• Title/Summary/Keyword: 폴리아미드

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Laccase Treatment on Polyamide Fabrics (라카제를 이용한 폴리아미드 섬유의 효소 가공)

  • Seo, Hye-Young;Kim, Hye-Rim
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.10
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    • pp.1264-1270
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    • 2011
  • This study is to optimize the conditions for the treatment of polyamide fabrics using laccase. The pH, temperature, treatment time, and concentration were varied; their effects were evaluated by measuring the number of primary amide groups by the uptake of an acid dye measured by K/S of dyed polyamide fibers. The hydrophilicity of the fabrics was evaluated in terms of moisture regain and wettability. The effects of the mediator, ABTS, on the laccase activity were also evaluated. The optimal treatment conditions were identified as a pH of 4.5, temperature of $30^{\circ}C$, treatment time of 6 hours, and concentration of 10% of the weight of the fabric (o.w.f.). ABTS facilitated the activity of laccase on the polyamide fabrics. Voids and cracks on the surfaces of the laccase-treated polyamide fabrics were responsible for improved wettability. The results proved that laccase treatment improved the hydrophilicity of polyamide fibers without decreasing their strength.

Organic fiber reinforcement for Performance improvement of Blast resistance and Flexural Performance Evaluation of Fiber reinforced concrete using organic fiber reinforcement (방폭 성능 강화용 유기계 섬유보강재 제조 및 이를 혼입한 섬유보강 콘크리트의 휨성능 평가)

  • Jeon, Chanki;Jeon, Joongkyu;Kim, Sungil;Kim, Kihyung
    • Journal of the Society of Disaster Information
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    • v.11 no.2
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    • pp.211-218
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    • 2015
  • This study propose the organic fiber reinforcement for performance improvement of blast resistance. Proposed fibers are polyamide fiber, PET fiber and aramid fiber and fiber reinforcements were produced by ATY method. To evaluate strain energy absorption capacity of organic fiber reinforced concrete using organic fiber reinforcement, 4-point bending test and 3-point bending tests on notched beam were performed. Test results show that PET fiber reinforced concrete has outstanding performance. It is thought that the PET fiber is effective for the performance improvement of blast resistance.

A Processing and Flexural Performance Evaluation of Hybrid Organic Fiber Reinforced Concrete (하이브리드 유기섬유 보강 콘크리트의 제조 및 휨성능 평가)

  • Jeon, Chanki;Jeon, Joongkyu;Shim, Jaeyeong
    • Journal of the Society of Disaster Information
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    • v.13 no.2
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    • pp.213-220
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    • 2017
  • Organic fiber reinforced concrete is applicable to many applications for construction material. In general, organic fibers have low tensile strength and elastic modulus, but they have many advantages such as high crack resistance, impact resistance, chemical resistance, flexural behavior and corrosion resistance. In this study, hybrid organic fibers were prepared by mixing polyamide (PA) fibers and high strength polyester (PET) fibers. Then, flexural performance test of fiber reinforced concrete containing hybrid organic fiber was performed. The energy absorption capacity of the hybrid organic fiber reinforced concrete was evaluated.

Discoloration and the Effect of Antioxidants on Thermo-Oxidative Degradation of Polyamide 6 (폴리아미드 6의 열 산화반응에 의한 황변 현상과 산화방지제의 효과)

  • ;;;T. Mori
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.452-461
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    • 2002
  • In this study, the effect of various concentrations of antioxidants on thermo-oxidative degradation of polyamide 6 was investigated. Unstabilized and stabilized polyamides 6 were subjected to long-term oven aging in ambient atmosphere at 70~$160^{\circ}C$. All of specimens were discolored within 100 hr at temperature range of 70~$160^{\circ}C$. Optimum antioxidant concentration was determined from the data of mechanical properties, yellowness index and relative viscosity. The synergistic effect of each primary and secondary antioxidant concentrations was not observed. Yellowing phenomenon was explained by using NMR, IR and EA. Different carbonyl groups were detected by $^{13}C$/NMR. During thermooxidative degradation, oxygen consumptions were determined by EA. The lifetime after long-term aging was predicted using Arrhenius equation.

Controlled Release of Insulin through Glucose Oxidase Immobilized Composite Poly(vinyl Alcohol)/Chitosan Blend Membrane (글루코오즈가 고정화된 Poly(vinly Alcohol)/Chitosan 블렌드 복합막을 통한 인슐린의 방출조절)

  • Kim, Jin Hong;Shim, Jin Ki;Lee, Young Moo;Son, Tae Il
    • Membrane Journal
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    • v.3 no.2
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    • pp.70-78
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    • 1993
  • The permeation of insulin was conducted through glucose oxidase(GOD) immobilized composite membrane composed of poly(vinyl akohol)/chitosan blend and porous polyamide membrane. The permeation coefficient of insulin through GOD-immobilized membrane was in the order of $10^{-6}{\sim}10^{-7}\textrm{cm}^3cm/\textrm{cm}^2sec$. The sensitivity of the composite membrane to the glucose concentration was high in a low glucose concentration resulting from the oxygen depletion from the membrane. The permeation of insulin through composite membrane made of PVA/chitosan and porous polyamide membrane was changed by pH and glucose concentration. The permeability was progressively increasing with the glucose concentration at least up to 500mg%.

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Syntheses, Solubilities and Thermal Properties of Polyamide-imides containing Bis(p-carbonylphenyl)diphenylsilane units (Bis(p-carbonylphenyl)diphenylsilane 단위를 함유한 폴리아미드-이미드의 합성과 용해도 및 열적성질에 관한 연구)

  • Un Sik Kim;Young Kiel Sung;Yoon Koo Sik
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.590-600
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    • 1987
  • Silicone-containing polyamide-imides were prepared from bis(p-chlorocarbonylphenyl)diphenylsilane (BCCDPS), pyromellitic dianhydride(PMDA) and diamines. The thermal characteristics of the above polymers had been carefully studied using a thermogravimetric analyzer. The thermal stability of polymer was decreased with increasing contents of bis(p-carbonylphenyl)diphenylsilane units(BCDPS). The effect of diamine on thermal stability of polymer led benzidine > m-phenylenediamine> 4,4'-diaminodiphenyl ether > 4,4'-diaminodiphenyl sulfone. The activation energy of degradation of polymer obtained by Friedman method increased as the contents of BCDPS in the polymer decreased. The degradation temperature of polymers generally increased as the activation energy increased. The solubility of polymer increased as the content of BCDPS increased except polymers prepared with benzidine.

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Evaluation on the Mechanical Performance of Concrete Using Entanglement Polyamide Fiber (다발형 폴리아미드섬유 보강 콘크리트의 역학적 성능평가)

  • Jeon, Joong Kyu;Kim, Gyu Yong;Jeon, Chan Ki;Lee, Soo Choul
    • Journal of the Society of Disaster Information
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    • v.8 no.3
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    • pp.223-233
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    • 2012
  • Steel fiber is high stiffness and large weight. So, Pumping hose to rupture of the safety management is difficult. Steel fiber caused by corrosion of the deterioration of durability and high-rebound losses are needed for the improvements. Thus, the revised regulations in 2009 by a steel fiber to reinforce other materials is possible. Variety of fiber reinforcement material for concrete review of applicability is needed. Steel fiber strength than the other fibers is large and by the geometry of the fibers are attached to improve performance. However, compared to steel fiber organic fibers and low modulus of elasticity and tensile strength of fiber and agglomeration occurs in the concrete to be used as reinforcement material is difficult. In this regard, the present study as a single object in the micro-fiber bouquet sharp entanglement through make muck attach surface area, distributed fibers from surfactant of the surface enhanced polyamide fibers, steel fiber and PP fiber reinforced concrete by comparing the scene to provide a basis for the use.

Properties of PA 6,6/Elastomer Blends with Various Elastomer Content (탄성중합체 함유량 변화에 따른 폴리아미드-6,6/탄성중합체 블랜드물의 특성)

  • Lee, Yoong;Lee, Chang-Woo;Cho, Yoon-Ho;Hahm, Yeong-Min
    • Elastomers and Composites
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    • v.34 no.1
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    • pp.20-30
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    • 1999
  • In this study, binary polyamide 6,6(PA 6,6)/ethylene-propylene rubber(EPM) or EPM-g-maleic anhydride(EPM-g-MA) blends and ternary PA 6,6/EPM/EPM-g-MA blends with various elastomer content were prepared in order to investigate the degree of influence of elastomer content and average particle size, morphology, and distribution of dispersed elastomer on mechanical and thermal properties of blends. According to the results, notched Izod impact strength and relative crystallinity of binary blends modified with EPM-g-MA as well as average particle size and distribution of dispersed elastomer in such blends were more improved than those of binary blends modified with EPM. Notched Izod impact strength of blend whose composition ratio(wt % ) was 70:30(PA 6,6 : EPM-g-MA) was the highest among the binary PA 6,6/EPM-g-MA blends. The impact strength was increased by 25 times and its relative crystallinity was increased by 7 times when compared with those of polyamide 6,6. In the case of ternary PA 6,6/EPM/EPM-g-MA blend of which composition ratio was 70:15:15(PA 6,6:EPM:EPM-g-MA), the elastomer was finely distributed with the average particle size of $0.56{\mu}m$. The Izod impact strength of this blend was the highest of all blends prepared with different elastomer content.

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Evaluation for Long Term Drying Shrinkage and Resistance to Freezing and Thawing of Hybrid Fiber Reinforced Concrete (하이브리드 섬유보강 콘크리트의 장기 건조수축 및 내동해성 평가)

  • Kim, Yo-Seb;Bae, Su-Ho;Lee, Hyun-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.60-66
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    • 2019
  • Many researches have been performed on hybrid fiber reinforced concrete for years, which is to improve some of the weak material properties of concrete. Researches on characteristics of hybrid fiber reinforced concrete using amorphous steel fiber and organic fiber, however, yet remain to be done. Therefore, the purpose of this research is to estimate the compressive strength, long term drying shrinkage, and resistance to freezing and thawing of hybrid fiber reinforced concrete(HFRC) using amorphous steel fiber and polyamide fiber as one of organic fibers. For this purpose, HFRCs containing amorphous steel fiber and polyamide fiber were made according to their total volume fraction of 1.0% for target compressive strength of 40 and 60 MPa, respectively, and then the compressive strength, length change, and resistance to freezing and thawing of these were evaluated. As a result, the long term length change ratio of HFRC used in this study decreased by more than 30%, 25% than plain concrete at 365 and 730 days, respectively, and the durability factor of HFRC was very excellent as more than 90%.

짧은 실록산사실을 가지는 폴리아조메틴의 합성 및 산소선택투과성

  • ;Aoki, Toshiki;Itoh, Katsuhito;Oikawa, Eizo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.38-39
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    • 1996
  • 우수한 산소선택 투과막 소재를 얻기 위하여 높은 산소투과계수를 보이는 짧은 실록산 사슬과 금속이온과 착체를 형성할 것으로 기대되는 피리딘 고리를 번갈아 가지는 폴리 아조메틴을 합성하여 얻어진 막의 산소투과성을 검토했다. 또 같은 방법으로 합성한 폴리아미드의 한소투과특성과의 비교도 시도하였다.

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