• Title/Summary/Keyword: 폴리비닐 알코올 섬유

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Preparation of Water-Soluble Syndiotacticity-Rich Low Molecular Weight Poly(vinyl alcohol) by Solution Copolymerization of Vinyl Pivalate/Vinyl Acetate in Tetrahydrofuran and Saponification (피발산비닐과 아세트산비닐의 테트라히드로푸란계 용액공중합에 의한 수용성 저분자량 교대배열 폴리비닐알코올의 제조)

  • Lyo, Won-Seok;Yeum, Jeong-Hyun;Ji, Byung-Chul
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.187-190
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    • 2002
  • Poly(vinyl alcohol) (PVA) is a representative hydrophilic and water-soluble polymer and widely employed in various applications such as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials. Moreover, PVA fibers, gels, and films are potentially high-performance materials because they have high tensile and impact strengths, high tensile modulus, high abrasion resistance, excellent alkali resistance, and oxygen barrier property which are superior to those of any known polymers[1,2]. (omitted)

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Preparation of Sponge-type Wound Dressings Composed of Chitosan Oligomer and Poly(vinyl alcohol) (키토산 올리고머와 폴리비닐알코올로 구성된 창상피복용 스폰지의 제조)

  • Yoo, Yong;Park, Won-Ho
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.478-480
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    • 2002
  • 피부란 인체를 외부의 자극으로부터 보호하며 수분의 손실을 막아주는 기능을 수행하는 중요한 장기 중의 하나이다. 피부가 화상이나 각종 외상에 의하여 결손이 일어나게 되면 그 보호작용이 상실되어 기능의 장애를 일으키게 된다. 또한 수분손실에 따른 여러 가지 부작용과 외부로부터의 세균감염 등을 일으켜 환부의 치료를 어렵게 하거나 2차적인 기능장애 또는 손상 등과 같은 추가적인 부작용을 초래하게 된다. (중략)

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Synthesis of High Molecular Weight Poly(vinyl Alcohol) with High Yield by 1 Batch Suspension Polymerization and Saponification and Its Characterization (일욕 현탁중합과 비누화에 의한 고분자량 폴리비닐알코올의 고수율 제조 및 그의 특성해석)

  • Lee, Hee-Won;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.187-190
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    • 2001
  • The poly(vinyl alcohol) (PVA) fiber is recognized as the best candidate because of its good machanical properties together with excellent resistance to alkalis[1-5]. PVA cannot be prepared by the direct polymerization due to tautomerism of vinyl alcohol monomer. Thus PVA is obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) (PVAc). (omitted)

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Effect of Fiber Types on Fundamental Properties of Pavement Concrete (섬유 종류가 도로포장용 콘크리트의 기초적 특성에 미치는 영향)

  • Han, Cheon-Goo;Park, Jong-Sup;Jung, Woo-Tai;Jeon, Kyu-Nam
    • Journal of the Korea Concrete Institute
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    • v.22 no.4
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    • pp.473-479
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    • 2010
  • The objective of the paper is to experimentally investigate the effect of commercially avaliable fiber types such as polypropylene (PP), nylon (NY), polyvinyl alcohol (PVA) and cellulose (CL) on the engineering properties of concrete for pavement application. The results, showed the fluidity tends to decrease with fibers addition compared to that of plain concrete. As for the effect of fiber types on fluidity loss, use of NY appear to give the most favorable results among all of the fiber types investigated in this study while the effect of the fibers on air content was negligible. For the properties of hardened concrete, compressive and flexural strengths increased with fibers compared to plain concrete. The contribution of NY fibers to strength was the highest followed in the order by NY, PVA, PP, and CL. However, in the case of the splitting tensile strength, its values were increased with NY and PP only. For porosity based on MIP(mercury intrusion penetration) method, the number of around 1 was observed when NY was mixed resulting in increased cumulated amounts of porosity compared with that of plain mix. Thus, based on the consideration of fluidity and strength it was found that the addition of NY fiber showed the optimal results under the conditions applied in this study.

Animal Experiments on an Antithrombogenic Small-Caliber Vascular Prostheses and Vascualr Patch : Observation in Canine Models (항혈전성 소구경 인조 혈관 및 봉합편에 대한 동물 실험)

  • 김수철;김원곤;유세영
    • Journal of Chest Surgery
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    • v.36 no.2
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    • pp.63-72
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    • 2003
  • Although a variety of synthetic vascular grafts are available in modern vascular surgery, no ideal prosthesis ha,4 yet been developed. Small-caliber vascular grafts with low flow, as used in the lower extremity, continue to become thrombosed at unacceptable rates. We have developed and evaluated the new antithrombogenic blood contacting surfaces in canine model. Material and Method: Two now antithrombogenic blood contacting surfaces(Polyvinylalcohol -Polyurethane(PVA-PU) blend and natural Graphite-polyurethane(G-PU) blend) have been developed and evaluated in canine model, using vascular grafts and patches. The luminal surfaces of the test vascular grafts(5 mm ID) were fabricated by dipping a glass rod in PVA-PU blend solution(50 % PVA) using phase separation method. Mongrel dogs of either sex weighing 18-22 kg were anesthetized by endotracheal intubation using halothane and their lungs were ventilated with a volume-cycled ventilator, Maintenance anesthesia with 0.5-1.0% halothane and supplemental oxygen was used. Two pairs were used for comparison in the bilateral femoral arteries for both vascular grafts(PVA-PU vs. PU) and vascular patches(G-PU vs. PU). Bilateral groin incisions were made and the arteries were exposed and clamped. After an excision of 1 cm of the artery between clamps, a grail of 2.5 cm in length was implanted end-to-end using 6-0 polypropylene suture. The vascular patch was implanted as a form of on-lay patch. Animals were sacrificed at 1, 2, 4, 6, 8 and 16 weeks for vascular grafts and 1, 2. 4 and 6 weeks for vascular patches. Result The vascular grafts of PVA-PU blends showed patent lumina in the 2 and 16 weeks animals, while those of PU showed a patent lumen in 2 weeks animal. PVA-PU graft of 16 weeks showed a fairly clean luminal surface. A light microscopic finding of this graft demonstrated good tissue infiltration through porosity, The animals with vascular patches showed patent arteries in both groups except 2 weeks animal. Scanning electron microscopy of the luminal surfaces of G-PU patches in 4 and 6 weeks animals showed endothelial cell covering with microvilli. PU patches showed qualitatively less endothelial cell covering. Conclusion: In conclusion, PVA-PU and G-PU blends can be a promising blood contacting surfaces for application in a synthetic vascualr graft. However, further animal study is needed to determine the real long-term effects of these methods of surface modifications.

Rheological Properties of Organic Fiber-Reinforced Thermoplastics (유기섬유 강화 열가소성 복합재료의 유변학적 특성)

  • Lee, Yong-Mu;Cha, Yun-Jong;Kim, Seong-Hyeon;Yun, Yeo-Seong;Yun, Ju-Ho;Choe, Hyeong-Gi
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.786-795
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    • 1996
  • The fiber reinforced thermoplastics(FRTP) were prepared with polypropylene fiber(PP) as matrix and polyvinyl alchol(VF), aramid(KF) or polyamide fiber(PAF) as the reinforcing materials using the integrated fiber mixing apparatus. The reinforced thermoplastic sheets were prepared by com¬pression molding and their morphology, rheological and mechanical properties were characterized. In the morphological properties of composites, the wettability of the reinforced thermoplastics were decreased in proportion to the content of fibers. At low angular frequency, the viscosity of PAF /PP and VF/PP composite was increased with the content of reinforced fiber. However at high frequency the viscosity of composite reinforced with 5~20wt% fiber, was shown the reduced values which approaches that of the neat matrix. The mechanical properties of the composite were changed with the content of reinforecd fiber, and VF/PP and KF/PP composite had better properties than PAF/PP system.

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