• Title/Summary/Keyword: 한계조건

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Analysis of Biurea Decomposed from Azodicarbonamide in Food Products by High Performance Liquid Chromatography Mass/Mass Spectrometry (LC/MS/MS를 이용한 식품 중 아조디카르본아미드 분해산물인 Biurea 함량 분석)

  • Lim, Ho-Soo;Pahn, Kyeong-Nyeo;Kim, Jun-Hyun;Jang, Gui-Hyeon;Moon, Gui-Im;Yang, Hyo-Jin;Park, Sung-Kwan;Park, Hae-Kyong;Kim, So-Hee
    • Korean Journal of Food Science and Technology
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    • v.42 no.4
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    • pp.377-382
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    • 2010
  • This study was conducted to establish a method to analyze biurea decomposed from azodicarbonamide in processed foods such as wheat flour and bread. New method was developed using high performance liquid chromatography mass/mass spectrometry to determine biurea in wheat flour and bakery products. The recovery rate was 94.3-112.5%. The limit of detection for biurea was 0.003 mg/kg, and the limit of quantification was 0.01 mg/kg. The monitoring results for biurea content using established methods showed that biurea was detected at 2.76 mg/kg in the azodicarbonamide-detected flour (detection rate, 2%). The detection rate in processed foods such as baked goods was 27% (16/59). The detection range was 0.19-18.01 mg/kg (average, 3.79 mg/kg). However, it was thought that the detection level was safe due to much lower values than the standard (45 mg/kg). As a result, the newly established biurea analytical method will contribute to the management of azodicarbonamide in processed foods such as wheat flour and bakery products.

Influence of Temperature and Soil moisture affecting the death to Vegetative organs of perennial weeds (답다년생잡초에 대한 영양번식기관의 사멸에 미치는 온도 및 토양분수의 영향)

  • Chang, Yung-Hee;Kusanagi, Tokuichi
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.24 no.1
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    • pp.107-118
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    • 1979
  • The critical low temperature of death under submerged soil was -5^\circ C for the underground tuber of Cyperus serotinus while the vegetative organ (tuber or bulb) of Sagittaria pygmaea and Potamogeton distinctus -6^\circ C, -7^\circ C respectively. On the critical high temperature of death in water bath with 45^\circ C. Potamogeton distinctus and Sagittaria pygmaea were 1 hour, 24 hours, but Cyperus serotinus did not die. When vegetative organs of perenivial weeds setted on the soil surface, the propagation organ of Potamegeton distinctus did not die by desication in 17% of soil moisture, but Cyperus serotinus and Sagittaria pygmaea were dead within 2 to 3 hours in 25^\circ C of soil moisture.

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Wall-Droplet Interaction Modeling and Comparative Study on Deformation Models for the Improvement of Icing Analysis Under SLD Conditions (SLD 조건에서 착빙 해석 정확도 개선을 위한 Wall-Droplet Interaction 수치 모델링 및 Deformation 모델 비교 연구)

  • Bae, Jinkyu;Yee, Kwanjung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.4
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    • pp.255-267
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    • 2020
  • Under SLD conditions, due to the large size of droplets, physical phenomena such as wall-droplet interaction and deformation have a significant effect on the icing process. Accordingly, many studies have been conducted in order to computationally simulate SLD effects. As one of the efforts, post-processing method have been proposed to describe wall-droplet interaction effect, which modified collection efficiency using Wright model. However, since the model doesn't properly consider the wall condition, it still overestimated collection efficiency and impingement limit. To solve this problem, impingement areas were divided into 3 different regions, and the post-processing method was introduced with the new wall-droplet interaction model developed based on Bai and Gosman rebound model. In order to consider the effect of deformation, the most suitable model was selected by comparing the deformation models used in the various icing codes. As a result, the modified post-processing method showed improved accuracy in predicting the impingement limits and collection efficiency by further estimating mass flux loss due to rebound, and it was observed that the result was the closest to the experimental data when the deformation effect was included by using Wiegand model.

Analysis of Azodicarbonamide in Food Products by High Performance Liquid Chromatography (HPLC를 이용한 식품 중 아조디카르본아미드 분석)

  • Lim, Ho-Soo;Bahn, Kyeong-Nyeo;Kim, Jun-Hyun;Jang, Gui-Hyeon;Moon, Gui-Im;Park, Sung-Kwan;Yang, Hyo-Jin;Park, Hae-Kyong;Kim, So-Hee
    • Journal of Food Hygiene and Safety
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    • v.25 no.2
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    • pp.100-105
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    • 2010
  • This study was conducted to establish a method to analyze azodicarbonamide (ADA) in wheat flour. A new method using high performance liquid chromatography (HPLC) was developed for the determination of ADA in wheat flour. The recovery rate was 91.93~97.54%. The limit of detection for ADA was 0.02 mg/kg and the limit of quantification was 0.05 mg/kg. The monitoring results for ADA contents using the established methods showed that it was detected as the low value of 0.95 mg/kg in one of 51 flour samples (detection rate : 2%), but not detected in 59 bakery samples. The detected ADA level was suitable to its usage standard, compared to the standard (45 mg/kg). Although the detection rate was very low, the established analytical method of ADA will contribute to the management of ADA in processed foods such as wheat flour and bakery.

Case histories on design alternatives during excavation of underground LPG storage cavern and traffic tunnel using TSP survey (TSP 탐사를 이용한 지하유류저장공동 및 도로터널의 시공 중 설계변경 사례 고찰)

  • Cha Sung-Soo;Kim Se-Hoon;Yun Sang-Pil;Bae Jung-Sik;Lee Jin-Moo
    • 한국지구물리탐사학회:학술대회논문집
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    • 1999.08a
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    • pp.117-136
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    • 1999
  • The geophysical survey at pre-investigation stage can hardly provide the detailed information on geological structure of site which has difficulty in access and thick overburden. The TSP (VSP applied in tunnel) survey at post-investigation stage can show the detailed geology ahead of tunnel and around cavern. The TSP survey was carried out at the Pyongtaek LPG storage cavern site during the cavern excavation and provided the location and orientation of the fault inferred below Namyangho. In order to confirm the result of TSP survey four boreholes were drilled in access tunnel. The fault was also detected by borehole survey and the location was coincided with the result of TSP survey. Depend on the result of TSP survey and core logging, the design such as cavern layout and length could have been changed. As another case history the TSP survey was performed at the Mumeuje road tunnel which has poor geological information due to thick overburden. The support design was also changed on the base of TSP survey.

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An analysis of hydraulic characteristics of stepped boulder fishway installed in mountain stream (산지하천에 설치된 계단식 전석 어도의 수리 특성 분석)

  • Kim, Ki Heung
    • Journal of Korea Water Resources Association
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    • v.55 no.1
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    • pp.99-109
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    • 2022
  • This study was intended to suggest the applicability of stepped boulder fishway using the concept of traditional boulder weir, focusing on the problems of existing concrete pool-and-weir fishways installed in mountain streams. To achieve this purpose, a stepped boulder fishway was designed and constructed as a pilot project in consideration of ascending capacity of the selected target fishes. Under the given discharge conditions, the hydraulic characteristics of the fishway were investigated in the field, and the characteristics and ascending capacity of the fishes were compared and analyzed. The fishway had a short length and steep slope, but the mean drops between each baffle were the range of 0.15 to 0.29 m, and this range satisfied the limit condition of about 0.40 m, which was in the limit of the drop that target fishes can ascend. The mean velocities of each baffle and pool were 0.82 to 0.87 m/sec and 0.13 to 0.24 m/sec. This result satisfied the conditions of burst speed (10 to 30 times of body length) and mean velocity of the resting pool (7 to 25% of burst speed) for target fishes. Since the bottom surface of the pool formed of boulders had a gentle reverse slope and rotational flow did not occur, the efficiency of fishway can be increased, and it will also be possible to solve the maintenance problem by flushing bed materials.

Trace Measurement of Ruthenium by Adsorptive Stripping Voltammetry (벗김 전압전류법에 의한 루테늄의 미량 측정)

  • Czae, Myung Zoon;Kwon, Young Soon;Kim, So Jin
    • Journal of the Korean Chemical Society
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    • v.41 no.5
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    • pp.246-250
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    • 1997
  • In the presence of optimum amounts of hydroxylamine, trace ruthenium(III) can be conveniently determined in acidic (boric) media by coupling catalytic hydrogen processes with adsorptive accumulation of the catalyst, using differential pulse voltammetry. Cyclic voltammetry was used to characterize the redox and interfacial processes. Optimal experimental conditions were found to be a stirred borate (0.015 M, pH 2.5) solution containing 0.55 M hydroxylamine, a preconcentration potential of - 0.70 V, and a scan rate of 5 mV/s. With a 7 min accumulation period the detection limit was 3${\times}$10-10 M. The possible interferences by other platinum group metals are investigated.

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Influence of average process on components recognition efficiency in agricultural field IR images (농지의 IR 이미지에서 평균 처리가 구성물 인지의 효율성에 미치는 영향)

  • Kim, Won-Kyung;Kim, Deok-keun;Yang, Seung-Hwan
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.174-174
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    • 2017
  • 농지의 구성물을 인식하는 기술은 농작업 기계를 로봇으로 전환하는데 필요한 기술 중 하나이다. 하지만 실외에서는 태양광과 날씨 변화에 따른 광 조건의 변화가 매우 커서 기존의 영상처리 방법으로 구성물을 인지하는데 한계가 있었다. 본 연구에서는 광 조건의 변화에 따른 영향을 줄이는 방안으로 IR 이미지를 이용한 농지 구성물의 인지를 수행하였다. 농지 구성물로는 토양, 식물, 멀칭비닐, 자갈을 선정하였다. 농지의 IR 이미지에서 농지 구성물을 구별하기 위한 픽셀값을 작게 적용하면 미세한 구분은 가능하지만 토양, 식물, 멀칭 비닐 등을 구성물 단위로 구별할 대는 후처리가 필요로 해지는 문제가 발생하였다. 본 연구에서는 IR 영상의 픽셀값을 평균 처리하여 농지 구성물의 인지를 수행 때의 효과를 확인 하였다. 평균 처리하는 픽셀값이 많을수록 처리속도가 빠르고, 작은 노이즈를 제어하는 효과가 있었지만, 픽셀값이 너무 커지면 구조물의 구별 정확도가 떨어졌다. 이 결과를 바탕으로 농지 구성물 인지를 위한 효율적인 IR 이미지 평균 처리 수준을 확인하였다.

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Stripping Voltammetric Determination of Osmium (벗김 전압전류법에 의한 오스뮴 정량)

  • Kwon, Young-Soon;Kim, So-Jin;Czae, Myung-Zoon
    • Analytical Science and Technology
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    • v.10 no.2
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    • pp.114-118
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    • 1997
  • A stripping voltammetric scheme for the determination of osmium, based on the adsorptive accumulation of osmium in the presence of hydroxylamine, was described. Cyclic voltammetry was used to characterize the redox and interfacial processes. Optimal experimental conditions were found to be a stirred 0.05M hydroxylamine hydrochloride solution(pH 1.8), accumulation at -0.65V for 60s, and a differential pulse mode with a scan rate of 10mV/s. The detection limit was $6.3{\times}10^{-8}M$(12ppb) with the optimal condition.

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Adsorptive Stripping Voltammetric Determination of Ruthenium (흡착 벗김법에 의한 루테늄 정량)

  • Hong, Tae-Kee;Kwon, Young-Soon;Czae, Myung-Zoon
    • Analytical Science and Technology
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    • v.10 no.2
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    • pp.119-125
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    • 1997
  • A stripping voltammetric procedure for determining ruthenium was developed, based on the adsorptive accumulation of ruthenium in the presence of hydrazine in acidic acetate buffer. After preconcentration of ruthenium compelex and reduction, the ruthenium-catalyzed hydrogen current at -0.84V was measured by differential pulse voltammetry. Optimal experimental conditions were found to be a stirred acetate buffer solution(pH 2.0) containing 0.01M acetate and 0.01M hydrazine, accumulation potential of -0.76V, and a scan rate of 5mV/s. The detection limit was $2{\times}10^{-9}M$ for a 7 min accumulation period. The possible interferences by other platinum group metals were also investigated.

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