• 한국해양학회지
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• v.8 no.1
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• pp.9-21
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• 1973

When industrial wastewater containing fluoride runs into the ocean, approximately 0.1ppm of F$\^$-/ will react with seawater and will be eventually lost, and the remaining F$\^$-/ can be determined withe the ALC. Therefore F$\^$-/ is eligible to be used as a tracer of pollutant which contains fluoride. Determination of F$\^$-/ in the seawater with the Dotite reagent, Alfusone, has been made by the following method: To 10 ml of water sample, 1 ml of buffer solution (pH=4.0), 8 ml of acetone, and 1ml of 10% Alfusone were added and diluted to 25ml with distilled water. After 20 minutes the absorbance at 620 nm against a reagent blank was measured. The distributions of F$\^$-/ in Jinhae Bay has been made on the basis of water samples collected from 103 different sampling stations occupied in Jinhae Bay. The water samplings, three in the spring tide and two in the neap tide, were taken from surface layer during the flood and ebb tide periods respectively. The average concentration of F$\^$-/ in the bay, except the area to which the wastewater runs off from the Chemical plant, was 1.45 ppm(1.07-6.33ppm), and that of F$\^$-/ in the plant effluent was 330ppm, occasionally up to 562 ppm. Thus high levels of F$\^$-/ in the bay are strongly correlated to the amount of effluent from the plant, and waters of Jinhae Bay contains at least 0.13% of the plant effluent.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.542-548
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• 2005

The self-assembled monolayers (SAMs) of perfluorocarboxylic acids were fabricated on several metal oxide powders. Perfluorododecanoic acid and perfluorooctadecanoic acid were used to study the effect of chain length on SAM. Alumina, Tantalia, Titania, and Zirconia were the metal powders used. The formation of the SAMs was confirmed by DRIFT(Diffuse Reflectance Infrared Fourier Transform) spectroscopy. Since the perfluorohydrocarbons are well known for their hydrophobicity, the resulting monolayers are also expected to have high hydrophobicity. The quality of DRIFT spectra of SAMs was dependent on the powder size as well as the element of metal oxides.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2131-2134
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• 2015

In this study, It has been demonstrated a new and realizable possibility of the ferroelectric random access memory devices by all solution processing method with paper substrates. Organic ferroelectric poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) thin films were formed on paper substrate with Al electrode for the bottom gate structure using spin-coating technique. Then, they were subjected to annealing process for crystallization. The fabricated PVDF-TrFE thin films were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). It was found from polarization versus electric field (P-E) measurement that a PVDF-TrFE thin film on paper substrate showed very good ferroelectric property. This result agree well with that of a PVDF-TrFE thin film fabricated on the rigid Si substrate. It anticipated that these results will lead to the emergence of printable electron devices on paper. Furthermore, it could be fabricated by a solution processing method for ferroelectric random access memory device, which is reliable and very inexpensive, has a high density, and can be also fabricated easily.

• Journal of the Korean Chemical Society
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• v.54 no.6
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• pp.711-716
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• 2010

New electroluminescent polymers with fluoro groups in vinylene units, poly(m-silylphenyl-p-phenylene-difluorovinylene) (m-SiP-PPDFV) have been synthesized by GILCH polymerization. These polymers have been used as the electroluminescent (EL) layers in single layer light-emitting diodes (LEDs) (ITO/PEDOT/polymer/Ca:Al). m-SiP-PPDFV shows PL around $\lambda_{max}$ = 452 nm and green EL around $\lambda_{max}$ = 497 nm. The current-voltage-luminance (I-V-L) characteristics of the polymers show turn-on voltages of 4.0 V approximately. Two fluoro groups were introduced on every vinylene units of m-SiP-PPV to give m-SiP-PPDFV in an attempt to increase the electron affinity of the parent polymer, and the devices show an increased color stability even with vinylene units. The color stability is attributed to the electron-withdrawing effect of the fluoro groups, which protect vinylene units from oxidation in PPV derivatives. We believe that fluoro groups can be introduced in vinylene units in order to attain excellent stability of PPV derivatives.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.8
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• pp.839-845
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• 2011

We performed numerical simulations of freely propagating premixed flames at atmospheric pressure to investigate the influence of trifluoromethane on $CH_4/O_2/N_2$ flames under oxygen enrichment. Trifluoromethane significantly contributed toward a reduction in flame speed, the magnitude of which was larger in terms of the physical effect than the chemical effect. More trifluoromethane could be added and consumed on oxygen-enriched $CH_4/O_2/N_2$ flames. $CHF_3$ was decomposed primarily via $CF_3{\rightarrow}CF_2{\rightarrow}CF{\rightarrow}CF:O{\rightarrow}CO$ and $CHF_3+M{\rightarrow}CF_2+HF+M$ played an important role in oxygen-enhanced flames. When an inhibitor was added to oxygen-enriched flames, the position of the maximum concentration of active radicals was shifted to a relatively low temperature range, and the net rate of OH became higher than that of H.

• Journal of the Korean Chemical Society
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• v.12 no.4
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• pp.163-169
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• 1968

The analysis for the fluoride contents of river water and industrial waste water in Seoul area has been carried out by the spectrophotometric method, from February to July, 1968. The results show that the average fluoride contamination is found to be in the range of $0.07{\pm}0.03{\sim}0.29{\pm}0.05$ mg/l. The reason for this contamination is discussed in detail.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.252-256
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• 1985

Absolute infrared intensities are predicted for the vibrational bands of gas-phase SiF$_2$ using a fluorine atomic polar tensor transferred from various fluorine compounds. The predicted relative intensities agree well with published spectra of gas-phase SiF$_2$.

• Analytical Science and Technology
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• v.14 no.5
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• pp.416-421
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• 2001

The optimization of the reductant and acid concentration for stannane($SnH_4$) generation was investigated by using a continuous flow hydride generator combined with an inductively coupled plasma-atomic emission spectrometer. Several different prereductants were studied to remove the interfering effect of fluoride ion on the hydride generating of tin. The optimum acid concentration was 0.5-1.0 M for the 1-2% $NaBH_4$ and 1.0 M NaOH and the interfering effect of fluoride ion was minimized using boric acid and L-cysteine mixed solution as a prereductant. The reconveries of tin at 20 ng/mL level in the solution containing fluoride ion were 100~108 %.

• Proceedings of the Korean Fiber Society Conference
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• 1992.06b
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• pp.101-101
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• 1992

• Proceedings of the Korean Fiber Society Conference
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• 1991.06b
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• pp.49-49
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• 1991