• Title/Summary/Keyword: 표면 코팅제

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Transparent Conductive Polymer Sheets and Films for Electrostatic Discharge (정전기 방지용 투명 전도성 고분자 쉬트 및 필름)

  • 서광석;김종은;김태영;이보현;진영필;박현근
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.219-219
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    • 2001
  • 최근 정전기 방지 및 전자파 차폐재료로 주목받고 있는 전도성 고분자를 절연체 고분자 표면에 코팅하여 정전기 방지 포장용으로 사용되는 투명 대전방지 고분자 쉬트 및 필름을 개발하였다. 현재 사용하고 있는 정전기 방지 포장용 고분자는 폴리스티렌이나 폴리비닐에 카본블랙을 혼합하거나 또는 계면활성제를 표면 에 코팅하여 사용하였다. 그러나 카본블랙을 섞은 경우는 카본입자가 불순물로 작용하여 제품을 오염시키고 검은색 불투명이기 때문에 포장 후 제품을 확인 할 수 없으며 카본 혼합에 따른 기저수지의 물성 약화 가 문제가 되고 있으며 계면활성제를 혼합하거나 코팅하여 사용하는 경우는 시간이 지남에 따라 전도성이 소멸되며 입자가 표면으로 blooming out되어 제품을 오염시키는 단점을 가지고 있다. 본 기술 개발에 의하여 얻어진 투명 전도성 고분자 쉬트 및 필름은 기저수지가 투명할 경우 550nm에서 투명도를 5% 이하로 감소시키며 전도성 물질로 고분자를 사용하기 때문에 영구적인 전도성을 가지며 기저 고분자의 물성을 그 대로 유지 할 수 있는 장점을 가지고 있다. 본 개발품은 전자 부품 및 반도체 포장용 트레이, 캐리어 소재 및 정전기 방지를 필요로 하는 모든 분야에 사용될 수 있으며 전도성 부여 처리기술을 가지고 있기 때문에 포장, 운반 목적 외에 여러 가지 정전기 방지 처리분야에 적용이 가능하다.

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A comparative study on consolidants for bronze objects conservation (청동유물 보존처리에 사용되는 강화처리제의 특성 비교)

  • Cho, Hyun-Kyung;Cho, Nam-Chul
    • Analytical Science and Technology
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    • v.22 no.3
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    • pp.263-271
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    • 2009
  • The purpose of metal artifacts conservation is recovering the original state of objects and preventing it from further corrosion. Four different consolidants are selected that are widely used for bronze objects conservation. This study found out the characteristics of thin film by various experiments and analysis for the bronze plates coated using each solutions. After a series of analysis, resin B and V showed good coating properties. However, the evaluation point suited to this purpose are adhesive strength, stability against yellowing and corrosion resistance. Therefore, resin B of four different consolidants could expect to get the most suitable consolidation effect for consolidation purpose.

Preparation of Water-Resistant Hydrophilic Coating Solutions for PET film (내수성이 우수한 PET 필름용 친수성 코팅액의 제조)

  • Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.584-594
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    • 2014
  • To increase of surface hydrophilicity of polymeric thin films is an important approaching technique for introduction of self-cleaning and/or antifogging properties on the surfaces of those films. In general, hydrophilic surface can be produced by coating non ionic surfactants or by increasing surface energy. Various non-ionic surfactants, such as Tween, Span, and PEG-PPG block copolymers were selected for our experiments, because they are cheap and well soluble in toluene system as well as they contain several reactive hydroxy fuctional groups with coupling agents. Blending conditions influence the PET film surface hydrophilicities. However, the introduction of only these surfactants on the surface of PET films did not show the high durability of hydrophilic properties after washing with water. To improve the durability two types of coupling agents such as epoxide and diisocyanate were adopted. Contact angle of water on hydrophilically coated PET film surface with 6 wt% of isophrone diisocyanate(IPDI) containing coating solution was reached to $8.7^{\circ}$, which was an indirect evidence for very high surface hydrophilicity. A light(500 nm of wavelength) transmittance value of coated PET film was changed only from 87% to 85% with keeping a good transparent property. This film can be usable for self-cleaning film industries.

Preparation and Characterization of Hybrid Ozone Resistance Coating Film Using Carbon Nanotube (탄소나노튜브를 이용한 하이브리드 내오존성 코팅 막의 제조 및 특성)

  • Kim, Sung Rae;Lee, Sang Goo;Yang, Jeong Min;Lee, Jong Dae
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.573-579
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    • 2014
  • The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.

An Experimental Evaluation on Performance of Surface Protector for Concrete Structures (콘크리트 구조물 표면 보호재의 성능에 대한 실험적 평가)

  • Nam, Yong-Hyuk;Chung, Young-Jun;Jang, Suk-Hwan;An, Young-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.157-163
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    • 2006
  • This study is on the evaluation of double surface protection method using water repellent primer and final top coat to protect concrete. Water repellent agent has been applied on the final top coat to protect concrete. However, to make up for the weakness to the ultraviolet of the water repellent, the work procedure of these protectors is done vice versa. This combination of protectors was compared with existing ones in this study. Even though the final top coat was applied on the water repellent primer, its adhesive strength met to KS F 4936-' 03 with other protectors used in this study. All surface protectors used in this study were excellent in protecting concrete. Especially, in case of applying with final top coat in conjunction with water repellent primer, the resistance against chloride ion penetration and neutralization by $CO_2$ was more efficient than other surface protectors used in this study under this given condition.

Influences to Additive Type on Carbon Nanotube metal composite (첨가제 종류에 따른 탄소나노튜브 금속복합재료 소결코팅 영향)

  • Kim, Dea-Hea;Zheng, XI-Ru;Kim, Myin-Su;Park, Chan-Woo
    • Composites Research
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    • v.25 no.5
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    • pp.159-163
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    • 2012
  • The coating of metal surface with carbon nanotubes(CNTs) has been studied for the heat transfer enhancement of the boiling and condensation of refrigerant. The multiwalled carbon nanotube/copper oxide(CuO) composite powder, which has been surface modified by dispersant and polyvinyl alcohol solution, was ultrasonically sprayed and sintered on a copper wafer. In this paper, experiments were performed to assess the characterization and comparison of the carbon nanotube before and after sinterning and the morphology changes of the CNT/CuO-coated surface by using different dispersants. The dispersants used are THF (Tetrahydrofuran), SDBS(Dodecylbenzenesulfonic acid sodium salt), SDS(Sodium dodecy sulfate). The samples were examined by scanning electron microscopy(SEM), thermogravimetric analysis(TGA), differential scanning calorimeter(DSC) and Raman spectroscopy.

A Study on Carbonation Resistance of Concrete Using Surface-coated Lightweight Aggregates (표면코팅된 경량골재를 사용한 콘크리트의 탄산화 저항성에 관한 연구)

  • Eom, In-Hyeok;Jeong, Euy-Chang;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.1
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    • pp.21-28
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    • 2014
  • The purpose of this study is to investigate the mechanical properties and carbonation resistance of concretes using lightweight aggregate coated surface finishing materials. To evaluate the mechanical properties and carbonation resistance of concrete, slump, air amount, air-dried unit volume weight, compressive strength, and carbonation depth are tested. In terms of the unit volume weight of concrete, air-dried unit volume weight of concrete using coating lightweight aggregate was measured as $1,739{\sim}1,806kg/m^3$. When using coating aggregate, compressive strength of concrete at 28 days was measured as much as 82.7~95.9% of the compressive strength using non-coating aggregate. It is found that compressive strength tends to decrease with coating lightweight aggregate. However, all concretes using coating lightweight aggregate except O-LWAC satisfied the criteria for 28-day compressive strength suggested in KS. The measurement of carbonation depth when the water-repellent agent was used found that carbonation depth was reduced by as much as 2.6~6.1%. On the other hand, when using polymer waterproof agent, carbonation depth was reduced by as much as 8.6~12.0%. Consequently, to improve carbonation resistance, polymer waterproof agent was more effective than water-repellent agent. In particular, epoxy showed the most outstanding performance.

Effect of proton concentration in TEOS to improve durability of hydrophilic and high light transmittance properties of nanosilica coating (친수 및 높은 광투과 기능을 함유한 나노실리카 코팅액의 내구성 향상을 위한 수소이온 농도에 따른 TEOS의 반응 연구)

  • Lee, Soo;Chan, Sung Il;Hwang, Heon
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.483-491
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    • 2016
  • Even though the antifogging property of nanosilica coated glass surface is highly increased due to the hydrophilic hydroxyl groups on nanosilica surface, the durability of this property on outdoor glass was diminished rapidly after rain washing. In addition the topology of nanosilica coated glass surface plays very important roles to control an light transmittance or antireflection property. To improve these coating durability and characteristics a hydrophilic nanosilica coating on glass was prepared by coating with 1.5 wt% of nanosilica (Ludox) suspension in the presence of hydrolyzed tetraethylorthosilicate (TEOS). The optimum hydrolysis condition of TEOS in acidic or basic aqueous solution was also examined by contact angle measurement. The final transparent hydrophilic coating layer coated with nanosilica-TEOS in acidic condition (pH=4) showed much improved durability of hydrophilic surface as well as higher visible light transmittance than original uncoated glass by 2 % point.

Analysis and Mechanical Behavior of Coating Layer in Metallic Glass Matrix Composite (비정질 기지 복합재 코팅층의 미세조직 분석 및 기계적 거동)

  • Jang, Beom Taek;Yi, Seong Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.6
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    • pp.629-636
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    • 2014
  • For surface modification, bulk metallic glass coatings were fabricated using metallic glass powder and a mixture of a self-fluxing alloy or/and hard metal alloys with a heat-resisting property using a high velocity oxy-fuel coating thermal spraying process. Microstructural analyses and mechanical tests were carried out using X-ray diffraction, a scanning electron microscope, an atomic force microscope, a three-dimensional optical profiler, and nanoindenation. As a result, the monolithic metallic glass coating was found to consist of solid particle and lamellae regions that included many pores. Second phase-reinforced composite coatings with a self-fluxing alloy or/and hard metal alloy additives were employed with in-situ $Cr_2Ni_3$ precipitate or/and ex-situ WC particles in an amorphous matrix. The mechanical behaviors of the solid particles and lamella regions showed large hardness and elastic modulus differences. The mechanical properties of the particle regions in the metallic glass composite coatings were superior to those of the lamellae regions in the monolithic metallic glass coatings, but indicated similar trends in matrix region of all the coating layers.