• Elastomers and Composites
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• v.39 no.4
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• pp.309-317
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• 2004

Synthesis of fullerene oxides [$C_{70}O_n$] ($n=1{\sim}3$ or n=1) in solid state by fullerene [$C_{70}$] and several oxidants such as 3-chloroperoxy benzoic acid, chromium(VI) oxide, benzoyl peroxide, and trichloroisocyanuric acid was taken place under microwave irradiation. The reactivity in solid state oi fullerene [$C_{70}$] with various oxidants under same microwave condition increased in the order of 3-chloroperoxy benzoic acid > chromium(VI) oxide > trichloroisocyanuric acid ${\simeq}benzoyl$ peroxide. The MALDI-TOF-MS, UV-visible spectra and HPLC analysis confirmed that the products of fullerene oxidation were [$C_{70}O_n$] ($n=1{\sim}3$ or n=1).

• Elastomers and Composites
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• v.41 no.1
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• pp.57-62
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• 2006

The reaction of fullerene$[C_{60}]$ and 3-chloroperoxy benzoic acid in 1,2-dichlorobenzene was monitored by high resolution ultrasonic spectroscopy and the product of reaction by fullerene $[C_{60}]$ and 3-chloroperoxy benzoic acid in 1,2-dichlorobenzene was characterized using MALDI-TOF-MS spectra.

• Elastomers and Composites
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• v.49 no.2
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• pp.155-159
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• 2014

High resolution ultrasonic spectroscopy was used to observe the oxidation of [$C_{70}$]fullerene with 3-chloroperoxy benzoic acid in 1,2-dichlorobenzene. UV-vis spectroscopy and X-ray diffraction confirmed the resulting roducts of [$C_{70}$]fullerene oxidation.

• Elastomers and Composites
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• v.43 no.4
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• pp.264-270
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• 2008

$\alpha$-D-mannosyl fullerene[$C_{60}$]-functionalized gold nanoparticle films were selfassembled using the layer-by-layer method on the reactive of glass slides functionlized with 3-aminopropyltrimethoxysilane. The functionalized glass slides were alternately soaked in the solutions containing $\alpha$-D-mannosyl fullerene[$C_{60}$] and 4-aminothiophenoxide/hexanethiolate-protected gold nanoparticles. $\alpha$-D-mannosyl fullerene[$C_{60}$]-functionalized gold nanoparticle films have grown up to 5 layers depending on the immersion time. The self-assembled nanoparticle films were characterized using UV-vis spectroscopy showed that the surface plasmon band of gold at 530 nm gradually became more evident as successive layers were added to the films.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.11a
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• pp.374-375
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• 2008

In this study, the nano-composite actuator based on Fullerene and Nafion was newly developed to improve the electro active polymer actuators. The tensile test was employed to define the mechanical stiffness and strength of the nano-composite membrane. Also, the bending displacement of the Fullerene-Nafion based nano-composite actuator was investigated under DC and AC excitations with various magnitudes and frequencies. As a result, the new nano-composite actuator based on Fullerene-Nafion shows much larger deformation than the pure Nafion based actuator and solves the straightening back Problem of the previous electro active polymer actuators.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2005.09a
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• pp.31-34
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• 2005

분자 위치제어 메모리 시스템에 대하여 고전적인 분자동역학을 이용하여 결합에너지 및 다양한 외부전압의 형태에 따른 셔틀 풀러렌 동작에 관하여 연구하였다. 단일 나노피포드 형(single-nanopeapod type)은 질화붕소 나노튜브(boron-nitride nano tube) 속에 세 개의 엔도풀러렌(endo-fullerene)과 양쪽 끝에 구리 전극이 채워져 있는 구조를 갖고 있는 구조를 갖고 있다. 결론적으로, 분자동역학 시뮬레이션 결과로부터 이 나노메모리 시스템은 비휘발성임을 알 수 있었다. 안정적인 bit 변화를 위해서는 단일 나노피포드 형은 0.1 eV/$\AA$ 외부전압이 필요로 함을 알 수 있었다.

• Elastomers and Composites
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• v.40 no.3
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• pp.174-180
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• 2005

Sonochemical synthesis of fullerene oxides $[C_{70}O_n](n=1{\sim}2)$ by fullerene$[C_{70}]$ and metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) took place under air atmosphere. The reactivity of fullerene$[C_{70}]$ and several metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) under same ultrasonic condition increased in the order of $Mo(CO)_6$ > $W(CO)_6$ > $Cr(CO)_6$. The MALDI-TOF-MS, UV-visible spectra, and HPLC analysis confirmed that the products of sonochemical reaction were $[C_{70}O_n](n=1{\sim}2)$.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2009.04a
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• pp.351-352
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• 2009

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.321-321
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• 2016

한경오염의 증가에 따라 광촉매 물질을 이용한 환경 정화의 필요성이 대두되고 있다 [1]. 광촉매와 전기화학셀은 빛을 이용하여 다른 에너지를 생산하는 능력을 가지고 있다. 이 전기화학셀의 성능향상을 위해서는 적절한 밴드갭을 이용한 광흡수의 증가, 전자재결합의 감소, 전기화학적 반응 표면의 증가가 필요하다. 산화 아연은 잘 알려진 n형 산화물 반도체로서 좋은 전기적 특성과 광촉매 성능으로 전기화학셀에 적합한 소재이다. 그러나 산화 아연은 액체 전해물질 상에서 안정성이 좋지 못하다 [2]. 이를 해결하기 위해 단층 그래핀 혹은 풀러렌(C60)을 이용하여 산화아연을 코팅하는 방법을 제안하였는데, 풀러렌을 사용 시 단층 그래핀에 비하여 전기화학셀의 전기화학적 반응은 높았으나 안정성은 더 떨어지는 모습을 보였다 [3]. 본 연구에서는 다층 그래핀을 이용하여 전기화학적 반응도 높고 안정성도 높은 산화아연-다층 그래핀 양자점의 합성 및 이를 이용한 전기화학셀 소자의 특성을 연구하였다. X선 회절법, 라만 분광법, 투과 전자 현미경, 광발광 분광기, 시간-분해성 광발광 분광기를 이용하여 산화아연-다층 그래핀 양자점의 특성을 분석하였고, 이를 이용하여 광양극을 제작하여 전기화학적 특성을 관측하였으며 로다민 B 염료를 이용한 분해 테스트를 통하여 광촉매 성능을 확인하였고 사이클 테스트를 통하여 안정성을 확인하였다.

• Polymer(Korea)
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• v.34 no.1
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• pp.84-87
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• 2010

Copper-indium-diselenide (CIS) particles were prepared by the electrochemical reduction from the mixture solution of corresponding ion compounds. The prepared CIS was used as an insertion layer or a blending component in the organic photovoltaic bulk heterojunction cells composed of poly(3-octylthiophene) and fullerene. The increase of CIS content resulted in the rapid decrease of the open-circuit voltage as well as short-circuit current. The photovoltaic parameters were analyzed in relation to the structures, composition, and morphology of the photovoltaic blends.