• Title/Summary/Keyword: 피복재료

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상용 핵연료 피복관의 대량수소화 반응속도 연구

  • 김선기;김용수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.243-249
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    • 1998
  • 상용 핵연료 피복관 재료로 사용되고 있는 Zircaloy-2와 Zircaloy-4 및 ZIRLO$^{TM}$에 대한 수소와의 반응거동 및 속도론적(kinetic) 자료를 얻기 위하여 electro-microbalance가 장착된 TGA (thermogravimetric analysis) 장치를 이용하여 30$0^{\circ}C$~50$0^{\circ}C$의 온도범위에서 1기압 수소와의 반응에 따른 무게증가를 in-situ로 측정하였다. Zircaloy와 수소와의 반응거동은 chamber내 온도상승시 생성되는 산화막에 의해 초기에는 느린 반응이 진행되는 영역이 존재하고 온도가 낮은 35$0^{\circ}C$ 이하에서는 이것이 잠복기 형태로 나타난 후 직선속도법칙(linear rate law)을 따르며 반응이 가속화되는 것으로 나타났고 40$0^{\circ}C$ 이하의 저온에서는 직선속도법칙에서 반응이 지연되는 방향으로 약간의 편차(deviation)가 관찰되었다. 그 결과 Zircaloy-2와 ZIRLO$^{TM}$가 Zircaloy-4보다 수소와의 반응속도가 빠르고 활성화에너지가 낮은 것으로 나타났으며 직선속도법칙을 근거로 하여 각각 1.1x$10^{7}$ exp(-20,800/RT)와 1.5x$10^{6}$exp(-18,000/RT) 및 6.9x$10^{7}$ exp(-23,800/RT) (mg/dm$^2$/min) 의 속도상수를 도출하였다. 또한, 열구배가 존재하지 않는 out-of-pile 조건하에서도 'sunburst' 형태의 국부적 수소침투가 발생할 수 있음이 ~l,000 ppm이상의 수소침투 시편에서 확인되었다. ~3,000ppm이상 침투하게 되면 표면에 수소화물이 농축되어 있는 hydride layer가 형성됨을 관찰하였으며 ~5,000ppm 이상의 경우에는 수소화물의 방향성이 random하였으며 특히, ZIRLO$^{TM}$ 시편의 경우에서는 원주방향으로 길게 이어진 수소화물과 기계적 성질에 치명적인 반경방향의 수소화물이 평행하게 배열된 것을 관찰하였다.

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Experimental Study on Segregated Layers of Materials and Compressive Strength of Concrete for Pretensioned Spun High Strength Concrete Pile (PHC 파일의 압축강도와 재료분리층에 대한 실험연구)

  • 이성로;강성수;유성원
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.16-22
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    • 2001
  • Pretensioned spun high strength concrete (PHC) pile has to be quality-controlled and provided an adequate concrete cover to assure high load carrying capacity, impact resistance, economy, and durability. During spun pre-casting, the pile section is divided into several segregated layers such as laitance, paste, mortar, and concrete layers. Greater the thickness of segregated layers, more difficult it is to guarantee the capacity and the durability of PHC pile. The experimental study was performed to investigate the effects of centrifugal condition on the segregated layers of materials and the compressive strength of concrete for PHC pile. The considering factors in the test were centrifugal time and magnitude of centrifugal force. These factors have been found to have greater influence on the segregation than the concrete strength. The moderate centrifugal condition has to be considered to maintain quality assurance in the production of PHC pile, especially to provide the adequate concrete cover over its tendons.

Evaluation of fire-proofing performance of reinforced concrete tunnel lining coated by newly developed material (신개발 내화재료에 피복된 철근콘크리트 터널라이닝의 내화성능평가)

  • Park, Hae-Genn;Kim, Jang-Ho Jay
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.10 no.4
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    • pp.329-336
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    • 2008
  • Efficient traffic network is required in urban area for good living condition. However, dense traffic network creates traffic jam and gives bad influences to the ground environment. Therefore, advanced use of underground and tunnel is required. But, in the last 20 years many tunnel fire accidents have occurred all over the world. Increase of tunnels and increase of traffics result in increase of tunnel fire. Tunnel fire creates damage to people and to the tunnel structure. Also, tunnel fire creates a big economical loss. In a mountain tunnel, the stability of the tunnel will not be disturbed by fire although the tunnel lining will get a severe damage. However, in a shield tunnel or immersed tube tunnel, cut and cover tunnel, there is a high possibility that tunnel itself will collapse by fire because their tunnel concrete lining is designed as a structural member. The aim of this experimental research is to verify the fire protection performance of newly developed cementitious material compared with the broadly used existing products in Europe and Japan. For the experiments, the general NATM tunnel concrete linings with the newly developed material were tested using fire loading curve of RABT (Maximum peak temperature is $1,200^{\circ}C$) and RWS (Maximum peak temperature is $1,350^{\circ}C$). From the test results, the newly developed fire protection material applied with 30 mm thickness showed good fire-proofing performance under RABT fire loading.

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Evaluation of Side-ditch Erosion Factors and Judgment of Side-ditch Stability in Forest Road (임도(林道) 옆도랑의 침식요인(浸蝕要因) 평가(評價)와 안정성(安定性) 판별(判別)에 관(關)한 연구(硏究))

  • Lee, Hae-Joo;Ji, Byoung-Yun;Jung, Do-Hyun;Kim, Jong-Yoon;Cha, Du-Song
    • Journal of Korean Society of Forest Science
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    • v.89 no.3
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    • pp.397-404
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    • 2000
  • This study was carried out to investigate the influence of the road structure and site conditions on side-ditch stability of forest road. For experimental purposes, the forest road in the Kwangrung Experimental Forest, Korea Forestry Research Institute, was chosen as a study site. A total of 556 plots wes set up as every longitudinal gradient changing points by belt-transect method. Data of 10 road structural characteristics and side-ditch stability were collected from each plot and analysed by Quantification II. The main factors in order of partial correlation coefficient were longitudinal gradient, road position, inclination of cut-slope, constituent material of cut-slopes, distance of surface flow, cross-sectional shape of road, pavement material, vegetation of cut-slopes and length of cut-slope. The erosion of side-ditch of forest road occurred in the following cases; more than 8% of the longitudinal gradient, road position of hill under side and foot hill, more than $50^{\circ}$ of inclination of cut-slope, constituent material of cut-slopes of hard soil and gravel soil, more than 80m of distance of surface flow, pavement material with earth or gravel, more than medium covered of vegetation of cut-slopes, and the straight and convex form of road-bed.

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Study on the Characteristics of Pressure by Knitted Fabrics for Foundation (여성 파운데이션용 편포의 압력특성에 관한 연구)

  • Shim Bu-Ja;Lee Yang-Hun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.2 s.30
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    • pp.117-127
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    • 1989
  • 여성 파운데이션용 편포의 압력특성에 관한 문제를 공학적 관점에서 검토해보기 위하여 거들용 편포와, 또한 비교를 위하여 드로우어즈용 편포를 시료로하여 완전강체 및 완전탄성체, 그리고 강체와 탄성체를 동시에 가지는 수압체를 모델로 제작하고, 시료를 고리형태로 만들어 피복시킨후 그 압력을 12시간 동안 연속측정하였다. 이때 시료의 신장정도, 수압체의 탄성체 구성비 등을 여러가지로 달리 하여 그에 따른 압력의 변화를 봄과 동시에 시간경과의 효과도 검토하여본 바 다음과 같은 결과를 얻었다. 1. 강체를 수압체로한 경우는 시료의 신장률 증가에 따라 압력이 거의 직선적으로 증가하였고, 그 정도는 거들의 재료가 드로우어즈의 재료에 비하여 훨신 크게 나타났다. 2. 수압체의 탄성체구성비가 증가할수록 신장률 증가에 따른 시료의 실질신장률의 증가 경향이 둔화되어, $40\%$신장률의 경우는 그 이전보다 오히려 감소하는 경향을 나타내었다. 3. 수압체에 탄성체가 포함된 경우는 매우 적은 압력을 나타내었으며, 시료 신장률의 증가에 따른 변화도 매우 적게 나타남으로써 시료 신장률이 클수록 강체수압체에 대한 압력과의 차이가 더욱 커지게 됨을 알 수 있었다. 그러나드로우어즈 재료의 경우는 탄성체가 받는 부담은 크지 않은 것으로 나타났다. 4. 압력의 경시변화는 초기의 압력분포 안정화 과정을 제외하고는 12시간까지 어떤 경우에도 크게 나타나지 않았다.

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Correlation of Cold Work, Annealing, and Microstructure in Zircaloy-4 Cladding Material (지르칼로이-4피복재에서 가공도, 열처리 및 미세조직과의 상호관계)

  • Jeong, Yong-Hwan;Kim, Uh-Chul
    • Nuclear Engineering and Technology
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    • v.18 no.4
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    • pp.267-272
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    • 1986
  • To obtain various necessary data for the manufacturing and the use of the nuclear fuel cladding tube, the effects of deformation and heat treatment on Properties of Zircalof-4 material have been studied. The hardness is increased rapidly at a low degree of cold work and increased rapidly at cold work above 10%. Recrystallization has been completed at 64$0^{\circ}C$, 59$0^{\circ}C$, and 555$^{\circ}C$ in 30%, 60% and 80% cold worked specimen, respectively. The transformation of microstructure with increasing cooling rate after $\beta$-annealing is as follows; coarse Widmanstatten ($\alpha$) longrightarrow fine parallel plate ($\alpha$) longrightarrow martensite ($\alpha$$^{'}$). At the same time, hardness increased with increasing cooling rate. rate.

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A Study on the Solubility of Nb in Zr-0.8Sn Alloy by Thermoelectric Power Measurement (TEP 측정방법을 이용한 Zr-0.8Sn 합금의 Nb 고용도에 관한 연구)

  • Oh, Yeong-Min;Jeong, Heung-Sik;Jeong, Yong-Hwan;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.453-459
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    • 2001
  • It is important for the fabrication of nuclear cladding to optimize the microstructure, because the properties of Zr-based nuclear claddings such as mechanical properties, oxidation-resistance and corrosion- resistance vary widely with its microstructure. The microstructure in Zr-based alloy is strongly dependent on the solubility of alloying element. However, it is very difficult to measure the solubility due to the low solution limit of alloying elements in Zr-based alloy. In this study, Thermoelectric Power(TEP) measurements are used to determine the solubility of Nb in Zr-0.8Sn alloy, which is confirmed by optical microscopy and transmission electron microscopy. The solutioning of Nb obtained by a homogenization treatment and water-quench leads to a decrease of TEP The saturation of TEP appears with the increase of homogenization temperature, which means the saturation of the Nb content in the matrix. From these results, the solubility ($C_{Nb}$) of Nb in Zr-0.8Sn with temperature could be expressed as fellow equation : $4.69097{\times}10^{16}{\times}e^{-25300\times\;I/T}$(ppm.at.%)

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Influence of Controlled-release Fertilizer Levels on Rice Growth, Weed Control and Nitrogen Efficiency in Paper Mulching Transplanting (벼 종이멀칭이앙 시 완효성비료 수준이 벼 생육, 잡초방제 및 질소효율에 미치는 영향)

  • Jeon, Weon-Tai;Yang, Won-Ha;Roh, Sug-Won;Kim, Min-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.345-350
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    • 2006
  • Recently we have interest on rice products developed by environment-friendly management. The technology of paper mulching was practised without herbicide in machine transplanting cultivation of paddy. A field experiment was conducted on Gangseo series (coarse loamy, mixed, nonacid, mesic family of Aquic Fluventic Eutrochrepts) at the National Institute of Crop Science (NICS), RDA, Suwon, Gyeonggi province, Republic of Korea in 2004. This experiment was carried out to evaluate rice growth, weed control and nitrogen efficiency by the different controlled-release fertilizer levels in paper mulching transplanting. Treatments consisted of conventional fertilization, controlled-release fertilizer (100%, 80%, 60%) compared with nitrogen amount ($110kg\;ha^{-1}$) of conventional fertilization and no nitrogen plot. Mulching paper consisted of recycled paper which was coated with biodegradable plastics. There were no differences between conventional rice transplanting and paper mulching on missing hills. Weed occurrence and control were diverse and low as fertilizer amount increased. Plant height and tiller number per hill increased as fertilizer amount decreased. There were no difference between controlled-release fertilizer 80% and conventional fertilization plot on rice growth traits. Leaf color and $NH_4{^+}-N$ in soil had similar trends. There was no difference in yield between controlled-release fertilizer 80% and conventional fertilization plot. Agronomic nitrogen-use efficiency was high as fertilizer amount decreased. Therefore, these results suggested controlled-release fertilizer 80% should be optimum amount under paper mulching transplanting of rice considering weed control, rice growth and nitrogen efficiency.

Effect of Physical, Chemical Properties and of Pelleting Solid Materials on the Germination in Pelleted Carrot Seeds (펠렛 피복물질의 물리, 화학적 특성이 당근 펠렛종자의 발아력에 미치는 영향)

  • Kang, Jum-Soon;Son, Beung-Gu;Choi, Young-Whan;Lee, Yong-Jae;Park, Young-Hoon;Choi, In-Soo
    • Journal of Life Science
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    • v.17 no.12
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    • pp.1701-1708
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    • 2007
  • Seed pelleting is generally conducted in order to save the labor for sowing and thinning by enabling the precision mechanical planting. In the present study, the influence of physical and chemical properties of pelleting solid materials was investigated on carrot seed germination. Among the pelleting solid materials evaluated, dialite, kaolin, and talc showed low bulk density and high porosity. Bentonite and dialite carried high water holding capacities of 184% and 173%, respectively, while calcium carbonate, calcium oxide, and fly ash showed relatively low water holding capacity. The pH of kaolin (6.8) and dialite (7.4) were close to neutral, while limestone (12.8), calcium oxide (13.0), and bentonite (10.0) were highly basic. High electro-conductivity was shown in limestone and calcium oxide. EDS analysis revealed that the main elemental compositions of talc were Si (71.0%) and Mg (29.0%), and those of calcium carbonate were Ca (66.6%), Si (22.9%), and Mg (10.5%). High granulation capacity was observed from talc and the mixture of talc and calcium carbonate. Seeds pelleted with bentonite showed the highest hardness. The dissolving type of the pellet layer after imbibition was split type in talc, limestone, zeolite, and fly ash, melt type in calcium carbonate and calcium oxide, and swell type in bentonite and vermiculite. The shortest dissolving time of pellet layer was observed from calcium carbonate and kaolin. The germination speed $(T_{50})$ was delayed as the size of pelleted seeds increased. The optimum size of pelleting was 19 ratio in carrot.

Performance Evaluation of Repair Material and Method for Reinforced Concrete Structure by Long Term Exposure Experiment (장기폭로실험에 의한 철근콘크리트 구조물의 보수재료.공법 성능평가)

  • Kim, Moo-Han;Kim, Gyu-Yong;Cho, Bong-Suk;Kim, Young-Duck;Kim, Young-Sun
    • Journal of the Korea Concrete Institute
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    • v.19 no.1
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    • pp.39-46
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    • 2007
  • In this study, for the establishment of the performance evaluation methods and the quality control standards of durability recovery method, the quantitative exposure data by long term exposure test under the coast and normal atmosphere is accumulated and analyzed. Investigating and evaluating the result of exposure test during 30 months of exposure age under the coastal and normal atmosphere environment, carbonation depth and chloride-ion penetration depth very little penetrated than cover depth. It seems reasonable to conclude that main cause of Corrosion of reinforcing bar are chloride-ion and macro cell from the result of corrosion area and corrosion velocity. Therefore, it is considered to be applied as the fundamental data on the performance evaluation and quality control standards of repair material and method through continuous exposure test in the future.