• Title/Summary/Keyword: 표면피막

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An Experimental Study on Corrosion Behavior in Steel of Concrete Applied with Arc Metal Spray Method Surface Treatment Technology Using EIS (EIS를 이용한 아크 금속용사 표면처리기법이 적용된 강재의 콘크리트 내 부식 거동에 관한 실험적 연구)

  • Yoon, Chang-Bok;Park, Jang hyun;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.87-95
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    • 2020
  • As an experimental study on the corrosion behavior of steel materials to which ATMS method using EIS was applied in concrete, immersion of Ca(OH)2 saturated aqueous solution and NaCl aqueous solution simulating the environment inside concrete The corrosion behavior was tested. The equivalent circuit was derived through the analysis of the Nyquist plot, and the interfacial resistance and the polarization resistance of the Ca(OH)2 aqueous solution were compared, and Al ATMS was the best interfacial resistance and Zn ATMS was the best polarization resistance. After burying ATMS steel material of cement mortar, the initial immersion impedance measurement value was the highest in the Zn ATMS test body in the impedance measurement by the immersion time by immersing it in the NaCl aqueous solution. Al ATMS test piece has the highest impedance and is highly reliable. This is because Al, which has a high ionization tendency, is continuously oxidized in a strong alkaline environment to form a film and protect the steel from permeation of chlorine ions.

Evaluation and Weathering Depth Modeling of Thermally Altered Pelitic Rocks based on Chemical Weathering and Variations: Ulju Cheonjeon-ri Petroglyph (화학적 풍화작용과 조성변화에 따른 열변질 이질암의 풍화심도 모델링 및 평가: 울주 천전리 각석)

  • LEE Chan Hee;CHUN Yu Gun
    • Korean Journal of Heritage: History & Science
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    • v.56 no.4
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    • pp.160-189
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    • 2023
  • The Cheonjeon-ri petroglyph is inscribed with shale formation belonging to the Daegu Formation of the Gyeongsang Supergroup in the Cretaceous of the Mesozoic Era. This rock undergoes thermal alteration to become hornfels, and has a high hardness and dense texture. Rock-forming minerals have almost the same composition as quartz, alkali felspar, plagioclase, calcite, mica, chlorite and opaque minerals, but calcite is rarely detected in the weathered zone. The petroglyph forms a weathered zone with a certain depth, and there is a difference in mineral and chemical composition between weathered and unweathered zones, respectively. The CaO contents of the weathered zone were reduced by more than 90% compared to that of the unweathered zone, because calcite reacted with water and dissolved. As a result of calculating the surface weathering depth for the petroglyph with the transmission characteristics of X-rays, depth of the parts in falling off and exfoliation showed a depth of about 0.5 to 1 mm, but the weathering depth in most areas was calculated to be about 3 to 4 mm. This can be proved by the contents and changes of Ca and Sr. The surface discolorations of the petroglyph are distributed with different color density, and the yellowish brown discoloration is alternated with a thin biofilm layer, showing a coverage of 79.6%. Therefore, periodic preservation managements and preventive conservation monitoring that can effectively control the physicochemical and biological damages of the Cheonjeonri petroglyph will be necessary.

THE MORPHOLOGICAL OBSERVATION OF HUMAN GINGIVAL FIBROBLASTS ATTACHMENT AND SPREADING ON THE MECHANICAL TREATED TITANIUM PLASMA SPRAYED IMPLANT SURFACE (기계적 표면 처리된 TITANIUM PLASMA SPRAYED IMPLANT에 대한 치은섬유아세포전개양상의 형태학적 관찰)

  • Whang, Yun-Hi;Lee, Jae-Mok;Suh, Jo-Young
    • Journal of Periodontal and Implant Science
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    • v.25 no.3
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    • pp.741-755
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    • 1995
  • Currently titanium is the material of choice for implants because of its biological acceptance. This high degree of biocompatibility is thought to result, in part, from the protective and stable oxide layer that presumably aids in the bonding of the extracellular matrix at the implant-tissue interface. Endosseous dental implants are interfaced with bone, connective tissue, and epithelium when implanted into the jaw bone. The soft tissue interface including connective tissue and epithelium is one of the most critical factors in the determination of implant maintenance and prognosis. For maintenance of failing or failed implants, it is essential to treat the implant fixture surface to remove bacterial endotoxins and make a surface tolerated by surrounding soft and hard tissues. In this study, the effect of mechanical treatment on titanium plasma sprayed implant on adhesiveness and proliferation of human gingival fibroblasts and changed surface characteristics were studied. titanium plasma sprayed discs manufactured by Friedrichsfeld company were treated with loaw speed stone bur, a rubber point and a jetpolisher. Its surface components were analyzed with Energy dispersive X-ray spectroscopy to evaluate whether the surface characteristics were altered or not. To observe the spreading pattern of the human gingival fibroblasts which attached to the all specimens author used the scanning electron microscope. The results were as follows : Pure titanium and plasma sprayed titanium, stone polished titanium showed titanium peak and small amout of aluminum, so there was no alteration on surface characteristics. Under the scanning electron microscopic examination in the initial attachment of human gingival fibroblast, there was a slight enhancement in pure titanium, stone polished titanium than plasma sprayed titanium. After 6 hours, the pure titanium and stone polished titanium showed human gingival fibroblasts were elongated and connected with numerous processes. Human gingival fibroblasts were more intimately attached on the pure titanium discs than on the other discs. The human gingival fibroblasts attached on the plasma sprayed titanium by thin and elongated processes. After 24 hours, the human gingival fibroblasts connected with each other via numerous processes and compeletly covered the pure titanium and stone polshed titanium discs. Human gingival fibroblasts had multiple point contacts with more long and thin lamellopodia and showed a little bare surface on plasma sprayed titanium discs.

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Development and research of gas sensor for monitoring sulfur compounds (황화물 측정용 가스센서의 연구개발)

  • Kim, Ki-Young;Kim, Jong-Min;Ham, Young-Hwan;Chang, Yong-Keun;Kim, Jong-Deuk;Chang, Sang-Mok
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.33-39
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    • 1994
  • A quartz crystal microbalance (QCM) sensor system for the detection of odorants, especially environmental pollutant, has been constructed by depositing various phospholipids, activated carbon and lead compound pigment onto the surface of the QCM. The characteristics of a QCM operating at 9 MHz deposited with phosphatidyl- choline were analysed. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids. The identification of odorants is discussed in terms of a comparison of their normalized resonant frequency shift patterns and relative response intensities calculated from the response areas. Applying the lead compound pigment coated QCM, it was possible to detect sulfur compound specifically. Using a number of different lipid-coated QCMs, odorants could be identified by comparing the response patterns.

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Development of Control Technology for Acid Mine Drainage by Coating on the Surface of Pyrite using Chemicals (산성광산배수의 발생저감을 위한 황철석 표면의 피막형성 기술개발)

  • Ji, Min-Kyu;Yoon, Hyun-Sik;Ji, Eung-Do;Lee, Woo-Ram;Park, Young-Tae;Yang, Jung-Seok;Jeon, Byong-Hun;Shim, Yon-Sik;Kang, Man-Hee;Choi, Jae-Young
    • Journal of Soil and Groundwater Environment
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    • v.15 no.4
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    • pp.46-52
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    • 2010
  • Acid mine drainage occurs when sulfide minerals are exposed to an oxidizing environment. The objective of this study was to inhibit the oxidation of pyrite by applying various coating agent such as $KH_2PO_4$, MgO and $KMnO_4$ over its surface as an oxidation inhibitors. Experiments were conducted for 8 days to test the feasibility of oxidation inhibitors. The optimal condition of coating agent for standard pyrite and IK mine was the combination of 0.01M $KH_2PO_4$, 0.01M NaOAc and 0.01M NaClO. Otherwise, for YD mine the combination of 0.01M $KMnO_4$, 0.01M NaOAc and 0.01M NaClO. The $SO_4^{2-}$ reduction efficiency of pyrite, IK and YD mine samples was 70, 92 and 84%, respectively. For 8 days, no significant increase of $SO_4^{2-}$ from pyrite sample coated with inhibitor was observed. The pH of solution remains in between 4 to 6 for the reaction conditions.

Characteristics of Reduction of Hydration Heat through Utilization of Blast Furnace Slag in the Cement-based Landfill Soil Liner System (고로슬래그를 이용한 폐기물 매립지 고화토차수층의 수화열 저감특성)

  • Cho, Jae-Beom;Hyun, Jae-Hyuk;Lee, Jong-Deuk;Park, Joung-Ku
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1327-1331
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    • 2005
  • This study was to investigate the reduction of hydration heat by utilizing industrial by-products such as BFS(Blast Furnace Slag). DM(Dredged Mud) was used by parent soil and Ordinary portland cement was used by cementing material. Additive added to reduce the heat of hydration was BFS. From the results of experiment, hydration heat was decreased in accordance with the addition of BFS. The reason was that surface of BFS coated with aluminosulfate. Initial uniaxial strength was low, neither was not long term uniaxial strength. It was concluded that silica rich layer($H_2SiO_4^{4-}$) in solid phase early in the reaction of hydration was difficultly moved in liquid phase due to the increase of ZP(Zeta Potential). However, the ZP in the later hydration was decreased due to the acceleration of mobility of silica rich layer($H_2SiO_4^{4-}$). Therefore, long term physical properties such as uniaxial strength revealed.

Electrodeposition of Nano TiO2 Powder Dispersed Nickel Composite Coating (전기도금법을 이용한 나노 산화티타늄 니켈 복합도금에 관한 연구)

  • Park, So-Yeon;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.4
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    • pp.65-69
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    • 2012
  • Composite coating can be manufactured during the electroplating with the bath containing a suspension of particles: ceramic, polymer, nanopowders. Improvement of hardness, wear resistance, corrosion resistance and lubrication properties are well-known advantage of composite coating. In this study, nano $TiO_2$ powder dispersed Ni composite plating was investigated. The improvement of surface hardness and photo decomposition effects can be expected in this coating. Zeta potential was measured with pH. The effect of ultrasonication time and types of ultrasonicator were studied to minimize the agglomeration of $TiO_2$ nanopowders in the electrolyte. Optimum conditions for nano $TiO_2$ dispersed Ni composite coating were $40mA/cm^2$ of current density, pH 3.5, and $50^{\circ}C$. At these conditions, $TiO_2$ nanoparticles contents in the Ni deposit was 15-20 at.%.

Effect of surface treatment on thermo-compression bonding properties of electrodes between printed circuit boards (표면처리에 따른 인쇄회로기판의 열압착 접합 특성 평가)

  • Lee, Jong-Gun;Lee, Jong-Bum;Choi, Jung-Hyun;Jung, Seong-Boo
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.81-81
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    • 2010
  • 전자 패키징은 미세화, 경량화, 저가화를 지향하고 신뢰성의 향상을 위해 발전해 왔다. 이러한 경향은 전자부품 자체의 성능 향상 뿐 아니라 전자부품을 장착, 고정할 수 있게 하는 인쇄회로 기판(PCB : Printed Circuit Board)의 성능에 많은 관심을 가지게 되었다. 전기적 신호의 손실을 줄이기 위해 전기, 전자 산업체에서는 가볍고 굴곡성이 우수한 연성인쇄회로기판(FPCB : Flexible PCB)과 가격이 싸고 신뢰성이 입증된 경성인쇄회로기판(RPCB : Rigid PCB)이 그 대상이다. 본 논문에서는 이 PCB중에서도 RPCB와 FPCB간의 열압착 방식으로 접합 시 전극간의 접합 양상을 보았다. 이 열압착 방식은 기존에 PCB를 접합하는데 사용하고 있는 connector를 이용한 체결법을 대체하는 기술로써 솔더를 중간층(interlayer)로 이용하여 열과 압력으로 접합하는 방식이다. 이 방식을 connector를 사용하는 방식에 비해 그 부피가 작고 I/O개수에 크게 영향 받지 않으며 자동화 공정이 쉬운 장점을 가지고 있다. 접합의 대상 중 RPCB의 경우는 무전해 니켈 금도금(ENIG : Electroless Nickle Immersion Gold)로 제작하였으며 FPCB의 경우는 ENIG와 유기보호피막(OSP : Organic solderability preservation) 처리하였다. 실험에 사용한 PCB는 $300\;{\mu}m$ pitch의 미세피치이며 솔더의 조성은 Sn-3.0Ag-0.5Cu (in wt%)과 Sn-3.0Ag (in wt%)를 사용하였다. 접합 온도와 접합 시간 그리고 접합 압력에 따라 최적의 접합 조건을 도출하였다. 접합 강도는 $90^{\circ}$ Peel Test를 통해서 측정하였으며 접합면 및 파괴면은 SEM과 EDS를 통하여 분석하였다.

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A Study on the Process Conditions of ACA( Anisotropic Conductance Adhesives) for COG ( Chip On Glass) (COG(Chip On Glass)를 위한 ACA (Anisotropic Conductive Adhesives) 공정 조건에 관한 연구)

  • Han, Jeong-In
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.929-935
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    • 1995
  • In order to develop COG (Chip On Glass) technology for LCD module interconnecting the driver IC to Al pad electrode on the glass substrate, Anisotropic Conductive Adhesive(ACA) process, the most promising one among COG technologies, was investigated. ACA process was carried out by two steps, dispensing of ACA resin in the bonding area and curing by W radiation. Load on the chip was ranged from 2.0 to 15kg and the chip was heated at about 12$0^{\circ}C$. In resin, the density of conductive particles coated with Au or Ni at the surface were 500, 1000, 2000 and 4000 particles/$\textrm{mm}^2$, and the diameter of particles were 5, 7 and 12${\mu}{\textrm}{m}$. As a result of the experiments, ACA process using ACA particle of diameter and density of 5${\mu}{\textrm}{m}$ and 4000 particles/$\textrm{mm}^2$ respectively shows optimum characteristic with the stabilzed bonding properties and contact resistance.

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Study on the Artifact pattern representation of a method using digital technology (디지털 기술을 이용한 유물의 문양표현 방법에 대한 연구)

  • Koo, Ja-Bong
    • Journal of Digital Contents Society
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    • v.16 no.1
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    • pp.113-121
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    • 2015
  • Artifact pattern representation of a method using the digital technology is largely are two digital rubbing technique and digital contrast technique. Digital rubbing technique is clearly with the naked eye to see the original prestigious and difficult to build a digital rubbing data patterns by scanning a prestigious and patterns carved into the artifacts in three dimensions without compromising the circle to represent the three-dimensional effect by contrast it to the objective value refers to a technique that can be represented in digital. Digital contrast technique can not be calculated if the depth information of the object due to the glassy film of artefacts in a three-dimensional surface scanning and the application of this technique refers to a realistic image mapped digital technique for generating digital image contrast. Digital rubbing technique is mainly useful to express the most prestigious and patterns expressed in pottery or tile and stone monument, etc. engraved or embossed, digital contrast techniques can be used effectively to artifacts such as magnetic or glass can not be applied to the digital rubbing technique.