• Title/Summary/Keyword: 폴리올레핀

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A Study on the Field Application of Superior Recycled Pavement of the Waste Asphalt (고품질 재활용 아스팔트 혼합물의 현장적용성에 대한 연구)

  • Kim, Jiwon;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.2
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    • pp.67-73
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    • 2012
  • Asphalt pavement waste can be recycled by crushing and heating methods with additional virgin materials and additives. In this study, a new additive using Sasol wax and Polyolefin elastomer was used for improving the quality of the Superior recycled asphalt pavement(SRP). Additive was added into the recycled mixture by 1.5% and 3% of binder content in order to have PG 70-22 and PG 76-22. Both mixtures were tested by Marshall apparatus, indirect strength testing methods, toughness testing methods, moisture susceptibility testing methods and wheel tracking testing methods. Test results met the standards of KS F 2349 and GR F 4005. Through research, it was found that these special recycled mixtures could be applied for the surface and base course of heavy traffic roads or equivalents. About 13,000 tons of the recycled mixture has been applied on Seoul Olympic road to provide new road to Hangang park for Seoul citizens.

Nano Ceramic Coating on Polypropylene Separator for Safety-Enhanced Lithium Secondary Battery (고안전성 리튬이차전지 구현을 위한 나노 세라믹 코팅 분리막 제조 및 전기화학특성 분석)

  • Lee, Jungmo;Jeon, Hyunkyu;Han, Taeyeong;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.41-48
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    • 2017
  • Herein, we have fabricated an ultrathin aluminum oxide ($Al_2O_3$) coated PP separator by using a RF sputter deposition process. Approximately 20 nm thickness coating layer on the bare PP separator was formed at the power of 55 W for 2 minutes without thermal damage. Whereas only permeability of the coated separator was degraded slightly, other properties such as thermal stability, uptake amount of liquid electrolyte, and ionic conductivity were improved comparing to the bare PP separator. As a result, an only 20-nm-thick $Al_2O_3$ coating layer could improve the rate capability compared with a bare PP separator under a high current density.

Synthesis of High Functionalized Anion Exchange Fibers Using Hybrid Polyolefine by $\gamma-Ray$ Mutual Radiation (방사선 동시조사법을 이용한 고관능성 Hybrid Polyolefine 음이온교환섬유의 합성)

  • Cho In-Hee;Kwak Noh-Seok;Kang Phil-Hyun;Nho Young-Chang;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.217-223
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    • 2006
  • Ion exchange fibers, high functionalized onto hybrid polyolefine fiber's surface, were synthesized by $\gamma-ray$ mutual radiation. Degree of grafting (DG) of copolymer increased with increasing GMA monomer concentration and the maximum rate of DG was 355% at 50 GMA. The graft reaction occurred in polar solvent and DG was 190% maximum value in $1.0\times10^{-3}$ Mohr's salt and 0.1 M sulfuric acid, respectively. The amination for graft copolymers varied depending on amine reagents, and the reactivity for copolymers was highest for methylamine, and that of triethylamine lowest. It was shown that water uptake and ion exchange capacities increased with increase in the rate of amination while surface area decreased rapidly as proceeding for graft reaction and amination.

Characterization and 3D Analysis of PETG/POE Thermoplastic Composites (PETG/POE 열가소성 복합재료의 특성평가 및 전산해석)

  • Yu, Seong-Hun;Lee, Jong-Hyuk;Sim, Ji-Hyun
    • Composites Research
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    • v.32 no.6
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    • pp.360-367
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    • 2019
  • In order to apply thermoplastic composites using PETG resin to various industrial fields such as bicycle frames and industrial parts, it is necessary to verify the impact resistance, durability, mechanical properties and 3D analysis of the manufactured composite materials. To improve the mechanical properties, durability and impact resistance of PETG resin, an amorphous resin, in this study, compound and injection molding process were carried out enhanced various weight percent POE(polyolefin elastomer). The thermal and mechanical properties of the thermoplastic composites, and the charpy impact strength, The analysis was performed to evaluate the characteristics according to weight percent of POE. Charpy impact strength test was conducted to analyze the impact characteristics, and the fracture section was analyzed after the impact strength test. In the case of POE material-added thermoplastic composites, thermal and mechanical properties tend to decrease, but workability and impact resistance tend to be superior to those of PETG materials.

Model Predictive Control of the Melt Index in High-Density Polyethylene(HDPE) Process (고밀도 폴리에틸렌 공정의 Melt Index 모델예측제어에 관한 연구)

  • Lee, Eun Ho;Kim, Tae Young;Yeo, Yeong Koo
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1043-1051
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    • 2008
  • In polyolefin processes melt index (MI) is the most important controlled variable indicating product quality. Because of the difficulty in the on-line measurement of MI, a lot of MI estimation and correlation methods have been proposed. In this work a new dynamic MI estimation scheme is developed based on system identification techniques. The empirical MI estimation equation proposed in the present study is derived from the $1^{st}$-order dynamic models. Effectiveness of the present estimation scheme was illustrated by numerical simulations based on plant operation data including grade change operations in high density polyethylene (HDPE) processes. From the comparisons with other estimation methods it was found that the proposed estimation scheme showed better performance in MI predictions. Using the model predictive control method based on the present dynamic MI estimation model, MI values are estimated and compared with those of MI setpoints. From the numerical simulation of the proposed control system, it was found that significant reduction of transition time and the amount of off-spec during grade changes were achieved.

Controlling Water Splitting Characteristics of Anion-Exchange Membranes by Coating Imidazolium Polymer (이미다졸륨 고분자 코팅을 통한 음이온교환막의 물분해 특성 제어)

  • Kim, Do-Hyeong;Park, Jin-Soo;Kang, Moon-Sung
    • Membrane Journal
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    • v.25 no.2
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    • pp.152-161
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    • 2015
  • In this study, novel pore-filled anion-exchange membranes (PFAEMs) with low electrical resistance, high permselectivity, and low water-splitting flux property under a concentration polarization condition have been developed for the enhancement in the efficiency of electrochemical water treatment processes. The base membranes have been prepared by filling a copolymer containing quaternary ammonium groups with an excellent ion-exchange capability into a porous polyolefin substrate, showing a high performance superior to that of a commercial membrane. In addition, it was confirmed that the electrochemical membrane performances are preserved while the water-splitting flux is effectively controlled by coating an imidazolium polymer onto the surface of the base membrane. The prepared PFAEMs revealed remarkably low electrical resistances of about 1/6~1/8 compared to those of a commercial membrane, and simultaneously low water-splitting flux comparable with that of cation-exchange membranes under a concentration polarization condition.

A Study on the Dielectric Characteristics of Non-Cross Linked Polyolefin for Distribution Power Cables (배전용 전력 케이블을 위한 비-가교 폴리올레핀 재질의 절연특성 연구)

  • Kim, Junil;Lee, Onyou;Bang, Seungmin;Kang, Jong O;Lee, Hongseok;Jeong, Yeong-Ho;Kang, Hyoungku
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.4
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    • pp.373-377
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    • 2014
  • A cross linked polyethylene (XLPE) material has been widely used to develop a distribution power cable due to its excellent electrical characteristics and mechanical strength. However, several problems such as environmental disruption, electrical aging, thermosetting property, and impurities which cause degradation also arise. Therefore, a novel dielectric material should be developed to substitute for the XLPE. Several kinds of polyolefin materials to substitute for the conventional dielectric material, XLPE are developed and A cylindrical rod to cylindrical rod electrode system made with stainless steel is used to perform the experiments according to the ASTM D-149 protocol under an AC and Impulse input voltage condition. The experimental results are calculated by the Weibull distribution method and analyzed by an Finite Element Method(FEM). Finally, the dielectric characteristics of the conventional XLPE and novel polyolefin are experimented compared with each other in this study.

A Study on the Selectively Block Barrier for Prevent the Spread of TPH and Phenol in the Ground (지중 내 TPH, Phenol의 확산방지를 위한 선택적 차수재 제조에 관한 연구)

  • HoJin Lim;WooRi Cho;SeungJin Oh;SuHee Kim;JaiYoung Lee
    • Journal of the Korean Geosynthetics Society
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    • v.23 no.1
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    • pp.1-7
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    • 2024
  • In this study, a selecvively block barrier was developed to prevent the spread of contaminants (TPH, Phenol) in the ground only when contamination occurs. The materials were used Jumunjin sand, bentonite, polyolefin elastomer and spill hound marine. First, the properties and environmental hazards characteristics of materials were analyzed for evaluated their usability. Then, the possibility of use as a barrier material was confirmed by analyzing the water permeability characteristics that change after 24 hours of contact with contaminants. As a result of the analysis, the pH of each component was similar to the general groundwater pH range. In addition, the toxicity characteristics and the possibility of dissolution of hazardous substances, it was determined that there was no environmental hazard as the content was below the regulation value. Lastly, when comparing the permeability coefficient before and after contact with the contaminant, the permeability coefficient of approximately α × 10-3cm/sec before contact was reduced to α × 10-6cm/sec after contact with the contaminant.

Fire Resistance Characteristics of Polyolefin cable Insulating Materials for Flame Retardant (난연성 폴리 올레핀 케이블 절연재료의 내화특성)

  • Yoon, Hun-Ju;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.251-254
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    • 2001
  • In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC 600[V] wire. Messurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflaming pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of $2.5{\pm}0.04[w/cm^{2}]$ for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomplete combustion of FR-PVC which has high content of carbon in compound.

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Fire Resistance Characteristics of Polyolefin cable Insulating Materials for Flame Retardant (난연성 폴리 올레핀 케이블 절연재료의 내화특성)

  • 윤헌주;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.251-254
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    • 2001
  • In this paper, we analysed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC [600] wire. Measurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflamining pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds generated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5${\pm}$0.04[w/$\textrm{cm}^2$] for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 7.2 to 77.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomp1ete combustion of FR-PVC which has high content of carbon in compound.

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