respectively. The test results shown that the more slurry density decrease, the more W/B increase at the fresh state, this tendency shown similar to in hardened state. Among the specimens of C/S ratio, the compressive strength of C/S ratio of 0.85 gave the highest the compressive strength. In the results of XRD, tobermorite generated by autoclaving curing was created all of specimens regardless of C/S ratio. To ascertain pore structure, we compared with existing porous calcium silicate product(ALC, organic sound absorbing porous material). The results of microscope observation, pore structure of specimen of this study was similar to that of existing inorganic sound absorbing foam concrete. therefore, we could conformed a possibility of sound absorbing porous solid material on the basis of the results.

Analysis of anatoxin-a in aqueous and cyanobacterial samples from korean lakes by liquid chromatography with fluorescence detection (액체크로마토그래피-형광검출법에 의한 호소시료의 아나톡신-a 분석)

  • Lee, In-Jung;Lee, Chul-Gu;Heo, Seong-Nam;Lee, Jae-Gwan
    • Analytical Science and Technology
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    • v.24 no.3
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    • pp.225-230
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    • 2011
  • Anatoxin-a is a cyanobacterial neurotoxin with a high toxicity produced by Anabaena, Aphanizomenon and Oscillatoria. Water bloom, formed by Anabaena has been occurring frequently in Lake Yeongchun. It is need to develop a sensitive method for determination of anatoxin-a to control potential hazard in raw water resources. In this study, we developed a highly sensitive analytical method of anatoxin-a using solid phase extraction (SPE) and high performance liquid chromatography (HPLC) with fluorescence detection. Anatoxin-a was converted into a highly fluorescent derivative using 4-fuoro-7-nitro-2,1,3-benzoxadiazole (NBF-F). The method was evaluated in terms of linearity of calibration curve, recovery and repeatability, and the adequate values were obtained. The method detection limit was $0.034\;{\mu}g/g$ and $0.022\;{\mu}g/L$ for algal and water samples, respectively. The concentrations of anatoxin-a were measured in algal and water samples from Lake Andong, Yeongchun and Daechung and ranged from $0.135\;{\mu}g/g$ to $10.979\;{\mu}g/g$ in algal samples and not detected in water samples.

Evaluation of Feeding Value of Brown Rice in Korean Native Beef Steers (Hanwoo) (한우에 대한 현미의 사료가치 평가)

  • 오영균;김경훈;최창원;강수원;정일병;노환국
    • Journal of Animal Science and Technology
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    • v.48 no.3
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    • pp.393-400
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    • 2006
  • The present study was conducted to evaluate feeding value of brown rice in Korean native beef steers (Hanwoo) fed concentrates and orchardgrass hay (50:50 on a wet basis) as a basal diet. Either 50% or 100% of corn in concentrates was substituted for brown rice, and ruminal fermentation characteristics, in situ degradability of feeds and in vivo digestibility of concentrate were investigated. The digestibility and nutritive values of corn and brown rice feeds were similar, whereas rumen degradability of brown rice was higher than that of corn. Compared with corn-based diets, the brown rice substitution decreased (P<0.05) ruminal NH3-N concentration, but did not affect rumen pH. Total volatile fatty acid content in ruminal digesta for the corn based diet was higher than those for the brown rice-contained diets. The brown rice substitution increased (P<0.05) the ratio of ruminal acetic acid to propionic acid (A/P) compared with corn-contained diets.Present results indicate that corn might nutritionally be substituted for brown rice as cattle feeds. In addition, we expect that relatively high A/P with brown rice may produce affirmative effects in rumen physiological aspect, particularly under the grain based feeding system for beef cattle in Korea.

Risk Assessment of Trifloxystrobin in Chinese Cabbage by Foliar Application and Drenching (경엽 및 관주처리에 따른 배추 중 Trifloxystrobin의 안전성 평가)

  • An, Xue-Hua;Lee, Sang-Bok;An, Wen-Hao;Kim, Jai-Duk;Kim, Sun
    • The Korean Journal of Pesticide Science
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    • v.11 no.1
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    • pp.27-31
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    • 2007
  • Trifloxystrobin standard was analyzed by high performance liquid chromatography (HPLC). The recovery of the trifloxystrobin and it's metabolite CGA321113 were $84.6{\sim}95.3%$ and $86.4{\sim}87.3%$ and their detection limits for both of them were 0.04 mg $kg^{-1}$. In case of foliar application in the chinese cabbage (Brassica campestris L. ssp pekinnensis (Lour.) Rupr.), the amount of the residue of trifloxystrobin was above the maximum residue level (temporary MRL, 0.5 mg $kg^{-1}$) when it was treated either two times three to five days before harvest or three times three to seven days before harvest. Whereas in case of drenching the mount of the residue was below the temporary MRL, the residues in the cabbage in both the cases where the recommended amount (150 mL of the solution diluted 1500 times) and double of the amount were treated were 0.16 and 0.31 mg $kg^{-1}$, respectively. In conclusion, it should be safe to apply the trifloxystrobin (22% WP) in the soil of cabbage field abiding by the tentative recommendation level, but for the foliar application it appeared inappropriate.

Buffer Zones for Non-Target Organisms by Aerial Pesticide Application Around Rice Paddy (벼 재배지의 항공 방제시 비표적 생물에 대한 안전거리)

  • Park, Yeon-Ki;Jin, Yeoung-Duck;Kim, Byung-Seok;Park, Kyung-Hun;Lee, Jea-Bong;Shin, Jin-Sup;Bae, Chung-Han;Lee, Kyu-Seung
    • The Korean Journal of Pesticide Science
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    • v.11 no.1
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    • pp.32-37
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    • 2007
  • The study was carried out to establish buffer zone for the protection of the non-target organisms by aerial pesticide application. The two pesticide combination of 3-way tank-mixing of three pesticides for aerial application, ferimzone tricyclazole SC + BPMC EC + validamycin-A SL and hexaconzole EC + isoprothiolane EC+phenthoate EC were selected for the simultaneous control of key pests on paddy rice as blast, sheath blight, brown planthopper and moth. Aquatic organisms including killifish and loach in the paddy field and nearby water reservoirs were not affected by aerial application of the pesticides. However, all the water flea were killed, when they were exposed 10 m from the aerially sprayed site, while the water flea exposed in 30 m away from the site were not affected. Honeybees within 50 m in the wind direction and 20 m in the opposite wind direction showed a mortality of $7{\sim}100%$. Residues concentration of the pesticides in paddy water were not detectable level after six days from aerial application. Drifting distance of aerially sprayed droplet from the target area was within 30 m in the wind direction and 20 m in the opposite direction. Consequently, it was the buffer zones in the aerial pesticides application for the protection of the non-target organisms should be at least 50 m for aquatic organisms and 100 m for honeybees.

Control Effect of Major Fungal Diseases of Cucumber by Mixing of Biofungicides Registered for Control of Powdery Mildew with Other Control Agents (오이 흰가루병 방제용 미생물농약의 혼용에 의한 오이 주요 곰팡이병의 방제 효과)

  • Kim, Gyoung-Hee;Park, Jae- Young;Cha, Ju-Hoon;Jeon, Chi-Sung;Hong, Sung-Joon;Kim, Young-Ho;Hur, Jae-Seoun;Koh, Young-Jin
    • The Korean Journal of Pesticide Science
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    • v.15 no.3
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    • pp.323-328
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    • 2011
  • Control efficacies of mixing of powdery mildew biofungicides with other control agents against major or fungal diseases of cucumber were investigated. Control efficacies against cucumber powdery mildew were quite different according to the kinds of biofungicides applied but those of powdery mildew biofungicides were increased by mixing application of two biofungicides. More than 80% of control efficacies on powdery and downy mildews of cucumber were obtained by mixing application of a powdery mildew biofungicide Bacillus subtilis KB-401 and a downy mildew chemical fungicide dimethomorph. Similarly, control efficacies on powdery and downy mildews of cucumber were 95% and 70% by mixing application of a powdery mildew biofungicide Bacillus subtilis KB-401 and cooking oils and yolk mixture, respectively.

Dissipation Pattern of Amisulbrom in Cucumber under Greenhouse Condition for Establishing Pre-harvest Residue Limit (생산단계 잔류허용 기준 설정을 위한 시설 재배 오이 중 살균제 Amisulbrom의 잔류특성 연구)

  • Hwang, Kyu-Won;Kim, Tae Wan;Yoo, Jae-Hong;Park, Byeoung-Soo;Moon, Joon-Kwan
    • The Korean Journal of Pesticide Science
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    • v.16 no.4
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    • pp.288-293
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    • 2012
  • The dissipation patterns of amisulbrom in cucumber under a greenhouse condition was investigated to establish biological half-life and pre-harvest residue limit (PHRL). Amisulbrom residue in/on cucumber on the day of application under standard application condition was $0.15mg\;kg^{-1}$ and decreased to $0.06mg\;kg^{-1}$ after 5 days after treatment, so that biological half-life calculated 3.6 day, while initial concentration of amisulbrom twice application 3 days interval under standard application condition was $0.35mg\;kg^{-1}$ and decreased to $0.09mg\;kg^{-1}$ after same period and the biological half-life calculated 2.4 day. PHRL was suggested by prediction curve calculated from the decay constant of amisulbrom at standard rate. For example, $1.83mg\;kg^{-1}$ at 5 days before harvest and $1.03mg\;kg^{-1}$ at 2 days before harvest were suggested.

Controlling Activity of Bacillus subtilis KB-401 against Cucumber Powdery Mildew Caused by Sphaerotheca fusca (오이 흰가루병에 대한 Bacillus subtilis KB-401의 방제 효과)

  • Nam, Myung-Hyeun;Choi, Jae-Pil;Kim, Hyung-Jo;Lee, Jae-Jun;Lim, Keun-Hwan;Kim, Young-Gwon;Kim, Heung-Tae;Jeun, Yong-Chull
    • The Korean Journal of Pesticide Science
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    • v.14 no.1
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    • pp.49-53
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    • 2010
  • Disease control efficacy was evaluated with use of Bacillus subtilis KB-401 against cucumber powdery mildew in a greenhouse and fields. B. subtilis KB-401 showing inhibitory effect on mycelial growth of various phytopathogenic fungi was formulated for the evaluation. The formulated biofungicide of B. subtilis KB-401 was less effective at 1,000 times dilution rate than that at 250 or 500 times dilution rate. The powdery mildew was successfully controlled by the biofungicide at the early stage of disease development. The field performance of the biofungicde was conducted in Asan and Cheonan city. Three or four consecutive applications of the biofungicide at 500 dilution rate with 10-day intervals resulted in considerable efficacy of disease control as high as 83.3%.