• Title/Summary/Keyword: 표면 자유 에너지

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Transport Mechanism of an Initially Spherical Droplet on a Combined Hydrophilic/Hydrophobic Surface (친수성/소수성 복합표면상에서 초기 구형 액적의 이송 메커니즘)

  • Myong, Hyon Kook;Kwon, Young Hoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.11
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    • pp.871-884
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    • 2015
  • Fluid transport is a key issue in the development of microfluidic systems. Recently, Myong (2014) has proposed a new concept for droplet transport without external power sources, and numerically validated the results for a hypothetical 2D shape, initially having a hemicylindrical droplet shape. Myong and Kwon (2015) have also examined the transport mechanism for an actual water droplet, initially having a 3D hemispherical shape, on a horizontal hydrophilic/hydrophobic surface, based on the numerical results of the time evolution of the droplet shape, as well as the total kinetic, gravitational, pressure and surface free energies inside the droplet. In this study, a 3D numerical analysis of an initially spherical droplet is carried out to establish a new concept for droplet transport. Further, the transport mechanism of an actual water droplet is examined in detail from the viewpoint of the capillarity force imbalance through the numerical results of droplet shape and various energies inside the droplet.

Prediction of Wave Energy Absorption Efficiency and Wave Loads of a Three-Dimensional Bottom-Mounted OWC Wave Power Device (착저식 OWC 파력발전장치의 파에너지 흡수효율 및 파랑하중 계산)

  • Hong, Do-Chun;Hong, Key-Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.1
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    • pp.47-52
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    • 2010
  • The wave energy absorption efficiency and the first-order and the time-mean second-order wave loads of a three-dimensional bottom-mounted oscillating water column (OWC) chamber structure are studied. The potential problem is solved by making use of a hybrid Green integral equation associated with the finite-waterdepth free-surface Green function outside a twin chamber and the Rankine Green function inside taking account of the fluctuating air pressure inside the chamber. Numerical results of the primary wave energy converting efficiency and the oscillating and steady wave loads of a three-dimensional bottom-mounted OWC pilot plant have been presented.

A Unified Analysis of Low-Power and High-Power Density Laser Welding Processes with Evolution of Free Surface (자유표면변형을 고려한 저에너지밀도 및 고에너지밀도 레이저 용접공정 통합 해석)

  • Ha Eung-Ji;Kim Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.10 s.241
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    • pp.1111-1118
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    • 2005
  • In this study, a unified numerical investigation has been performed on the evolution of weld pool and key-hole geometry during low-power and high-power density laser welding. Unsteady phase-change heat transfer and fluid flow with the surface tension are examined. The one-dimensional vaporization model is introduced to model the overheated surface temperature and recoil pressure during high-power density laser welding. It is shown that Marangoni convection in the weld pool is dominant at low-power density laser welding, and the keyhole with thin liquid layer and the hump are visible at high-power density laser welding. It is also shown that the transition from conduction welding to penetration welding fur iron plate exists when the laser power density is about $10^6W/Cm^2$.

A Study on the Effect of Si Surface on Diamond Film Growth by AES (Diamond 박막 성장에 미치는 Si 표면 영향의 AES에 의한 연구)

  • Lee, Cheol-Ro;Sin, Yong-Hyeon;Im, Jae-Yeong;Jeong, Gwang-Hwa;Cheon, Byeong-Seon
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.199-208
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    • 1993
  • The effect of nucleation free energy related to Si surface states on diamond film growth behavior has been studied. Ar first, the three kinds of diamond thin films (A, B, C) were deposited on various Si substrates (A-Si, B-Si, C-Si) whose surfaces were polished with 1 ${\mu}m$ diamond paste, 6 ${\mu}m$ Al_2O_3$ powder and 12 ${\mu}m$ Al_2O_3$ powder respectively. And then, relative nucleation free energy calculated is ${\Delta}G_{A-Si}<{\Delta}G_{B-Si}<{\Delta}G_{C-Si}$. Although there are some difference in grain size, shape and nucleated size, the thin films on A-Si and B-Si were diamond including a small amount of DLC which was confirmed by AES, SEM, XRD, and RHEED. Namely, the diamonds of films (B) were not nucleated in scratches but in dents and larger in grain size compare with the film (C) of which diamond sere nucleated not only scratches but also dents. And, the sphere diamond which is not general shape was grown on C-Si. After all, the sphere was turned out to be the diamond including much graphite as a result of the AES in situ depth profiling. Consequently, the diamond shape and quality grown on Si were Changed from the crystal which the (100) and (110) planes were predominent to the crystal in which (111) plane was predominent, and newt to sphere shape diamond including much graphite according as the nucleation free energy increases.

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THE ABRASION OF SURFACE PENETRATING SEALANT BY TOOTH-BRUSHING (칫솔질에 의한 레진 표면 강화재의 마모)

  • Song, Ju-Hyun;Hahn, Se-Hyun;Jang, Ki-Taeg;Lee, Sang-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.33 no.4
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    • pp.633-642
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    • 2006
  • This study evaluated the surface changes such as surface average roughness(RA), surface free energy(SFE) and wear depth among groups treated with surface penetrating sealant(Fortify, Biscover), non treated polishing group before and after tooth-brushing, analyzing the influence of the sealants in filling of surface microdefects formed during the finishing and polishing procedures of composite resin. Results were as follow(p= 0.05) : 1. Ra was increased Biscover. Fortify and Polishing group. Before abrasion and in 6 months, all groups were statistically significant. In 1 month, 2 months and 3 months no statistical difference was noticed between Fortify and Biscover 2. SFE of Polishig and Biscover group. Fortify and Biscover group were statistically significant before abrasion. SFE of Polishing and Fortify group was statistically significant in 1 month. No statistical difference was noticed among groups in 2 months. SFE of Fortify and Biscover group was statistically significant in 3 months. Polishing and Fortify group, Fortify and Biscover group were statistically significant in 6 months. 3, Wear rate between Polishing and Fortify group was statistically significant in only 1 month. Wear rate between Polishing and Biscover group was statistically different in each month except for 2 month and so it was between Fortify and Biscover group. Considering film thickness of Fortify and Biscover, Fortify almost discappeared after 2 months and Biscover did after 6 months.

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Hydrophilicity Improvement of Polyamide66/Polyphenylene Blends by Plasma Surface Treatment (Polyamide66/Polyphenylene 블렌드의 플라스마 표면처리를 통한 친수성 향상)

  • Ji Young-Yeon;Kim Sang-Sik
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.391-396
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    • 2006
  • It has been reported that plasma treatments are used to modify surface properties of polymers such as adhesivity hydrophobicity and hydrophilicity. Using plasma treatment, interfacial pro-perty can be introduced to a polymer surface without affecting the desired bulk properties of a material. In this study, commercial polyamide66 (PA66) /polyphenylene (PPE) polymer was modified by plasma treatment under a various gas specious for elimination of organic compound and polymer surface property with hvdrophilicity. PA66/PPE polymer with hydrophilicity was treated by RF plasma vacuum system under a various parameter such as gas specious, processing time and partial pressure. Hydrophilicity of PA66/PPE was confirmed by calculation of the surface free energy from contact angle measurement. The highest surface free energy of $50.03 mJ/m^2$ with the lowest contact angle of $14^{\circ}$ was obtained at plasma process power of 100 W, treatment time of 2 min and $Ar/O_2$ gases of 100 and 200 sccm. Moreover the change of organic compounds on the polymer surface was analyzed by fourier transforms infrared spectrometry (FTIR).

Effect of Surface Free Energies on Mechanical Properties of Epoxy/Polyurethane Blend System (에폭시/폴리우레탄 블렌드 시스템의 표면 자유에너지 변화가 기계적 특성에 미치는 영향)

  • 박수진;진중성;이재락;박병기
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.245-251
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    • 2000
  • A blend system prepared from epoxy(EP) and polyurethane (PU) was investigated in terms of the contact angle and mechanical properties. The contents of EP/PU were varied within 100/0~100/60 phr in the presence of 20 phr DDM (4,4'-diamino diphenyl methane) as a curing agent for epoxy resin. Contact angle measurements were performed employing a Rame-Hart contact angle goniometer. Deionized water and diiodomethane were chosen as the testing liquids. In this work, Owens-Wendt and Wu's models using a geometric mean were studied to analyze the surface free energy of blend system. For the mechanical and toughening properties of the casting specimens, the critical stress Intensity factor ($K_{IC}$) and impact test were performed. Especially, the impact test was carried out at room and cryogenic temperatures. As a result, specific or polar component of the surface free energy of the blend system was largely influenced on the addition of the PU resulting in increasing the impact strength for the excellent low- temperature performance.

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Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks (충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향)

  • Kim, Jeong-Soon;Choi, Kyung-Eun;Park, Soo-Jin
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.94-101
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    • 2001
  • In this work, the effect of NE plasma treatment generated by radio-frequency was investigated in acid-base surface values, ion adsorption characteristics, and surface free energies of carbon blacks. As the results, it was clearly found that the obvious improvement of the treatment is in the London dispersive component (${\gamma}s^L$) of surface free energy of carbon blacks. Also both electron-acceptor ( ${\gamma}s^+$) and -donor (${\gamma}s^-$) parameters for the specific component (${\gamma}s^{sp}$) were also increased with increasing the treatment time, resulting in increasing the surface functional groups of the carbon blacks studied, together with a consequence of the increases of acidic and basic surface functional groups, ion exchange, zeta potential, and ion mobility.

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The Influence of Plasma Surface Modification on Frictional Property of Natural Rubber Vulcanizates

  • Nah, C.;Kim, D.H.;Mathew, G.;Jeon, D.J.;Jurkowski, B.;Jurkowska, B.
    • Elastomers and Composites
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    • v.39 no.1
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    • pp.12-22
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    • 2004
  • The plasma surface modification of natural rubber vulcanizate was carried out using chlorodifluoromethane in a radio-frequency (13.56 MHz) electrodeless bell type plasma reactor. The modification was qualitatively assessed by Fourier transform infrared spectroscopy. The frictional force of the plasma-treated surface was found to decrease with the time of plasma treatment. An increase in the surface polarity, as evidenced by the decrease in contact angle of a sessile drop of water and ethylene glycol on the natural rubber vulcanizate surface, was noted with the plasma modification. In the case of similar plasma treatment of glass surface, only a reduction in the polarity was observed. The use of geometric and harmonic mean methods was found to be useful to evaluate the London dispersive and specific components of surface free energy. Irrespective of the method used for evaluation, an increasing trend in the surface free energy was noted with increasing plasma treatment time. However, the harmonic mean method yielded comparatively higher values of surface free energy than the geometric mean method. The plasma surface modification was found to vary the frictional coefficient by influencing the interfacial, hysteresis and viscous components of friction in opposing dual manners.