• 제목/요약/키워드: 피복층

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Gas Separation by Polyimide.Silica Composite Membrane (폴리이미드/실리카 복합막에 의한 가스분리)

  • 송병준;김건중;남세종
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.71-72
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    • 1997
  • 1. 서론 : 공기중의 산소분리용 고분자막은 높은 선택도를 동시에 요구한다. 이 두가지 조건을 만족시키는 소재 개발과 기존의 고분자물질을 수식하는 연구가 진행되고 있다. 고분자막에 대한 수식방법으로는 UV처리, plasma처리등이 있으나, 이들 방법은 선택도는 증가시키나 투과도를 감소시키는 경향이 있다. 기체의 투과저항을 줄이기 위하여 다공성 지지체 위에 박막을 입힌 복합막과 박막의 skin layer와 sub-layer를 갖는 비대칭막은 투과저항을 줄일수 있으나 선택도는 고분자 고유의 80%정도까지 감소되는 것으로 알려졌다. 본 연구의 목적은 고분자 복합막의 투과분리특성을 향상시키기 위한 것으로 지지층의 세공과 표면에 실리카/고분자를 충전, 피복시켜 투과분리특성을 조사하였다. 현재까지의 연구는 낮은 투과계수와 높은 선택도를 갖는 고분자물질이 사용되었으나, 본 연구에서는 폴리이미드로는 폴리이미드 중에서 투과계수가 가장 높다고 알려진 6FDA-p-TeMPD[{(3,3',4,4'-dicarboxyphenyl)hexafluoropropanedianhydride}-{2,3,5,6-Tetra-methyl-1,4-phenylenediamine}] 폴리이미드를 택하였으며 다공성지지체는 aluminum oxide를 사용하였다 . 본 실험에서는 선택도와 투과속도에 주로 영향을 미치는 폴리이미드와 실리카의 양에 대하여 고찰하였다.

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Oxidation and Fretting Wear Characteristics of Zirconium Alloy Tubes (지르코늄 합금 튜브의 산화와 프레팅 마멸 특성)

  • Chung, Il-Sup;Lee, Ho-Seong;Lee, Myung-Ho
    • Tribology and Lubricants
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    • v.25 no.4
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    • pp.250-255
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    • 2009
  • Oxidation characteristics of Zirlo and Zircaloy-4 tubes, which are widely used as nuclear power fuel cladding, are studied in steam environment up to $1200^{\circ}C$. Oxidation resistances are compared in terms of the mass increase due to the absorption of oxygen. The evolution of microscopic structure accompanied with the oxidation process is investigated. Also, the influence of oxidation on the fretting wear characteristics of the tubes is studied. Piezo-electrically actuated rig is employed to fret the tubes with cross-contacting arrangement. Wear scar is observed and measured, by using microscopes and a 3D-profiler. The results of fretting wear are quantified in terms of scar size, wear volume and wear coefficient, and compared for the three different tube materials of oxidated Zirlo, virgin Zirlo and Zircaloy-4.

Effects of Underlayer (TiN, TiCN) on Transverse Rupture Strength, Bonding Strength and Cutting Tool Life of Cemented Carbide Coated with Titanium Carbide by CVD Process (화학증착(CVD)법에 의한 TiC 증착시 하부층(TiN, TiCN)이 피복 초경합금의 항절력, 접착력 및 공구수명에 미치는 영향)

  • 이건우;오재현;이주완
    • Journal of Surface Science and Engineering
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    • v.25 no.1
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    • pp.16-23
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    • 1992
  • Generally brittle eta phase produced during TiC deposition has a bad effect on the TRS (transverse rupture strength ; thoughness). Therefore it is necessary to reduce eta(η) phase for the improvement of tool life. At this experiment some properties (TRS, bonding strength, tool life, eta phase) have been investigated by inserting TiN or TiCN underlayer between TiC layer and substrate. The results obtained were as fellows; 1. by inserting underlayer eta phase was decreased and TRS was increased, but the bonding strength was decreased. 2. the diffusion of W, Co from the substrate was hindered by the underlayer. 3. TiC layer with TiCN underlayer had the finsest gain size. 4. by inserting underlayer (TiCN or TiN) the tool life was improved and especially notch and crater wear resistance was greatly improved.

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Influence of Corrosion Products on Corrosion Resistance of Al-Mg Coating Films (Al-Mg 코팅막의 부식특성에 대한 부식생성물의 영향)

  • Lee, Seung-Hyo;Kim, Hye-Min;Im, Gyeong-Min;Yun, Yong-Seop;Jeong, Jae-In;Yang, Ji-Hun;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.190-190
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    • 2012
  • 여기서는 5% NaCl 염수분무 환경에 노출된 Al-Mg 다층 코팅막의 부식 거동이 부식생성물 분석을 통하여 평가되었다. 동일 두께의 코팅막이라고 할지라도 Al과 Mg의 코팅층을 다층으로 할수록 내식성이 우수한 경향으로 나타났다. 이때 SEM, EDS 및 XRD 평가 기법을 통하여, 내식성에 기여하는 주요 부식생성물은 수산화알루미늄($Al(OH)_3$)이 지배적인 것으로 확인 되었다. 코팅막이 다층인 경우 차폐(barrier) 특성을 가진 수산화알루미늄이 상대적으로 치밀하게 표면을 피복됨으로써 내식성을 오래도록 유지해 주는 것으로 사료된다.

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Thermal and Mechanical Characteristics of Functionally Graded ZrO$_2$ Thermal Spray Coating (경사기능성 지르코니아 용사피복층의 열 및 기계적특성)

  • 오동현
    • Journal of Surface Science and Engineering
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    • v.31 no.2
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    • pp.91-100
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    • 1998
  • NiCrAlY/YSZ(8wt%$Y_2O_3-ZrO_2$) functionally graded thermal barrier coating (FGC) layers on a Co-base superalloy (HAYNESS 188) substrate were fabstrate were fabicated using Ar shielded single torch air plasma spraying method. Functional grading with the stepwise compositional change throughout layer thickness. Microstructural observation trvealed a successful fabrication of NiCrAlY/YSZ FGC. From the results of the curvature measurement, adhesive strength measurement and thermal shock test for the FGC, it was concluded that the optimum conditions of functionally graded coating layer thinkness and compositional pattern exit to enhance the properties of FGC, which is closely related to the internal residual stess distribution witin it.

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AN EXPERIMENTAL STUDY ON TRACHEAL RECONSTRUCTION USING RIB CARTILAGE AND PERICHONDRIUM IN RABBITS (가토의 자가 늑연골 및 늑연골막을 이용한 기관재건술에 대한 실험적 연구)

  • 채우석;김경래;이형석;안경성;김선곤
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1991.06a
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    • pp.24-24
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    • 1991
  • 기관협착증은 이비인후과 영역에 있어서 치료가 어려운 질환중의 하나로 이의 재건에는 여러가지 자가조직이 각각의 장점에 따라 사용되어 왔지만 완전하고 만족할만한 결과를 얻지 못하는 실정이다. 저자들은 가토의 자가 늑연골 (1군) 및 늑연골막 (2군)을 이용한 기관 재건술을 시행하여 다음과 같은 결과를 얻었다. 1) 이식편은 술후 10주 (1군) 및 12주 (2군)에 흡수나 섬유조직으로의 대치는 없었으며, 기관강의 크기는 직상 하부의 정상기관과 큰 차이가 없었다. 2) 늑연골을 이식한 부위는 연골막의 내세포층에서 연골세포가 분화, 이동되어 절단된 연골사이로 이동하여 새로운 연골을 형성하였다. 3) 늑연골막을 이식한 부위는 연골막에서 형성된 연골세포 및 연골기질이 절단된 연골사이로 이동하여 새로운 연골을 형성하였다. 4)) 이식한 부위의 점막층은 점막재생이 이루어져 원주상피로 피복되었다. 5) 기관 전벽의 결손부위는 늑연골 및 늑연골막을 이용하여 성공적으로 재건되었다.

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The Coastal Geomorphic System of Sagye, Jeju (제주 사계해안의 지형시스템)

  • Seo, Jong-Cheol;Son, Myoung-Won
    • Journal of the Korean association of regional geographers
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    • v.13 no.1
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    • pp.32-42
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    • 2007
  • In Sagye coast of Andeok-myeon, southwestern Jeju, shore platform of noncohesive Hamori Formation, marine terrace deposit of round gravels, coastal dune composed of shell sand and volcanic sand, and back lake are linked closely with each other. In this paper, the formation process of Sagye coastal geomorphic system analysed by using OSL dating method is as follows: Firstly, Hamori Formation is a horizontal stratum filed up of tuff reworked by submarine volcanic eruption during 3$\sim$7.6 ka BP. Hollow at the boundary between Hamori Formation' flat and Kwangheak Basalt's gentle slope become a back lake when block is appeared over the sea level by uplift. Secondly, while Hamori Formation was laid below sea level, gravels which had been broken and abraded at southwestern rocky coast composed of Kwangheak basalt or been transported through the small stream from adjacent hillslope were deposited in rapid flow environment. Thirdly, deposition of round gravels was ceased by earth uplift, and shore platform was constructed by abrasion process of energy of swash moving forward. As altitude of shore platform is equal to high tidal level of spring tide, compared it with present high tidal level of study area, earth is uplifted about 105m since shore platform was formed. Fourthly, much sandy sediments transported from offshore bottom covered shore platforms and marine terrace deposits. Lighter sediments among sandy sediments was blown to back, formed secondary sand dune since about 500 year.

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Late Quaternary Paleoenvironmental Changes in the Western Nakdong River delta (낙동강 삼각주 서부지역의 제4기 후기 고환경 변화)

  • Ryu, Choon-Kil;Kang, Sora;Chung, Sung-Gyo
    • Journal of the Korean earth science society
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    • v.26 no.5
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    • pp.443-458
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    • 2005
  • Late Quaternary deposits of the core in the western area of the Nakdong River delta consist of four sedimentary units: Unit I, II, III and IV, in ascending order, controlled by the sea-level change since the last interglacial period. Unit I unconformable overlying Cretaceous basement rocks is composed of sandy gravel and sand deposited in a fluvial channel before the first marine transgression. Unit II composed of stiff massive mud is interpreted as a shallow marine deposits formed during the last interglacial period (probably MIS 5). The development of the fissures coated with oxidized materials in the upper part of Unit II is a feature of subaerial exposure, which indicates erosional contact with the upper Unit III. Unit III is made up of soft massive mud and soft shelly massive mud deposited in a tidal flat and a inner shelf, respectively, since the Holocene transgression (about 9,000 yr BP). Unit Ⅳ consisted of soft shell bedded mud and yellowish sandy mud was deposited in the delta environments during the regression (after about 5,000 yr BP). The lower shell bedded mud was deposited in a tidal flat and the upper sandy mud was deposited in the floodplain corresponding to present site of the Nakdong River delta.

Interpretation of Sedimentary Structure and Depositional Environment Based on a High-Resolution Seismic Profile across the Northeastern Boundary of the Pungam Basin (고해상도 탄성파자료를 이용한 풍암분지 북동부의 퇴적구조 및 퇴적환경 연구)

  • Kim, Gi Yeong;Heo, Sik
    • Journal of the Korean Geophysical Society
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    • v.2 no.2
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    • pp.91-99
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    • 1999
  • A high-resolution seismic profile acquired across the northeastern boundary of the Pungam Basin, one of the Cretaceous sedimentary basins in Korea, has been interpreted to delineate subsurface geological structures across the basin boundary. We identified boundary faults and unconformity surfaces of the basin and divided sediment body into three seismic depositional units (Units I, II, and III from youngest to oldest). Inferred from fault geometry and type, northeastern part of the Pungam Basin has been formed by a strike-slip fault whereas the normal faults near the boundary were formed by transtensional movement along a fault zone. A 350-400 m thick sediment layer is overlying the Precambrian gneiss. Bedding planes of Unit III are dipping westward and are closely related to an anticline in the acoustic basement. Unit II is also tilted westward, suggesting that the eastern part of the fault zone was uplifted after deposition of lower part of the sedimentary body. Afterward, the uplifted sediment layers were eroded and transported to the western part of the basin. Chaotic reflection pattern of sedimentary Units II and III may suggest that strike-slip movement along the fault zone deformed basin-filled sediments.

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Stratigraphy, Lithology and Diagenetic Mineral Facies of the Tertiary Yeonil Group (제 3기 연일층군의 층서, 암상 및 속성 광물상)

  • Noh Jin Hwan
    • The Korean Journal of Petroleum Geology
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    • v.2 no.2 s.3
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    • pp.91-99
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    • 1994
  • In the Heunghae area, genetic relationships among sedimentary facies, lithology, stratigraphy and diagenetic mineral facies of the Yeonil Group, are discussed. Conglomerate and sandstone of lower to middle parts of the Yeonil Group contain considerable amounts of volcaniclastic sediments, which were derived from the Tertiary volcanics exposed in the western margins of the sedimentary basin. A new stratigraphic division of the Yeonil Group into the Chunbuk and Pohang Formations is proposed on the basis of sedimentary facies, lithologic characteristics including volcaniclastic feature, and the presence of a key bed of siliceous mudstone overlying the Chunbuk Formation. Diagenetic mineral facies largely depend on the lithology and composition of sediments. Heulandite, smectite, calcite, and opal-CT are commonly found as diagenetic minerals in the Yeonil Group. Among these authigenic minerals, heulandite occurs as the coarse- grained main cement in conglomerates and sandstones of the Chunbuk Formation. Formation of the zeolite cement is favored by partial volcaniclastic lithology of the Chunbuk Formation. Smectite composition and diagenetic mineral facies such as heulandite and opal-CT may reflect that the Yeoil Group has undergone a shallow rial temperature ranging $40{\~}60^{\circ}C$.

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