• Title/Summary/Keyword: 표백

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Holographic recordings in acrylamide photopolymer (Acrylamide Photopolymer의 제작 및 홀로그램 기록 특성)

  • 경천수;성기영;곽종훈;최옥식;이윤우;이인원;서호형;이일항
    • Korean Journal of Optics and Photonics
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    • v.9 no.1
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    • pp.31-37
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    • 1998
  • We fabricated acrylamie photopolymer holographic recording materials by photopolymerization of acrylamide, and described hologram formation process. Light absorption and phtobleaching process by MB(methylene blue) dye and radical polymerization process due to TEA(triethanolamind) are explained in detail. We adopted the Beer-lambert law in order to explain the photobleaching kinetics. Dependencies of diffraction efficiency of the hologram on monomer amout and the exposure are investigated. The scattering effect caused by grain of polymer crystal, and fixing method are also illustrated.

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Manufacture of Printing and Writing Papers from Old Corrugated Containers (OCC) (Old Corrugated Containers (OCC)로부터 인쇄·필기용지 제조)

  • Lee, Goo;Ahn, Byoung-Jun;Paik, Ki-Hyon
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.367-373
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    • 1999
  • Increasing consumer demand for recycle of most paper products is challenging manufacturers to use lower value raw materials while maintaining high quality. This study was carried out to investigate the composition of old corrugated containers (OCC) and to manufacture printing and writing papers of over 85% (ISO) brightness by ECF and TCF bleaching from OCC. Fiber length of American old corrugated container (AOCC) was longer than that of Korean old corrugated container (KOCC) in fiber length. The former was composed of unbleached kraft pulp (UKP) of about 80 percentage, the latter about 20 percentage. OCC is feasible for manufacturing of pulps i.e., AOCC is for printing and writing papers and KOCC is for whiteboards, in the aspects of brightness and mechanical properties on the other hand, the cost of manufacturing upgraded papers by OCC is high because of bleaching chemicals. Neverthless, considering various aspects, especially environment, there are many advantages in recycling. In case of the treated AOCC pulp, over 85% (ISO) brightness can be achieved through TCF or ECF bleaching step, while the treated KOCC pulp did not allow high brightness through TCF bleaching. The tensile index of the bleached KOCC pulp was lower than that of the bleached AOCC pulp, but the burst and tear index of KOCC was higher than that of AOCC.

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Analysis of Sludges from Wastewater of Hanji Production (한지 생산공정에서 발생하는 슬러지의 분석)

  • Choi, Hee-Seon;Kim, Tai-Jin
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.318-325
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    • 1999
  • Sludges from the wastewater of hanji production were analysed to see that sludges from the bleaching process, the bleach washing process, and the paper preparation process were fibrous, while sludges from the process cooking with NaOH and the process of final chemical and microbiological treatment were non-fibrous. Sludge solution from the bleaching process had the most amount of solid matters. Sludges from the bleaching process, the bleach washing process, and the final chemical and microbiological treatment process contained about 80-90 %(w/w) moisture. Owing to hypochlorite ion, pH of sludge from the bleaching process was higher than any other sludge samples. The inorganic components of sludges were determined by ICP-AES. The major inorganic component of sludge from the process cooking with NaOH was Na, while the sludge from the bleaching process had Na and Ca, major components in the final chemical and microbiological treatment process were Ca and Al. Trace amount of Mg, Fe, K, P, Mn and Ti were observed in sludges. Sludge from the bleaching process had ashes more than any other sludges. Shape of sludges observed by SEM was appeared to fibrous or crystalline, and the breadth of fibrous sludge was $5{\sim}50{\mu}m$. The sludge from the bleaching process had the most amount of matters soluble by cold and hot water and by alcohol-benzene.

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A Study on the Development of Bleaching efficiency for flex fabrics by Using Ozone Treatment (오존을 이용한 마직물의 표백성 향상에 관한 연구)

  • Lee, Mun-Soo;Song, Kyong-Hun;Kim, Gyoung-A;Song, Bong-Keun;Lee, Rae-Yohn
    • The Journal of Natural Sciences
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    • v.10 no.1
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    • pp.93-102
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    • 1998
  • In order to study on the bleaching efficiency of flex fabrics, ozone which has been produced by an ozone generator, has been contacted with flex fabrics in water at various conditions. The equipments used for the ozone reatment of flex fabrics were the ozone generator and a liquor/ozone contactor. For the study of the bleaching efficiency on flex fabrics, the Hunter's whiteness, tensile strength, microscopic properties of the ozone treated flex fabrics were measured. The concentration of generated ozone was increased, as the voltage increase, flow ratio decrease and oxygen amount increase. The bleaching efficiency of ozone treated fabrics was increased with increasing the net concentration of ozone. The whiteness ozone of treated fabrics was found to be best when treated temperature was $0-15^{\circ}C$ and treated time was 20 min. The tensile strength of treated fabrics decreased as the treating time increased, and as the temperature raised.

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Development of one batch type and multi functional agent for CPB process (CPB용 다기능성 일욕형 조제 개발)

  • Park, Beob;Cho, Yeon-Jeong;Koo, Kang
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.32-32
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    • 2011
  • Cold Pad batch(CPB)처리에 의한 직물 전처리 공정은 특히 저온처리방식이라 에너지 소모가 적으며, 발생되는 대기오염 및 용수사용량이 연속식 방법에 비해 약 30%이상 절감되는 경제적 친환경적인 기술로 특히 정련과 표백을 동시에 수행할 수 있다. CPB 전처리는 호발, 정련, 표백을 포함하는 공정으로 일욕으로 처리시 패딩, 수세, 와인딩 공정을 단축시키기 때문에 약품 소비량 감소와 에너지 사용 절감 효과가 있어 전 세계적으로 확산되고 있는 Green Technology이다. 본 연구에서는 CPB용 다기능성 일욕형 조제에 개발하기 위해 전처리시 정련, 표백성에 대한 연구를 진행하였다. 시료는 NP/C 교직물을 사용하였고, CPB 처리액은 원료 및 첨가용제를 여러 비율로 조합하여 조제를 formulation 하였다. 이를 사용하여 패딩, 배칭, 수세 및 건조하여 전처리를 하였다. 표백된 정도를 파악하기 위해 Macbeth Color Eye-3100을 사용하여 백도(whiteness(CIE))를 5회 평균값을 구하여 측정 하였다. 정련된 정도를 비교하기 위해 C.I.Reactive Red 238의 2g/l 용액을 사용하여 wicking test를 하였다. 1분간 흡수높이를 측정하여 정련성을 확인하였다. 각각의 첨가용제를 비교한 결과 isopropyl alcohol을 첨가 시 hexylene glycol, butyl diglycol를 첨가한 경우에 비해 높은 흡수높이를 나타내었다. isopropyl alcohol의 농도별 정련성을 알아보기 위해 0%, 5%, 10%의 농도로 처리하였다. 그 결과 isopropyl alcohol 첨가량이 많을수록 정련성이 증가하였다. 다기능성 일욕조제의 문제점인 알칼리 안정성 부족을 보완하기 위해 polyoxyethlylene tridecyl ether derivatieves(LAP300)의 인화물을 첨가하였다. LAP300의 첨가량이 증가할수록 정련성이 증가하는 경향을 나타내었다. 알칼리 안정성 및 타 성능(정련성, 백도, 킬레이트 성)을 종합적으로 평가하여 향후, CPB용 다기능성 일욕형 조제의 개발에 대한 연구를 진행할 계획이다.

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