• Journal of Hydrogen and New Energy
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• v.17 no.3
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• pp.347-352
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• 2006

분자전해질연료전지 내의 다공성 기체확산층은 반응가스의 확산과 전자이동통로의 역할을 수행할 뿐만 아니라 전기화학반응에 의해 공기극에서 생성된 수분(기상 혹은 액상)을 반응면으로부터 분리판 채널 방향으로 이동시켜 배출시키는 중요한 역할을 한다. 따라서 물관리를 통한 성능향상을 위해서는 기체 확산층의 구조 및 재료특성에 대한 심도 릴은 연구가 필요하다. 실제 단위전지 체결시 기체확산층은 분리판의 리브(rib)에 의해 눌리게 되며, 그 부분의 기공 크기 분포의 변화를 야기한다. 또한 리브 전단부분에서 탄소 섬유가 손상을 입으며, 탄소 섬유를 감싸고 있는 PTFE coating이 벗겨지게 되어 표면화학적 특성이 달라진다. 본 연구에서는 단위전지 체결 시 분리판에 의해 눌리는 기체확산층의 기공 크기 분포 변화를 측정하였으며, 기공의 소수성에서 친수성으로의 변화를 알아보았다. Mercury 기공 측정기와 PMI 기공 측정기는 큰 기공 분포의 변화에, 질소의 흡/탈착을 이용한 BET 방식은 작은 크기의 기공 분포 변화 관찰에 사용되었다. 체결압에 의한 탄소섬유의 구조적 변화와 아울러 표면의 습윤 정도의 변화를 XPS와 물/알콜 Uptake를 이용해 알아보았다. 이 연구를 바탕으로 물관리를 통한 연료전지 성능 향상을 위한 최적 GDL 선정에 기반이 되는 자료를 도출하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.176-177
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• 2005

PDMS는 생명공학 분야에서 중요한 기술적 폴리머이다. Nd:YAG레이저의 4고조파 ($\lambda$=266nm, pulse) 레이저를 사용하여 표면 처리를 하여 PDMS 표면의 습윤성과 접착성의 향상됨을 확인하였다. 식각한 PDMS는 샘물체의 미세회로에 사용될 수 있다. 본 논문은 레이저 빔의 주사속도를 변화시키며 PDMS를 레이저로 식각하며 PDMS의 식각 특성을 연구한다 식각 특성을 의존성이 가장 효과적인 주사 속도에 대한 의존성을 규명하고자 스테이지 컨트롤러의 속도를 변화시키며 실험하였다. 그리고 최적의 레이저 출력값을 알아내려고 레이저 출력값을 조절하며 실험 하였다. 단차측정기(알파스템)을 이용하여 식각형상과 식각 효율 등을 분석하였다.

• 한국전산유체공학회:학술대회논문집
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• 2008.03b
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• pp.662-665
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• 2008

We experimentally investigate the evaporation characteristics of water droplet on surfaces of various wettabilities in the range of contact angle from 30$^{circ}$ to 150$^{circ}$. When a liquid droplet on a solid surface evaporates, the contact angle generally decreases with time and the evaporation rate varies with the droplet geometry such as the contact angle and the radius of curvature. Experimental data on the contact angle as a function of the droplet volume obtained by digital image analysis techniques cannot be explained by the existing theories. By measuring the temporal evolutions of the droplet radius and contact angle, we find the qualitative difference between the evaporation patterns on the hydrophilic surfaces where the contact radius remains constant initially and those on the superhydrophobic surfaces where the contact angle remains constant. Also, the evaporation rate is observed to depend on the surface material although the currently available models assume that the rate is solely determined by the droplet geometry. Despite the fact that the theory to explain this dependence on the surface remains to be pursued by the future work, we give the empirical relations that can be used to predict the droplet volume evolution for each surface. It is expected that the present study will contribute to interpreting the effect of droplet geometry on the evaporation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5D
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• pp.813-819
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• 2006

Skid Resistance is a index to represent the friction between tire and road surface, which influences driving safety. Skid resistance varies with the conditions of tire, abrasion of road surface, vehicle speed, drying, wet and freezing condition of road surfaces. Especially, freezing occurs when temperature drops below $0^{\circ}C$ followed by snow or rain causes decrease of skid resistance. To recover the decreased skid resistance deicing work is applied. As a results of deicing works, freezing condition is changed into wet condition. However the wet road surfaces containing the remaining deicings agents may not show the skid resistance of normal wet condition. In this study, skid resistances in the condition of freezing, deicing process and deicing agents remained after snow-removal are evaluated. The test results, skid resistance recover quickly when Pre-wetted salt spreading and NaCl was used as deicing method. Skid resistance of Deicing agents remained on the road surface showed that concrete is higher than asphalt. superior effect. Recovery rate of skid resistance by comparison wet condition is 54~80%.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.565-568
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• 1998

Amphipathic compounds (bis-sulfonate Gemini type) with double or triple long chain alkyl groups were prepared by the reaction of N-(long chain acyl)diethanolamine diglycidyl ethers with fatty alcohols, followed by the reaction with propanesultone. All these new Gemini type surfactants were soluble in water and showed much better micelle forming ability and lowering surface tension than sodium dodecyl sulfonate with one sulfonate group. cmc and ${\Upsilon}$ cmc values of the triple-chain compounds were still much smaller than those of the corresponding double-chain compounds with two common alkyl groups. The efficiency of adsorption at the water/air interface ($pC_{20}$) of these surfactants was very high. Their foaming properties, wetting ability toward a felt chip, and lime-soap dispersing requirement (LSDR) were measured. Their initial foaming properties were high but showed good low foam stability, wettability and LSDR.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.639-646
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• 2007

This study performed several tests for the durability of the concrete coated with nano synthesis ceramics which do not contain volatile organic compounds harmful to environment. The tests were adhesion test on dry and humid concrete, SEM test, MIP analysis, carbonation, chloride diffusion by electronic facilitation, freezing-thawing resistance, alkaline resistance, and brine resistance test. In the adhesion test on dry and humid concrete, nano synthesis ceramics coating produced the highest results among all the coatings tested. Nano synthesis ceramics adhered solidly on the concrete surface. The adhesive strength seemed to result from the hydrogen bond between nano synthesis ceramics which are inorganic and generated by hydrolysis and re-condensation reaction and the concrete's hydrates such as calcium silicate aluminate or calcium silicate hydrate. SEM test and MIP analysis results show surface structure with finest crevices pore in the nano synthesis ceramics coating applied concretes. In the carbonation, chloride diffusion, and freezing-thawing resistance tests, the concretes with nano synthesis ceramics coating indicated the best results. Based on these test results, further progress in application of nano synthesis ceramics coatings to various concrete structures including costal structures and sewerage arrangements can be expected.

• Journal of Surface Science and Engineering
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• v.16 no.2
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• pp.41-47
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• 1983

An investigation has been performed on the effects of temperature and Ni addition on the wetting behaviour of Cu on W substrate in hydrogen atmosphere. An sessile drop method was used to measure a wetting angle. The concentration profiles of W, Cu and Ni elements in W/Cu - 5 Ni specimen were made by EPMA. With increasing temperature, the wetting angle of Cu droplet on W plate decreases and the time to reach an equilibrium wetting angle is shortened in hydrogen atmosphere. The addition of Ni improves appreciably the wettability of Cu on W. With increasing Ni content in Cu liquid droplet(0, 1, 3, 5%), the wetting angle is decreased from 21$^{\circ}$to 0$^{\circ}$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1080-1083
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• 2002

In this paper, we have studied with regard to the use of lasers for modifying the surface properties of silicon in order to improve it's wettability and adhesion characteristics. Using an Nd:YAG pulse laser, the wettability and adhesion characteristics of silicon surface have been developed by an Nd:YAG pulse laser. It was found that the laser treatment of silicon surfaces modified the surface energy. In the result of wetting experiments, by the sessile drop technique using the distilled water, wetting characteristic of silicon after the laser irradiation shows a decreased value of the contact angle. In case of the laser treated silicon surface, laser direct writing of copper lines has been achieved by pyrolytic decomposition of copper formate films$(Cu(HCOO)_2{\cdot}4H_2Q)$, using a focused $Ar^+$ laser beam$(\lambda=514.5nm)$ on the silicon substrates. The deposited patterns were measured by energy dispersive X-ray(EDX), Scanning Electron Microscopy(SEM) and surface profiler($\alpha$-step) to examine the cross section of deposited copper lines and linewidth.

• Polymer(Korea)
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• v.36 no.3
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• pp.338-343
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• 2012

Interfacial properties of commercially available soft contact lens hydrogels were studied to understand thermodynamic phenomena of protein adsorption. Hydrogel particles ($1{\times}1mm^2$) with varying water wettability were exposed to bovine serum albumin solutions for an hour. The remained albumin solutions were analyzed with Bradford assay method. The amount of protein adsorbed to hydrogels increased with protein solution concentrations following Langmuir isotherm. The partition coefficient ($P$) and Gibbs free energy cost of dehydrating the surface region by protein displacement upon adsorption increased with increasing hydrophilicity of contact lens. Understanding of physical chemistry in protein adsorption to contact lens materials enabled elucidating relationships between surface energy and albumin adsorption capacity.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1547-1549
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• 2003

송배전용 설비에 사용되는 옥외 절연물로는 자기질이나 유리질의 애자가 주로 사용되어 왔지만 최근 신소재의 발달로 가볍고 절연성능이 우수한 폴리머 애자가 보편화되기 시작하였다. 폴리머 애자가 자기질 및 유리질의 애자에 비하여 내열성과 내후성이 부족한 것은 사실이지만 절연물이 오염과 습윤된 환경에서 폴리머 애자의 절연성능이 휠씬 우수한 것으로 밝혀지고 있다. 폴리머 애자의 장기성능 예측을 위하여 많은 수단과 측정방법이 연구되어 왔다. 폴리머 애자의 하우징 재료는 내열성, 내후성, 산화안정성, 발수성 및 내오염성 등 절연소재로서 우수한 특성을 가지고 있지만 하우징 표면에서의 방전이 발생될 때 옥외절연물에서의 성능은 하우징 재료의 배합처방에 따라서 많은 차이가 나고 있다. 본 논문에서는 하우징용 소재의 특성을 평가하기 위한 평가방법과 평가결과를 해석하는 기술에 대하여 기술하였다.