• Title/Summary/Keyword: 표면팽창

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Experimental Study of the Internal/external Pressure Variation of TTX Travelling through a Tunnel (한국형 틸팅차량의 터널 주행시 실내/외 압력변화에 대한 실험적 연구)

  • Yun, Su-Hwan;Kwak, Min-Ho;Lee, Dong-Ho;Kwon, Hyeok-Bin;Ko, Tae-Hwan
    • Journal of the Korean Society for Railway
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    • v.12 no.2
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    • pp.309-314
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    • 2009
  • When a train enters into a tunnel, a compression wave is generated by a front nose and a expansion wave is generated by a rear tail respectively. The interaction between pressure waves and the train makes the internal and external pressure of the train change dramatically. In this paper, we had measured the internal and external pressure variations of TTX and analyzed the pressure variations as the tunnel length. Also, the rate of internal pressure variations were investigated with the current airtight condition of TTX. In short tunnels, the internal and external pressure variation were not large because the superposition of pressure waves was not happened. In long tunnels, however, the rapid and large pressure variations were shown because of the superpositions between the same sort of pressure waves, such as expansion wave and expansion wave or compression wave and compression wave. In specific length tunnels, the pressure variation and the pressure variation rates were largely lessened because the compression wave and expansion wave were superposed.

The Kinetics of Montmorillonite Expansion in the Treatment with Hexadecyltrimethylammonium (HDTMA와 반응하는 몬모릴로나이트의 팽창 속도론)

  • Lee Seung Yeop;Cho Won Jin
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.299-307
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    • 2004
  • Surfactant adsorption by two montmorillonite types with different interlayer cations of Ca and Na was characterized by examining the time dependence of surfactant behavior on the clay surfaces. Surfactants with different micelle concentration were conducted in our experiment to observe a nonequilibrium activity of cationic surfactant on the clay over reaction periods ranging from 0.1 min to 11 days. As compared with Ca-montmorillonite (SAz), a more active intrusion of surfactant molecules into the interlayers was found in Na-montmorillonite (SWy). During a short 'initiation' stage, the basal spacing of SWy montmorillonite increased rapidly with logarithmic time. For SAz montmorillonite, however, the abrupt basal spacing increase occurred at the later stage of the reaction. From the result, the difference in the adsorption behavior exhibited by the two montmorillonite types partly results from their intrinsic nature, that is, inorganic cations originally existing on the clay surfaces. Additionally, the micelle concentration of surfactants affects the development of organo-montmorillonite, especially, in the intercalant formation and stabilization under nonequilibrium.

Behavior of Model Pile Embedded in Expansive Soil with Magnesia Oxide-Based Refractories (MgO계 내화물이 함유된 팽창성 지반에서의 모형말뚝 거동 분석)

  • Yoon, Boyoung;Kim, Mintae
    • Journal of the Korean Geotechnical Society
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    • v.39 no.11
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    • pp.33-40
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    • 2023
  • This study explores the performance of pile foundations in highly expansive soil, incorporating magnesium oxide-based refractory materials. A controlled model chamber, housing a fixed pile, was utilized to induce ground expansion through fused magnesia (FM). The investigation focused on measuring the vertical displacement of FM-sand mixtures and the axial load on the pile in relation to depth and time. The study varied the amount of FM content (FMc) at 30%, 50%, and 70%. The upward movement exhibited an augmentation with increasing FMc, tapering off with depth as accumulation progressed toward the mixture surface. Compression and tensile forces were both evident along the pile for FMc at 30% and 50%, while only a tensile force was observed at an FMc of 70%. These results offer valuable insights for the analysis of pile behavior within FM-sand mixtures.

탄소나노플레이트 지지체를 이용한 3차원 구조 탄소나노튜브/탄소나노플레이트 혼성체 합성법

  • Sin, Gwon-U;Park, Ji-Seon;Kim, Yun-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.232.1-232.1
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    • 2015
  • 흑연 박리를 통해 형성된 탄소나노플레이트를 탄소나노튜브 합성을 위한 지지체로 적용하여 탄소나노플레이트 위에 직접 탄소나노튜브를 합성함으로써 3차원 구조의 탄소나노튜브/탄소나노플레이트 나노혼성체를 합성하였음. 흑연의 박리를 통해 탄소나노플레이트를 제조하기 위해서 층간화합물 삽입과 열처리를 통해 팽창흑연을 제조하고, 물리적 분쇄 과정과 액상 고압균질기 방법을 통해 두께 30nm 이하, 수 마이크론 크기의 탄소나노플레이트를 제조하고 동결건조 방법으로 탄소나노플레이트를 제조하였음. 제조된 탄소나노플레이트 상에 탄소나노튜브 합성을 위해서 탄소나노플레이트 표면처리 공정을 적용하였는데, 표면처리 방법 및 물질에 따라 금속 촉매의 담지량 및 담지 형상이 결정되어 합성되어지는 탄소나노튜브의 합성 수율과 합성된 탄소나노튜브의 형성이 다르게 나타났다. 표면처리 방법으로는 산처리방법, 흡착성 고분자 처리법, 무전해 도금법, 무기산화물 처리법이 적용되었다. 또한 담지되는 촉매 종류 및 함량, 조촉매 적용에 따라 탄소나노튜브 합성 거동을 분석하여 최적 촉매시스템을 구축하여 촉매담지체 질량 대비 700% 이상의 고수율의 탄소나노튜브/탄소나노플레이트 혼성체 합성법을 개발하였다.

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Characterization of Cordierite by XPS (Ⅰ) (XPS에 의한 코디에리트의 특성 연구 (연구Ⅰ))

  • Han, Byoung-Sung
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.3
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    • pp.124-129
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    • 1989
  • The cordierite is of great interest for microelectronic packaging. Its main advantages are low dielectric constant and low thermal expansion. The cordierite precursor obtained by sol-gel synthesis whose sintering temperature is about $900^{circ}C$ is an amorphous and cristal white powder. Green and fired cordierite samples were studied by XPS for microscopic properties. At the surface the results of XPS show forte diminution of Mg in comparison with its value at volume and the deficit of Mg compensates by augmentation of Al and Si. $pi$-cordierite phase is present near the surface $<100{\AA}$ and small quantities of magnesium aluminate ($MgAl_2O_4) is present in the bulk. Sintering of the green cordierite introduces no chemical modification at the surface.

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A Study on the Surface Roughness of Corroded Reinforcing Rebar (부식된 철근의 표면 거칠기에 관한 연구)

  • Roh, Young-Sook;Lee, Sun-Gyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.1
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    • pp.78-83
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    • 2010
  • This paper discusses the surface roughness of corroded reinforcement rebar in reinforced concrete structures focusing on the quantitative measurement technique for rebar corrosion. Reinforcement rebar was corroded using accelerated corrosion induced method and corrosion rates were 0%, 1%, 2%, 3%, 5%, and 10% of mass losses. Using 3-dimensional scanner each surface profile of reinforcement rebar was established, and surface roughness was measured. Through tests and analyses of corroded reinforcement rebar, the following topics were particularly discussed: measurement of surface roughness, relationship between area and surface roughness, relationship between surface roughness and bond performance. As a result, surface roughness of corroded rebar was found to be very effective to bond strength until 2% of corrosion rate. It was also discussed how to relate surface roughness of corroded rebar to bond strength of reinforced concrete structures.

Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate (표면코팅 경량골재의 전기저항 특성)

  • Kim, Ho-Jin;Kim, Chang-Hyun;Choi, Jung-Wook;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.727-738
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    • 2023
  • In concrete, the interface between the aggregate and cement paste is often the most critical factor in determining strength, representing the weakest zone. Lightweight aggregate, produced through expansion and firing of raw materials, features numerous surface pores and benefits from low density; however, its overall aggregate strength is compromised. Within concrete, diminished aggregate strength can lead to aggregate fracture. When applying lightweight aggregate to concrete, the interface strength becomes critical due to the potential for aggregate fracture. This study involved coating the surface of the aggregate with blast furnace slag fine powder to enhance the interfacial strength of lightweight aggregate. The impedance of test specimens was measured to analyze interface changes resulting from this surface modification. Experimental results revealed a 4% increase in compressive strength following the coating of the lightweight aggregate surface, accompanied by an increase in resistance values within the impedance measurements corresponding with strength enhancement.

Evaluation of Spalling Property and Water Vapor Pressure of Concrete with Heating Rate (가열 속도에 따른 콘크리트의 폭렬 특성 및 내부 수증기압력 평가)

  • Choe, Gyeong-Cheol;Lee, Tae-Gyu;Nam, Jeong-Soo;Park, Byung-Keun;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.605-612
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    • 2012
  • Spalling of concrete occurs due to vapor pressure ignited explosion, temperature difference across a section, and combination of these factors. Factors affecting spalling can be classified into internal and external factors such as material property and environmental condition, respectively, have to be considered to precisely understand spalling behavior. An external environmental factor such as differences in heating rate cause internal humidity cohesion and different vapor pressure behavior. Therefore, spalling property, vapor pressure and thermal strain property were measured from concrete with compressive strengths of 30 MPa, 50 MPa, 70 MPa, 90 MPa, and 110 MPa, applied with ISO-834 standard heating curve of $1^{\circ}C/min$ heating rate. The experimental results showed that spalling occurred when rapid heating condition was applied. Also, when concrete strength was higher, the more cross section loss from spalling occurred. Also, spalling property is influenced by first pressure cancellation effect of thermal expansion caused by vapor pressure and heating rates.

An Evaluation Technique of Surface Roughness of Corroded Reinforcing Bar-in-Coils (코일철근의 표면 거칠기 물리량 평가 기술)

  • Roh, Young-Sook;Cho, Kang Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6551-6557
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    • 2015
  • This paper discusses the surface roughness of corroded reinforcement rebar-in-coil focusing on the quantitative measurement technique using 3D scanner. Reinforcement rebar-in-coil was stacked in site for 0 day, 3 days, 7 days, 14 days and 21 days. And rebar-in-coil was corroded 0.04%, 0.3367%, 0.6157%, 0.7898%, and 1.1965% respectively. Using 3-dimensional scanner, each surface profile of reinforcement rebar-in-coil was established, and surface roughness was measured. Through the tests and analyses of corroded rebar-in-coil, the increase of fractal dimension for each rebar-in-coil was measured as 0.0216, 0.0235, 0.028, 0.0319, and 0.0455 for different stacked periods. Therefore, surface assessment technique using fractal dimension showed similar results with the actual corrosion rate.

세륨산화물로 전처리된 다공성 니켈 지지체 위에 스퍼터 증착된 팔라듐-구리 합금 분리막 특성

  • An, Hyo-Seon;Gang, Seung-Min;Kim, Dong-Won;Lee, Sin-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.196-196
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    • 2011
  • 팔라듐-구리 합금 분리막은 세륨산화물로 전처리된 다공성 니켈 지지체 위에 마그네트론 스퍼터 공정과 구리리플로우 공정에 의해 제조되었다. 스퍼터 공정은 얇고 치밀한 팔라듐 합금 분리막 증착을 위해 아주 효과적이다. 본 연구에서는 고온 스퍼터 공정에 의해 증착된 팔라듐 상부에 유동성과 열적확산이 우수한 구리를 코팅한 후, 반도체 분야에서 기가 패턴 매립시 사용하는 구리리플로우 공정을 도입하였다. 구리리플로우 공정은 치밀하고 미세기공이 존재하지 않는 표면을 구현하고 무한대의 수소 투과도를 가능하게 한다. 이로써 마그네트론 스퍼터에 의해 $200^{\circ}C$에서 팔라듐과 구리를 순차적으로 코팅한 후, $700^{\circ}C$에서 2시간 구리리플로우 공정을 실시하여 $7.5{\mu}m$ 두께의 팔라듐-구리 합금 분리막이 제조되었다. 세륨산화물(CeO2)은 고온에서 장시간 운전하는 동안 다공성 니켈 지지체의 금속성분이 팔라듐 합금층으로 확산하는 금속의 확산 문제를 개선하고자 지지체와 코팅층 사이에 확산방지막으로 도입되었으며, 균일한 스퍼터 증착을 위해 평탄한 표면의 지지체를 구현하였다. 투과도 테스트는 100-400kPa 의 압력차, 673-773K 의 온도 조건에서 순수한 수소가스로 실시하였다. 표면 미세기공이 없는 치밀한 팔라듐-구리 합금 분리막은 혼합가스에서 질소의 투과 없이 수소만을 투과하는 무한대의 우수한 분리도를 나타내었으며, 상용온도 $500^{\circ}C$에서 12.6ml/$cm^2{\cdot}min{\cdot}atm$의 수소 투과 능력을 보였다. 본 연구에 의해 제조된 팔라듐-구리 합금 분리막은 표면 미세기공이 없는 치밀한 분리막 제조를 가능하게 하였으며 열팽창계수가 팔라듐과 매우 비슷한 세륨산화물($CeO_2$)로 인해 지지체층과 코팅층과의 접합력이 향상되고 수소취성에 강하고 높은 열적 안정성을 갖는다.

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