• Title/Summary/Keyword: 폴리아미드12

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폴리아미드(나일론)

  • 한국골판지포장공업협동조합
    • Corrugated packaging logistics
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    • no.48 s.11
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    • pp.67-68
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    • 2003
  • 폴리아미드는 산 아미드결합(-CO-NH-)에 의해 구성되는 고분자화합물로 나일론으로 알려져 있다. 나일론은 미국 듀퐁사의 상품명인데 폴리아미드대신 사용되고 있다. 나일론6, 나일론66, 나일론610, 나일론11, 나일론12, 나일론46, 나일론MXD6등이 제조되고 있다. 이들 가운데 가장 많이 사용되고 있는 것이 나일론6, 나일론66이다.

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Study on Tensile Properties of Polyamide 12 produced by Laser-based Additive Manufacturing Process (레이저 적층제조기술로 제작한 폴리아미드 12 시편의 인장특성 연구)

  • Kim, Moosun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.11
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    • pp.217-223
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    • 2019
  • The application of 3D printing technology is expanding due to the production of the complex-shape parts and the one-step manufacturing process. Moreover, various technical solutions in 3D printing are emerging through continuous research and development. Representative technologies include SLS technology, in which a desired area is sintered and laminated by irradiating a powder-type material with a laser. In addition, high-performance engineering plastic parts are being manufactured in increasing numbers. In this study, tensile specimens were fabricated from polyamide 12, a widely available polymer, and the glass bead-reinforced polyamide 12. The specimen-build orientation was divided into 0°, 45°, and 90° on the fabrication platform, and the tensile test temperature was -25℃, 25℃, and 60℃. The test results showed that the tensile modulus of both materials decreases as the build orientation becomes closer to 90°. In addition, the tensile strength of glass bead-reinforced PA12 showed more dependence on the build orientation than PA12. In addition, the tensile modulus and tensile strength decreased with increasing test temperature.

Characterization of Poly(ether-block-amide)s Prepared from Oligomeric Polyamide 12 via Dispersion Polymerization (분산중합에 의한 폴리아미드 12 올리고머의 제조와 그를 이용한 Poly(ether-block-amide)의 특성)

  • Kim, Doo-Hyeon;Lee, Ji-Hun;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.513-518
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    • 2012
  • Polyamide 12 (PA12) oligomers (oPA1) were prepared by dispersion polymerization of ${\omega}$-amino carboxylic acid and dibasic acid in a dispersion medium, thermally stable hydrocarbon liquid paraffin, YK-D130 (a step polymerization). The molecular weight and various properties of other oligomeric PAs (oPA2) obtained by bulk polymerization without the medium were compared with those of oPA1s. The oPA1s showed lighter white color and narrower molecular weight distribution than oPA2s at the same molecular weight. Moreover elastomeric poly(ether-block-amide) (PEBA)s were synthesized with oPA1 and oPA2 as hard segments and poly(tetramethylene glycol) (PTMG) as a soft segment. The molecular weight distribution, and mechanical property of the PEBA originated from the both oligomeric PAs were characterized.

Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives- (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성-)

  • Chun, Young-Sik;Hong, Young-Keun;Chung, Kyung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.194-202
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    • 1996
  • Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

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Preparation of Polyamide Thin Film Composite Memrbanes with Metal Complex Contained Polysulfone Support Layer and Evaluation of Forward Osmosis Performance (금속 착물을 함유한 폴리술폰 지지층을 이용한 폴리아미드계 복합막의 제조 및 정삼투 성능 평가)

  • Kim, Nowon;Jung, Boram
    • Membrane Journal
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    • v.26 no.4
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    • pp.281-290
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    • 2016
  • Thin film composite (TFC) polyamide membranes were prepared on polysulfone (PSF) supports for forward osmosis (FO) applications. To understand the influence of polarity and porosity of support layer on the formation of polyamide structure and the final FO performance, clathochelate metal complex (MC) contained PSF supports were prepared via the phase inversion process from various PSF casting solutions containing 0.1-0.5 wt% of MC in dimethyl formamide (DMF) solvent (18 wt%). A crosslinked aromatic polyamide layer was then fabricated on top of each support to form a TFC membrane. For the porous PSF supports prepared with relatively low concentration casting solutions (12 wt%), the PET film was removed after phase inversion and crosslinked aromatic polyamide layer was then fabricated. The tested sample from PSF (18 wt%)/MC (0.5 wt%) casting solution presented outstanding FO performance, almost similar water flux (9.99 LMH) with lower reverse salt flux (RSF, 0.77 GMH) compared to commercial HTI FO membrane(10.97 LMH of flux and 2.2 GMH of RSF). By addition of MC in casting solution, the thickness of the active layer in FO membranes was reduced, however, the increased RSF value was obtained.

The Study on Physical Properties and Applicability of Material of Polyamide-66/Glass Fiber Blends Composition to the Eyewear Frame (Polyamide-66/Glass fiber 블렌드 조성물의 물리적 특성 및 안경테 소재로써의 적용성에 관한 연구)

  • Son, Jin-Young;Lee, Ji-Eun;Choi, Kyung-Man;Bae, Yu-Hwan;Kim, Ki-Hong
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.4
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    • pp.365-371
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    • 2013
  • Purpose: In this study, we evaluated the physical and thermal properties of the compositions made by blending glass fiber (GF) of different contents into glass fiber polyamide-66, and investigated if the compositions applying to the glasses frame to replace the TR-90, which is polyamide-12 resin used as an injection-type spectacle frame material. Methods: To investigate the characteristics change of polyamide-66 (PA-66) compositions with the change of the content of glass fibers, we produced a composition of the content by using a twin-screw extruder. The mechanical strength of the composition production was measured and coating properties as well as cutting processability were evaluated. We evaluated the applicability of the glasses frame by comparison the results of new compositions with characterizations of traditional TR. Results: For the results of the characterization of Polyamide-66/GF composition, we found that the higher increase of content of the glass fiber, the less mold shrinkage rate, and the mechanical strength was increased. Tensile strength increased from $498kg/cm^2$ for 0 wt% of the content of the glass fibers to $849kg/cm^2$ for 30 wt% of the content of the glass fibers. As a result of a coating evaluation, the strength of coating was 4B in the GF 5wt% and 5B, which was extremely good coating characteristics, in the over than GF 5 wt%. Conclusions: In case that 30 wt% of the glass fiber was blended, the mechanical strength was greatly improved, the hardness was increased, injection temperature increased due to increase of the viscosity, and the flow mark of the product may occur. The paint coating of PA-66 blended with glass fiber was all excellent. With general evaluating physical properties and workability properties it was determined that around 10 wt% of the content of the glass fibers was possible to apply a spectacle frame.