• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.9
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• pp.3125-3134
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• 2010

Three-way catalyst durability in the Korea requires 5 years/80,000km in 1988 but require 10 years/120,000km after 2002. Domestic three-way catalyst satisfies exhaust gas conversion efficiency or pressure drop etc. but don't satisfy thermal durability. Three-way catalyst maintains high temperature in interior domain but maintain low temperature on outside surface. This study evaluated thermal durability of three-way catalyst by thermal flow and structure analysis and the procedure is as followings. Thermal flow parameters ranges were determined by vehicle test and basic thermal flow analysis. Response surface for rear catalyst temperature was constructed using the design of experiment (DOE) for thermal flow parameters. Thermal flow parameters for rear catalyst temperature in vehicles examination were predicted by desirability function. Temperature distribution of three-way catalyst was estimated by thermal flow analysis for predicted thermal flow parameters.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.615-618
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• 2003

This paper presents Bi thin films have been fabricated by atomic layer-by-layer deposition and co-deposition at an IBS method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(l00) was used as a substrate. In order to appreciate stable existing region of Bi 2212 phase with temperature and ozone pressure, the substrate temperature was varied between 655 and 820 $^{\circ}C$ and the highly condensed ozone gas pressure(PO$_3$) in vacuum chamber was varied between 2.0$\times$10$^{-6}$ and 2.3$\times$10$^{-5}$ Torr. Bi 2212 phase appeared in the temperature range of 750 and 795$^{\circ}C$ and single phase of Bi 2201 existed in the lower region than 785 $^{\circ}C$. Whereas, PO$_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with T$_{c}$(onset) of about 90 K and T$_{c}$(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as CaCuO$_2$ was observed in all of the obtained films.lms.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.507-507
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• 2013

유리기판으로 투과되는 빛들 중에는 내부 전반사나 wave-guided mode로 인하여 손실이 일어나 일반적으로 20%의 광추출 효율을 가진다. 이러한 문제점을 해결하기 위한 연구에는 Photonic Crystal과 같은 주기적인 나노 구조물이 있는데 이러한 구조물을 제작하기 위한 마스크 공정 과정은 대부분 복잡하거나 비싼 단점이 있다. 이에 본 발표에서는 마스크 없이 비정질소다라임 유리의 구조물 생성으로 광 추출 효율이 상승하는지 보고자 하였다. M-ICP (Magnetized-Induced Coupled Plasma)란 용량 결합형 플라즈마와 유도 결합형 플라즈마 두 가지 방식의 플라즈마를 이용한 것인데 용량 결합형 플라즈마를 이용해 이온이 sheath에 의해 가속되어 유리표면에 부딪히고 그에 따라 유리가 식각되는 물리적 식각을 이용하였다. 또한 이온의 밀도를 조절하기 위해 유도결합형 플라즈마 방식을 이용하여 식각률을 높였다. 화학적 식각을 위해서는 CF4와 O2혼합 가스를 이용해 F가 Si와 결합하여 SiF4가 되어 사라지고 탄소잔여물인 C는 O2와 반응하여 제거하였다. 그 결과, 랜덤한 분포를 가지는 미세한 구조물(stochastic sub-wavelength structure)을 유리 표면에 형성할 수 있었고, 또한 다양한 가스 종류와 압력, source power와 bias power, 그리고 시간을 바꿔가며 미세 구조물들을 관찰하였다. 실험 결과, 가시광선 파장 이하의 높이를 갖고 수 마이크로미터의 너비를 갖는 구조물이 전반사되는 빛을 효율적으로 추출하는 것을 산란되는 빛의 정도인 diffusive transmittance 가 기존 0%에서 15% 정도로 증가하는 것으로 스펙트로포토미터 측정을 통해 확인하였다. 이러한 유리 기판 위 구조물 생성방법을 OLED에 적용한다면 적은 비용으로 소자의 효율을 크게 향상 시킬 수 있을 것이다. 또한 본 처리 과정의 장점은 기존의 방법에 필요한 스퍼터링이나 RTA 처리 과정이 필요 없어 공정 단가 절감과 제조 공정의 단순화로 높은 생산성을 얻을 수 있으며 대면적화에도 유리하다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.1
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• pp.62-68
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• 2009

The interaction between wall blowing and oxidizer flow can generate a very complicated flow characteristics in combustion chamber of hybrid rockets. LES analysis was conducted with an in-house CFD code to investigate the features of turbulent flow without chemical reactions. The numerical results reveal that the flow oscillations at a certain frequency exists on the fuel surface, which is analogous to those observed in the solid propellant combustion. However, the observation of oscillating flow at a certain frequency is only limited to a very thin layer adjacent to wall surface and the strength of the oscillation is not strong enough to induce the drastic change in temperature gradient on the surface. The visualization of fluctuating pressure components shows the periodic appearance of relatively high and low pressure regions along the axial direction. This subsequently results in the oscillation of flow at a certain fixed frequency. This implies that the resonance phenomenon would be possible if the external disturbances such as acoustic excitation could be imposed to the oscillating flow in the combustion chamber.

• Food Science and Preservation
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• v.13 no.3
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• pp.363-368
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• 2006

This study was performed to develop flavor materials from Elsholtzia ciliata Hylander with analyzing functionality and aroma profile and to optimize supercritical fluid extraction method and optimum condition. The qualities of water extracts such as total yield total phenolic compound electron donation ability, estragole and L-carvone, were affected by extraction pressure than time. The response variables had significant with pressure than with time and the established polynomial model was suitable(P>0.05) model by Lack-of-Fit analysis. The optimum extraction conditions which were limited of maximum value for dependent variables under experimental conditions based on central composite design were 238 bar and 42 min.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.2
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• pp.185-190
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• 1997

The 6H-SiC single crystals were grown using a self-designed crystal grower by the sublimation method. The grown crystals were typically 30 mm in diameter and 10 mm in length. Optimum growth conditions were established as follows : the temperature of the raw material was $2150~2250^{\circ}C$, the temperature of the substrate was $1950~2050^{\circ}C$, the temperature difference between the raw material and substrate was about $200^{\circ}C$, growth pressure was 50~200 torr and growth rate was 300~700 $\mu\textrm{m}$/hr. Optical microscopy was used for observing the surface of the 6H-SiC single crystal grown and the phenomenological approach was performed on the formation mechanism of the defects in the 6H-SiC crystal. Especially, the micropipes in the as-grown surface were examined to determine the formation mechanisms of the micropipes.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.22 no.2
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• pp.248-255
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• 2013

The objective of this study is to optimize the Metal Injection Molding(MIM) process with design of experiments(DOE) and numerical analysis. To derive the optimal process condition, experiment or numerical analysis was performed under various process conditions. To analyze the interaction among influential factors contributing to the temperature at flow front and response surface in MIM, both central point and axial point were added to the full factorial design with 2 levels and 5 factors and then their impacts on response variable in 43 experimental conditions were analyzed and the significance was evaluated. As a result, sprue, runner, and gate were completely filled in about 0.247 seconds after injection, the front part of the green body was filled in about 0.3344 seconds, the green body except gate, etc changed to almost solid state in about 3.29 seconds, the Packinging pressure was completed in about 6.29 seconds, and the green body inside and outside and sprue, etc became solid in 13.2 seconds. The impact of individual or reciprocal action of factors on the temperature at flow front was analyzed through regular probability, test statistics, main effect, and interaction effect. As a result, of a total of 31 combinations of factors, 9 unit factors and reciprocal actions were significant, and the screening was also possible. A proper regression equation was drawn with regression analysis and response surface design on the response variable of temperature at flow front, and the applicability could be verified.

• Transactions of the KSME C: Technology and Education
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• v.3 no.3
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• pp.193-199
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• 2015

Sloshing of LNG cargo can cause high impact loads on the supporting and containing structures. This is particularly critical for membrane-type tanks since these will have flat surfaces and corner regions which can lead to increased peak pressures for sloshing impacts. The membrane-type containment system is much more flexible compared to the steel hull structure. As a result, fluid-structure interaction plays an important role in the structural analysis of the containment system under sloshing load. This study is based on the direct calculation method of applying sloshing loads to the KC-1 basic insulation system using finite element analysis. The structural analysis of KC-1 basic insulation system considers the dashpot as fluid-structure interaction between liquid cargo and the LNG containment system. The maximum stress of the polyurethane form for KC-1 insulation system is 1.5 times lower than one without dashpot.

• The Journal of the Acoustical Society of Korea
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• v.37 no.4
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• pp.163-173
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• 2018

This paper performed the prediction of the acoustic loads applied to the surface of the flight vehicle during flight. Acoustic loads during flight arise from the pressure fluctuations on the surface of body. The conventional method of predicting the acoustic loads in flight uses semi-empirical method derived from theoretical and experimental results. However, there is a limit in obtaining the flow characteristics and the boundary layer parameters of the flight vehicle which are used as the input values of the empirical equation through experiments. Therefore, in this paper, we use the hybrid method which combines the results of CFD (Computational Fluid Dynamics) with semi-empirical methods to predict the acoustic loads acting on flight vehicle during flight. For the flight vehicle with cone-cylinder-flare shape, acoustic loads were estimated for the subsonic, transonic, supersonic, and Max-q (Maximum dynamic pressure) condition flight. For the hybrid method, two kind of boundary layer edge estimation methods based on CFD results are compared and the acoustic loads prediction results were compared according to empirical equations presented by various researchers.

• Journal of the Korean Chemical Society
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• v.22 no.6
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• pp.370-379
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• 1978

The specific rate constants for the oxidation reactions of carbon monoxide on a unit catalytic surface area were measured. The catalysts used were NiO made from $Ni(NO_3)_2,\;and\;Ni(OH)_2$, and Mn$O_2$ made from Mn$(NO_3)_2$. At low pressure the reaction rate was found to be of second order and the activation energies were 12 kcal/mole (on NiO made from Ni$(NO_3)_2$, 17 kcal/mole (on NiO made from Ni$(OH)_2)$) and 18 kcal/mole (on Mn$O_2$). Plausible reaction mechanisms were proposed from the experimentally determined reaction orders.