• The Journal of the Petrological Society of Korea
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• v.10 no.3
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• pp.233-245
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• 2001

With the advent of super-conducting magnet, NMR spectroscopy becomes a very important tool in geology as well as in chemistry. $^{29}Si$ and $^{27}Al$ which are the main components of minerals and contain structural informations, are useful major targets for the NMR study in geology, but some other elements including alkali cations such as $^{23}Na$ are also one of them. NMR can be applied to many different fields. For example, it can be applied to study smaller range of structure (in molecular level) than XRD and TEM. NMR provides us with structural informations such as order-disorder in Al and Si distribution, oxygen coordination number, and distribution of other cations. Another important information that we can obtain from NMR is not only the static structural informations, but also the molecular dynamics. This dynamic informations of molecules also enable us to figure out the frequency of molecular motion and activation energy. Structure of amorphous minerals and chemistry and structure of natural organic materials are also studied by NMR.

• Korean Journal of Social Welfare
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• v.59 no.2
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• pp.143-169
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• 2007

The major purpose of this study was to offer a comprehensive analysis of the changing trends and causes of poverty among urban wage earners' households from 1995 to 2005. In order to do that, this study used the micro data of "Income and Expenditure Survey of Urban Households" by the National Statistical Office(NSO) and GEE(Generalized estimating equation) regression model which is know as an appropriate method for the longitudinal and clustering data. The results show that (1) the numbers of poverty rate and poverty gap in recent years are even getting seriously worse than those in the IMF crisis. (2) Main characteristics of poor are female headed, old aged, low educated households, and having atypical working position. (3) Major determinants of poverty are also related to the variables as mentioned the above. (4) However, poverty reduction effect of public transfer increased preferably in recent years.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.9
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• pp.1175-1183
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• 2010

A spacer grid assembly is one of the most important structural components in a Light Water Reactor(LWR) nuclear fuel assembly. In the case of the Zircaloy spacer grid assembly, the primary design consideration is to ensure that lateral dynamic crush strength of the spacer grid assembly is sufficient to resist design basis loads and thereby prevent seismic accidents, without a significant increase in the hydraulic head loss for the reactor coolant in the reactor core. In this study, factors affecting the lateral dynamic crush strength of a spacer grid assembly were analyzed by performing lateral dynamic crush tests and finite element analyses. Further, an effective and economical method to enhance the lateral dynamic crush strength of the spacer grid assembly is proposed.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.371.1-371.1
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• 2014

반도체 트랜지스터의 크기가 점점 미세화 함에 따라 이에 수반되는 절연막에 대한 요구 조건도 까다로워지고 있다. 특히 게이트 산화 막의 두께는 10 nm 이하에서 고밀도를 갖는 높은 유전율 막에 대한 요구가 증가되고 있으며 또한 증착 온도 역시 낮아져야 한다. 이러한 요구사항을 충족하는 기술중의 하나는 매우 낮은 압력 및 200도 이하 저온에서 절연막을 증착하는 것이다. 본 연구에서는 플라즈마 화학 기상 증착(PE-CVD) 시스템을 이용하여 $180^{\circ}C$의 온도 및 10 mTorr의 압력에서 SiN 및 SiCN 박막을 제조하였다. 박막의 특성은 원자층 증착 공정 결과와 유사하면서 증착 속도의 향상을 위해 개조된 사이클릭 화학 기상 증착 공정을 이용하였다. Si 전구체와 산화제는 기판에 공급되기 전에 혼합되어 1차 리간드 분해를 하였으며, 리간드가 일부 제거된 가스가 기판에 흡착되는 구조이다. 기판흡착 후 플라즈마 처리 공정을 이용하여 2차 리간드 분해 공정을 수행하였으며, 반응에 참여하지 않은 가스 제거를 위해 불활성 가스를 이용하여 퍼지 하였다. 공정 변수인 플라즈마 전력, 반응가스유량, 플라즈마 처리 시간은 최적화 되었다. 또한 효율적인 리간드 분해를 위해 ICP와 CCP를 포함하고 있는 이중 플라즈마 시스템에 의해 2회에 걸쳐 분해되어지고, 그 결과로 불순물이 들어있지 않는 순수한 SiN과 SiCN 박막을 증착하였다. XRD 측정 결과 증착된 박막들은 모두 비정질 상이며, 550 nm 파장에서 측정한 SiN 및 SiCN 박막의 굴절률은 각 각 1.801 및 1.795이다. 또한 증착된 박막의 밀도는 2.188 ($g/cm^3$)로서 유전체 박막으로 사용하기에 충분한 값임을 확인하였다. 추가적으로 300 mm 규모의 Si 웨이퍼에서 측정된 비 균일도는 2% 이었다. 저온에서 증착한 SiN 및 SiCN 박막 특성은 고온 공정의 그것과 유사함을 확인하였고, 이는 저온에서의 유전체 박막 증착 공정이 반도체 제조 공정에서 사용 가능하다는 것을 보여준다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.3
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• pp.1259-1264
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• 2014

Hydrogen is in the world limelight for future energy source, and it has been already used in various industry fields including aerospace. The extremely fine molecule of the hydrogen can be easily leaked from tiny size of the crack on the surface of transporting pipes or storage tanks, and it could bring on awfully terrible disaster. In this study, Laser-Induced Breakdown Spectroscopy (LIBS) was employed to develope a reliable detection scheme for a small quantity of hydrogen leakage. Effect of three different metal substrates (i.e. Al, Cu, SUS) on plasma generation and the intensity of the hydrogen atomic signal was investigated, and the surface damage of the substrates due to repetitive laser shots was observed using Scanning electron microscope. It was also evaluated how the surface damage could distort the atomic signal. The intensity of the atomic signal was found to be the strongest, and the signal distortion due to the surface damage was approximately $100W/m^2$ lower when Al was used for the substrate.

• Membrane Journal
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• v.27 no.2
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• pp.121-128
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• 2017

Mesoscale simulation is a type of molecular simulation techniques where groups of atoms are defined as a single bead for calculations, and accordingly, is possible to simulate longer time ($ns{\sim}{\mu}s$) and bigger size ($nm{\sim}{\mu}m$). There are two types of mesoscale simulations : (1) particle-based mesoscale which simulates the system by calculating the movement of the particles themselves and (2) field theory which simulates the system by calculating changes in the chemical potential filed or density field. Mesoscale simulations are powerful tools to study the macroscopic properties of polymers for various applications of energy and environment. In this review, we report the trends and useful information in mesoscale simulation and provide an opportunity for membrane researchers working in the energy-environment field to understand mesoscale simulation techniques.

• Applied Microscopy
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• v.29 no.3
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• pp.265-274
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• 1999

The microstructure of Cu thin films in various deposition conditions was characterized. Cr films (50 nm thick) and Cu films (500 or 1000 nm thick) were deposited on polyimide films by DC magnetron sputtering. The Ar pressure during Cu deposition was controlled to 5, 50 and 100 mtorr. The microstructure was characterized using conventional and high resolution SEM and TEM. As sputtering pressure increases, open boundaries are observed more frequently. The Cu film deposited at 5 mtorr has a dense and uniform structure, while low-density regions or open boundaries between columns exist in the film deposited at higher pressure. As the film grows thicker, open boundaries are wider and the density of open boundaries are higher. The comparison between SEM and TEM show that the small features shown in high resolution SEM are grains. High resolution SEM is very effective to characterize the microstructure of the thin films. One column in the films deposited at 50 and 100 mtorr consists of several grains, which are smaller than those deposited at 5 mtorr.

• Journal of the Korean Chemical Society
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• v.38 no.6
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• pp.411-417
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• 1994

For the analysis of fine ceramics, which is one of the new materials difficult to be dissolved, the methods of sample pretreatments such as alkali fusion and high pressure acid digestion were studied using inductively coupled plasma-atomic emission spectrometer(ICP-AES). For the Al2O3 powder sample, the results from high pressure acid digestion method showed better reproducibility than those obtained by alkali fusion technique. In the case of the analysis of SiC powder using the former method, impurities of the powder in the range of ppm were determined without matrix interference by removing Si as Si-F volatilization. Japan Certified Reference Materials (JCRM022 and JCRM023) were analyzed by this method for ultra fine powder and the results showed high accuracy and good reproducibility.

• Journal of the Korean Chemical Society
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• v.22 no.4
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• pp.202-220
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• 1978

Uniform semiclassical (WKB) solutions are obtained for nonseparable systems without using a close coupling formalism and are given explicitly in terms of well known analytic functions for various physically interesting and realistic cases. They do not become singular at turning points or surfaces and when taken in their asymptotic forms, they reduce to the usual WKB solutions that could be obtained if the Stokes phenomenon was properly taken care of for solutions. In obtaining such uniform solutions, the Schroedinger equations for nonseparable systems are suitably "renormalized" to solvable "normal" forms through certain transformations. Ehrenfest's adiabatic principle plays an important guiding role for obtaining such "renormalized" uniform solutions for nonseparable systems. The eigenvalues of the Hamiltonian can be calculated from the extended Bohr-Sommerfeld quantization rules when appropriate classical trajectories are obtained. An application is made to many-electron systems and for one of the simplest examples to show the utility of the method the approximate wavefunction is calculated of the ground state helium atom.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.523-523
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• 2013

대기압 제트 플라즈마는 의료산업 및 재료공정, 정수, 기체흐름 제어 등 다양한 분야에 적용을 위한 연구가 활발히 진행되고 있다. 뿐만 아니라 구동 조건에 따라 다양한 방전 모드가 존재하며, 이에 따라 발생된 플라즈마의 광학적 및 전기적 특성도 매우 다르게 나타나기 때문에 과학적으로도 새로운 현상들이 속속 발표되고 있다. 대기압 제트 플라즈마에서 중요한 과학적 현상 중 하나인 스트리머(streamer) 혹은 플라즈마 총알(plasma bullet)은 수-수십 kHz의 저주파 전압으로 구동 시 특정 조건에서 발생하는 현상으로, 최근 들어 시간분해능이 높은 ICCD 카메라를 이용하여 스트리머의 발생 및 전파에 대한 새로운 현상의 발견과 다양한 물리적 이해가 시도되고 있다. 본 연구에서는 헬륨 대기압 제트 플라즈마에 포함된 질소 함유량에 따른 다중 스트리머의 발생 및 기작의 이해를 시도하였다. 구동 전압 및 주파수, 헬륨기체의 유량, 전극 구조 및 간격 등 모든 조건이 동일한 상태에서 질소기체의 함유량을 증가시킬수록 특정 영역에서 스트리머의 개수가 증가하는 것을 관찰되었다. 또한 $N_2{^+}$의 방출광 세기가 헬륨 및 산소 원자의 방출광보다 지배적인 것으로 측정되었으며, 이는 헬륨 플라즈마에서 흔히 나타나는 헬륨 metastable에 의한 질소분자의 페닝 이온화(Penning ionization) 때문이다. 본 연구팀은 페닝 이온화($He^*+N_2{\rightarrow}He+N_2{^+}+e$)로 인해 추가적으로 발생하는 전자가 다중 스트리머 발생에 중요한 역할을 하는 것이라 제안한다. 좀 더 심화적인 분석을 하고자 헬륨-질소 플라즈마에서 주된 여러 가지 반응식을 이용하여 페닝 이온화에 의한 이온화율 및 전자의 직접적인 충돌에 의한 질소, 헬륨의 이온화율의 계산을 수행하여 특정 영역에서 헬륨의 이온화율보다 질소 페닝 이온화율이 더 커지는 것을 확인하였다.