• Title/Summary/Keyword: 표면수식

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Analysis For Surface Roughness of Fabric by Using FFT (FFT를 이용한 직물의 표면거칠기 해석)

  • 문지성;권영하;강대임;박연규
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 1999.11a
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    • pp.383-387
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    • 1999
  • 인간의 감성을 고려하는 제품의 생산에서 촉감은 인간이 제품을 만질 때 직접적으로 느낄 수 있는 중요한 감각이다. 이러한 촉감의 연구를 위해 직물을 대상으로 직물 표면의 거칠기를 측정하고 해석하였다. 측정된 표면 거칠기를 Fast Fourier Transform 변환하여 직물구조를 분석하는 기준으로 하였다. 각 peak 값들을 분석하여 나온 값이 직물 구조를 수식화하여 사용할 수 있는 좋은 방법이 됨을 알았다. 또한, 실의 잔털량을 측정하여, 잔털량과 인간의 주관적인 감각을 대표하는 값과의 상관관계를 조사하였다. 잔털량이 인간의 주관적인 감각을 객관적으로 표현할 수 있는 한 요소로 사용될 수 있다는 것을 확인하였다.

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Voltammetric Determination of Dopamine with the N-Hydroxysuccinimide Modified Carbon Paste Electrode (N-히드록시숙신이미드로 수식한 탄소반죽전극을 이용한 도파민의 전기화학적 측정)

  • Yoo Jae Hyun;Yoo Byung Wook;Kim Soon Shin;Uhm Jung Hee;Nam Hakhyun;Cha Geun Sig
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.109-112
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    • 2001
  • An activated carbon paste electrode was modified with the N-Hydroxysuccinimide(NHS) layer and applied to determine the dopamine in the presence of an excess ascorbic acid using square-wave voltammetry. The electrochemical properties of the modified electrode were examined in the solution containing dopamine/ascorbic acid using cyclic voltammetry(CV): the separation between the oxidation peaks of dopamine and ascorbic acid was largely dependent on the pH of the sample solution and became maximum at pH 4.0. Hence, the square-wave voltammetric determination of dopamine was carried out in a pH 4.0, 100mM phosphate buffer saline(PBS) containing 140mM NaCl. The detection limit and response slop were improved from $1.0{\mu}M\;to\;5.0\times10^{-2}{\mu}M\;and\;from\;0.93{\mu}A/{\mu}M\;to\;6.1{\mu}A/{\mu}M$, respectively, upon modification of the electrode surface by NHS.

음함수 모델 애니메이션 기술

  • 윤재홍;김은석;허기택
    • Review of Korea Contents Association
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    • v.2 no.1
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    • pp.34-42
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    • 2004
  • 음함수 곡면은 물체 표면을 직접 정의하지 않고 영역 구분 함수를 통해 물체를 포함하는 공간상의 모든 점들의 관계를 정의함으로써 간접적으로 표현하는 방법이다. 음함수 곡면을 이용한 모델링은 함수나 수식을 이용하여 물체를 표현하기 때문에 표면의 위치를 찾기 위한 계산이 필요하지만, 및 가지의 함수 정의만으로 복잡한 형태의 곡면을 직접 표현할 수 있으며 주어진 모델로부터 서로 다른 품질의 이미지를 제공할 수 있다는 장점을 갖는다.(중략)

Differential Pulse Voltammetric Determination of Iron(II) ion with a Nafion-Ethylenediamine Modified Glassy Carbon Electrode (Nafion-ethylenediamine이 수식된 유리탄소전극에 의한 시차펄스전압전류법으로 철(II) 이온의 정량)

  • Kyong Wone Kim;Hee Cheol Kim;Sung-Hyun Kim;Byung Ho Park;Yeon Hee Kim;Kyong Nam Kim;Yong Chun Ko
    • Journal of the Korean Chemical Society
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    • v.47 no.2
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    • pp.115-120
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    • 2003
  • Determination of iron(II) ion with a perfluorinated sulfonated polymer(nafion)-ethylenediamine(en) modified glassy carbon electrode was studied. It was based on the chemical reactivity of an immobilized layer(nafion-en) to yield complex $[Fe(en)_3]^{+2}$. The oxidation peak potential by differential pulse voltammetry(DPV) was observed at 0.340${\pm}$0.015 V(vs. Ag/AgCl). The linear calibration curve was obtained in iron(II) ion concentration range $5{\times}10^{-6}{\sim}0.2{\times}10^{-3} M(0.28{\sim}11.17\; mg/L)$, and the detection limit(3s) was $1.89{\times}10^{-5}$M(1.056 mg/L).

Electrocatalytic Oxidation of NADH at the Modified Graphite Electrode Incorporating Gold Nano Particles (금 나노입자를 회합시킨 수식된 흑연전극으로 NADH의 전기촉매 산화반응)

  • Cha, Seong-Keuck;Han, Sung-Yub
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.1-6
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    • 2007
  • Mercaptopropionic acid(mpa) has been used to make self-assembled monolayer(SAMs) on the surface of graphite electrode incorporating gold nano particles, which are subsequently modified with dopamine(dopa). Such modified electrodes haying types of Gr(Au)/mpa-dopa were employed in the electrocatalytic oxidation of NADH. The responses of such modified electrodes were studied in terms of electron transfer kinetics and reaction procedure in the reaction. The reaction of the surface immobilized dopa with NADH was studied using the rotating disk electrode technique and a value of $5.06{\times}10^5M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M phosphate buffer(pH=7.0), which was a $EC_{cat}$ and kinetic controlled procedure. But, the modified electrodes were diffusion controlled reaction having $4.64{\times}10^{-4}cm^2s^{-1}$ of the coefficient within $10^{-3}s$ after starting the reaction.

Development of Target-Specific Drug Delivery Systems Using Glycosylated Proliposome I-Binding of Asialofetuin-Labeled Liposomes to Lectin RCA- (표면수식된 프로리포솜에 의한 표적부위 지향성 약물수송체의 개발 I-갈락토스 당쇄로 표면수식된 리포솜의 간세포 렉틴 결합성-)

  • Shim, Chang-Koo;Lee, Chang-Yong;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.22 no.2
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    • pp.155-161
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    • 1992
  • Although glycosylated liposomes have attracted much attention as targeting delivery systems (DDS) of drugs to specific organs which have glycoside receptors, physical instability of liposomes greatly limits their practical application. In this case, proliposomes might be a potential answer to solve this problem. Utilizing the proliposomes as tageting DDS has been a goal of our series of works; we have tried to develop DDS which form liposomes uppon adding water and can deliver drugs to specific target organs/cells such as hepatocytes. In this paper, preparation of glycosylated liposomes and binding of the liposomes with lectin (agglutinin RCA 120) was studied. Asialoletuin (AF) was selected as a model compound which has galactose terminal and is favorable for binding with galactose receptor on the surface of hepatocytes. AF was obtained by splitting the terminal N-acetylneuraminic acid (NANA) of fetuin. Small unilamellar AF-liposomes were prepared by mixing aqueous solution of AF-palmitate with thin film of phosphatidyl choline and cholesterol (30:10 w/w) formed on the innersurface of the round bottomed flask. They were successively extruded through polycarbonate membranes (0.45 mm). Palmitoyl-AF not incorporated into the liposomal bilayer was separated from liposomes by a Sepharose 4B column equilibrated with 10 mM Tris-HCI buffered saline. Lectin (agglutinin RCA 120) was added to the suspension of AF-liposomes and incubated at $37^{\circ}C$ for 2 hr. After centrifugation, the unbound lectin in the supernatant was assayed for protein. The binding of the lectin to AF-liposomes (AF content 2.8 nmole) at $37^{\circ}C$ was linear at least upto 35 mg of lectin indicating high affinity association of the lectin to AF molecules of the liposomes.

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The Electrocatalytic Reduction of Molecular Oxygen with Clay Modified Electrodes (점토광물을 이용한 산소환원의 전기화학적 촉매성에 관한 연구)

  • Oh Sung-Hun;Hwang Jin-Yeon;Shim Yoon-Bo;Lee Hyomin;Yoon Jihae
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.1-9
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    • 2005
  • The electrocatalytic reduction of O₂ was investigated with methyl viologen and methylene blue incorporated clay-modified electrodes. Clay suspensions were prepared with Na-montmorillonite, Ca-montmorillonite, and kaolinite. The methyl viologen-clay modified electrodes were made by coating clay suspensions adsorbing methyl viologen on a glassy carbon electrode. Cyclic voltammetry were performed in aqueous media to investigate the electrocatalytic property of the modified electrode in reducing O₂. A Na-montmorillonite modified electrode showed the greatest adsorption capacity for methyl viologen. The modified electrode made of Na-montmorillonite suspension of 0.87 g/10 mL and a 2.5 mM of methyl viologen solution showed the most effective electrocatalytic property, where the catalytic reduction potential was shifted by 242.6 mV toward the positive potential. The electrocatalytic ability was more significant in acidic (pH=3.7) and alkaline (pH=12.7) media than the neutral pH range (6.3∼8.3). The methyl viologen-Na-montmorillonite modified electrode had the good reproducibility and maintain the electrocatalytic property over 20 times reuse.

Electrocatalytic Oxidation of NADH at Electrodes of Self-assembled Monolayers Modified with Dopamine (도파민으로 수식된 SAMs 전극에서 NADH의 전기촉매에 의한 산화)

  • Cha, Seong-Keuck
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.151-155
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    • 2004
  • The self-assembled mololayers(SAMs)were prepared with cysteine(cys) and subsequently coupled with dopamine(dopa) containing quinone functionality on the gold modified electrodes. The SAMs annealed in ethanol for 6 hours gave a better shaped cyclic voltammogram which had a 0.28 V of formal potential and same redox potential in 0.1M phosphate buffer(pH=7.10). The electrodes were employed to determine concentration of HADH with the result that calibration curve exhibited an excellent correlation(${\geq}$ 0.993) for the concentrations ranging up to 5.0${\times}10^{-4}$ M.

Gas Separation by Polyimide.Silica Composite Membrane (폴리이미드/실리카 복합막에 의한 가스분리)

  • 송병준;김건중;남세종
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.71-72
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    • 1997
  • 1. 서론 : 공기중의 산소분리용 고분자막은 높은 선택도를 동시에 요구한다. 이 두가지 조건을 만족시키는 소재 개발과 기존의 고분자물질을 수식하는 연구가 진행되고 있다. 고분자막에 대한 수식방법으로는 UV처리, plasma처리등이 있으나, 이들 방법은 선택도는 증가시키나 투과도를 감소시키는 경향이 있다. 기체의 투과저항을 줄이기 위하여 다공성 지지체 위에 박막을 입힌 복합막과 박막의 skin layer와 sub-layer를 갖는 비대칭막은 투과저항을 줄일수 있으나 선택도는 고분자 고유의 80%정도까지 감소되는 것으로 알려졌다. 본 연구의 목적은 고분자 복합막의 투과분리특성을 향상시키기 위한 것으로 지지층의 세공과 표면에 실리카/고분자를 충전, 피복시켜 투과분리특성을 조사하였다. 현재까지의 연구는 낮은 투과계수와 높은 선택도를 갖는 고분자물질이 사용되었으나, 본 연구에서는 폴리이미드로는 폴리이미드 중에서 투과계수가 가장 높다고 알려진 6FDA-p-TeMPD[{(3,3',4,4'-dicarboxyphenyl)hexafluoropropanedianhydride}-{2,3,5,6-Tetra-methyl-1,4-phenylenediamine}] 폴리이미드를 택하였으며 다공성지지체는 aluminum oxide를 사용하였다 . 본 실험에서는 선택도와 투과속도에 주로 영향을 미치는 폴리이미드와 실리카의 양에 대하여 고찰하였다.

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Optimization of the surface structure of reflector for reflective LCDs (반사형 LCD용 반사판의 표면구조의 최적화)

  • 김홍철;박원상;황용석;윤태훈;김재창
    • Korean Journal of Optics and Photonics
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    • v.13 no.2
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    • pp.166-170
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    • 2002
  • Reflectors for reflective LCDs must be designed to be able to control the direction of the image and the viewing angle range for optimal display. In this paper, we tried to optimize the reflector for reflective LCDs. The conventional surface structures showed many defects and problems. Therefore we made efforts to improve the surface structures of the conventional reflectors through both a theoretical approach and analytic work. As a result, we proposed surface structures which showed almost uniform reflectance within the viewing angle range specified by a user even at any oblique incidence. By using Beckmann's equations, we could check the reflective property of the proposed surface structures.