• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.5
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• pp.337-343
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• 2020

This study investigated the low temperature sintering with various templates of Bi-based lead-free piezoelectric ceramics. The effects of using CuO-coated Na_0.5Bi_4.5Ti₄O₁₅ templates on the sintering behavior as well as the dielectric, ferroelectric, and piezoelectric properties of Bi_1/2(Na_0.78K_0.22)_1/2TiO₃ (BNKT) ceramics have been examined. In comparison with the specimens sintered with the Na_0.5Bi_4.5Ti₄O₁₅ templates without CuO coating, those sintered with the CuO-coated Na_0.5Bi_4.5Ti₄O₁₅ templates showed larger template sizes as well as a larger electric field induced strain (S_max/E_max) of 422 pm/V after sintering at temperatures as low as 975℃. These results are promising for low-cost multilayer ceramic actuator applications.

• Asian Journal of Turfgrass Science
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• v.16 no.1
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• pp.19-30
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• 2002

This study was conducted to investigated the effects of rubber chips from used tires on sports turf ground as soil conditioner to improve soil physical properties. The release of heavy metal ions was detected to check the soil contamination by incorporation of recycled rubber chips with topsoil. The effects of the chips were also evaluated as topdressing material to improve surface resilience. The rate of rubber chips showed a positive relationship with soil temperature increasement. Incorporation of rubber chips increased soil temperature on surface at 2.5 cm-depth. The rates of rubber chip showed a negative relationship with ground cover rate of turfgrass in early growth season. However, after 20 weeks, treatment of 10% rubber chips at 2.5 cm-depth showed a prominent cover rate of 70% which was not significantly different with untreated control. Incorporation of rubber chips within topsoil seemed to reduce soil compaction, but the effects was not prominent on physical properties. Rubber chips did not affect chemical properties and heavy metal contamination to soil environment. Rubber chips improved resilience of the compacted ground surface as topdressing material, this effect was prominent when aerification practise was preceded.

• Journal of the Korea Concrete Institute
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• v.22 no.6
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• pp.753-760
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• 2010

Ultra high performance concrete (UHPC), is characterized by its high compressive strength and advanced tensile behavior that is much superior to those of conventional concrete. In order to apply this new material in practice, the bond characteristics of UHPC were evaluated in this study. Pull-out tests between UHPC and deformed steel rebar were carried out according to the modified RILEM test method, and were verified by finite element analysis. From the test results showed that UHPC presents 5 to 10 times higher bond strength compared to normal strength concrete, this study suggested remarkably reduced development length and concrete cover comparing to existing specifications. The test results of 700 MPa high strength steel rebar demonstrated the applicability of high strength steel to UHPC. In addition, the transfer length measurements of seven-wire strand in UHPC specimens indicated that the transfer length limit set by the current design code is very conservative for UHPC.

• Korean Journal of Materials Research
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• v.17 no.3
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• pp.160-166
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• 2007

TRISO coatings on $ZrO_{2}$ surrogate kernels were conducted by a fluidized-bed chemical vapor deposition (FBCVD) method. Effects of the deposition temperature and the gas flow rate on the properties of SiC layer were investigated in the TRISO-coated particles. Deposition rate of the SiC layer decreased as the deposition temperature increased in the temperature range of $1460^{\circ}-1550^{\circ}C$. At the deposition temperature of $1550^{\circ}C$ the SiC layer contained an excess carbon, whereas the SiC layers had stoichiometric compositions at $1460^{\circ}C\;and\;1500^{\circ}C$. Hardness and elastic modulus measured by a nanoindentation method were the highest in the SiC layer deposited at $1500^{\circ}C$. The SiC layer deposited at the gas flow rate of 4000 sccm exhibited a high porosity and contained large pores more than $1{\mu}m$, being due to a violent spouting of particles. On the other hand, the SiC layer deposited at 2500 sccm revealed the lowest porosity.

• Korean Journal of Materials Research
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• v.13 no.10
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• pp.691-696
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• 2003

To improve the photocatalyticactivity of $TiO_2$-coated coal fly ash, tungsten hydroxide was doped by impregnation method and was oxidized by heat treatment in temperature ranges of $WO^{\circ}C$ for 2 hrs. The changes of crystal structure and crystal size of $TiO_2$and $WO_3$on coal fly ash were investigated by X-ray diffraction analysis. The crystal structure of titanium dioxide showed only anatase type and $TiO_2$-$WO_3$ compounds appeared in the heat treatment temperature ranges of $500∼600^{\circ}C$. By adding $V_3$in $TiO_2$coated on fly ash, the growth of crystal size of anatase was restrained and the anatase phase was stabilized in temperature ranges of TEX>$500∼<800^{\circ}C$. And $WO_3$acted as a trap site of electrons excited from anatase by irradiating UV. The maximum removal efficiency of NO gas for $TiO_2$/$WO_3$-coated coal fly ash was 84% and appeared when the ammonium tungstate of $1.3${\times}$10^{-3}$ M was doped and then heated at $600^{\circ}C$ for 2 hrs.

• Korean Journal of Materials Research
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• v.9 no.9
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• pp.913-918
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• 1999

As an alternative evaluation method of electromagnetic shielding properties, the material parameters are considered in determining the qualitative value of shielding effectiveness. The specimens are metallized nylon fabrics with the thickness of about 0.1 mm and the electrical conductivities in the range from 6.4$\times$10~2.4$\times$10(sup)5 mhos/m. On the basis of shielding theory, the shielding effectiveness (which is a sum of reflection loss and absorption loss) has been determined from the material parameters of the barrier sheets. For the conductive fabrics, the dominant shield mechanism is predicted to be reflection loss, which shows an increasing function of electrical conductivity. Comparing these theoretical value with the directly measured surface impedances, the error range is found to be within 10 dB, which demonstrates that the proposed material-parameters method can be a convenient way to determine the electromagnetic shielding properties.

• Korean Journal of Materials Research
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• v.13 no.2
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• pp.126-132
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• 2003

In order to evaluate the corrosion resistance at the anode side separator for molten carbonate fuel cell, STS316 and SACC-STS316 (chromium and aluminum were simultaneously deposited by diffusion into STS316 authentic stainless steel substrate by pack-cementation process) were applied as the separator material. In case of STS316, corrosion proceeded via three steps ; a formation step of corrosion product until stable corrosion product, a protection step against corrosion until breakaway occurs, a advance step of corrosion after breakaway. Especially, STS316 would be impossible to use the separator without suitable surface modification because of rapid corrosion rate after formation of corrosion product, occurs the severe problem on stability of cell during long-time operation. Whereas, SACC-STS316 was showed more effective corrosion resistance than the present separator, STS316 due to the intermetallic compound layer such as NiAl, Ni3Al formed on the surface of STS316 specimen. And it is anticipated that, in order to use SACC-STS316 alternative separator at the anode side, coating process, which can lead to dense coating layer, has to be developed, and by suitable pre-treatment before using it, very effective corrosion resistance will be achieved.

• Korean Journal of Materials Research
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• v.18 no.6
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• pp.326-333
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• 2008

Since the 1990s, the second generation of Zirconium alloys containing main alloy compositions of Nb, Sn and Fe have been used as a replacement of Zircaloy-4 (Zr-Sn-Fe-Cr), a first-generation Zirconium alloy, to meet severe and rigorous reactor operating conditions characterized by high-burn-up, high-power and high-pH operations. In this study, the mechanical properties and creep behaviors of Zr-Sn-Fe-Cr and Zr-Nb-Sn-Fe alloys were investigated in a temperature range of $450{\sim}500^{\circ}C$ and in a stress range of $80{\sim}150\;MPa$. The mechanical testing results indicate that the yield and tensile strengths of the Zr-Nb-Sn-Fe alloy are slightly higher compared to those of Zr-Sn-Fe-Cr. This can be explained by the second phase strengthening of the $\beta$-Nb precipitates. The creep test results indicate that the stress exponent for the steady-state creep rate decreases with the increase in the applied stress. However, the stress exponent of the Zr-Sn-Fe-Cr alloy is lower than that of the Zr-Nb-Sn-Fe alloy in a relatively high stress range, whereas the creep activation energy of the former is slightly higher than that of the latter. This can be explained by the dynamic deformation aging effect caused by the interaction of dislocations with Sn substitutional atoms. A higher Sn content leads to a lower stress exponent value and higher creep activation energy.

• Journal of Korea Water Resources Association
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• v.53 no.3
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• pp.167-179
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• 2020

Recently, new levee material has been developed to enhance natural soil strength and vegetation growth using biopolymer. In the study, critical tractive force of vegetated mats mixed with biopolymer mixed soil has been evaluated to apply the mixed soil to levee construction material. The mixed soil has been produced by mixing beta-glucan, clay, and sand. Full scale test bodies have been constructed with 3 cm thick of the mixed soil. Total 4 test bodies have been constructed and experimented. Critical tractive forces have been evaluated by observation and measurement of failure conditions and soil loss. Although performance of the vegetated revetments are affected by vegetation coverage conditions, the critical tractive forces are shown about 40 N/㎡ and the critical velocities are shown about 4 m/sec by full scale experiment. Erosion resistance is also enhanced by combination of root and net with mat materials.

• Korean Journal of Materials Research
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• v.12 no.5
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• pp.334-340
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• 2002

$TiO_2$-coated fly ash was synthesized by dropping method of coating agent in order to get $TiO_2$ coating layer with high photocatalytic activity on the surface of coal fly ash. The properties of the $TiO_2$ coating layer such as morphology, crystal structure, crystal size and photocatalytic activity were compared with those of the $TiO_2$-coated fly ash prepared by the traditional method of precipitation. $TiCl_4$ aqueous solution was used as a titanium stock solution and $NH_4HCO_3$ was used as a precipitant. The $TiO_2$ coating layer obtained by dropping method of coating agent was more uniform than that coated by precipitation. However, the crystal of $TiO_2$ coated by dropping method of coating agent was easy to grow by heat treatment because of the small primary particle size and bulky morphology, and its photocatalytic activity was consequently lower than that of the $TiO_2$ coated by precipitation. The $TiO_2$ coating layer obtained by both methods had a crystal structure of anatase, and the temperature of phase transformation into rutile was 90$0^{\circ}C$. The minimum crystal size of $TiO_2$ for the highest photocatalytic activity was found to be about 10nm.