• Proceedings of the Korean Society of Fisheries Technology Conference
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• 2010.05a
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• pp.91-94
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• 2010

• Polymer(Korea)
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• v.30 no.2
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• pp.118-123
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• 2006

The effect of transesterification on the rheological properties in the melt reactive blending of poly(butylene terephthalate)(PBT) with poly(ethylene terephthalate)(PET) has been studied. The melt viscosity depression in PBT was found in PBT/PET blends due to the intrinsic low melt viscosity of PET compared to PBT. In addition, the thermal degradation in the melt blending and transesterification between two polyesters were considered as other factors fer the lowering of the melt viscosity in the blends. In the PBT/PET blends, calcium stearate was less effective than in PBT as a lubricant, however it accelerated both the thermal degradation and transesterification during melt blending. As a result, further melt viscosity drop was obtained in the reactive melt blending of PBT/PET.

• Polymer(Korea)
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• v.30 no.1
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• pp.22-27
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• 2006

The effect of transesterification on the rheological property of poly(ethylene naphthalate)/poly(butylene tore-phthalate) (PEN/PBT) blends has been investigated. The melt viscosity of PEN/PBT blends decreased with increasing PBT content due to the relatively low melt viscosity of PBT as well as introducing ransesterification between PEN and PBT Further melt viscosity decrease was achieved by the thermal annealing which caused both the chain scission and the acceleration of transesterfication. Calcium stearate (CaST) was applied as a lubricant in order to lower the melt viscosity of PEN and it was found that CaST was acting as the catalyst of transesterification as well. In general, reactive melt blending of PEN and PBT by transesterification resulted in the decrease of molecular weight of PEN and PBT, as a result, the loss of mechanical properties in PEN/PET blend was inevitable.

• Proceedings of the Korean Fiber Society Conference
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• 2001.04b
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• pp.51-54
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• 2001

• Polymer(Korea)
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• v.34 no.3
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• pp.237-241
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• 2010

Mechanical characteristics and chemical resistance have been investigated for PC/PBT blends. The changes in mechanical performance of PC/PBT blends was monitored during the treatment with both the PC thinner and general-purpose thinner to figure out the chemical resistance. The PC thinner greatly affected the mechanical properties of PC/PBT blends compared with general-purpose thinner. In the case of PC thinner treatment, the mechanical performance was improved with increased PC content at lower PC content ranges, say below 50%. However the mechanical performance was dropped rapidly at higher PC content ranges due to poor chemical resistance of PC. Transparent pure PC specimen became opaque after chemical treatment with PC thinner, and this can be interpreted by solvent-induced crystallization.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1576-1581
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• 2004

An experimental study has been carried out to investigate the frosting behaviors of thermally conductive plastic(PBT based resin) resin by comparing with those of aluminum and some plastic(PTFE based resin) test specimens. It is found that the frosting behavior of plastic specimens with 1 mm thickness show similar trend with aluminum except PTFE. The properties of frost formed on the specimens are affected by both thermal conductivityand surface characteristics (hydrophilic/hydrophobic) of the materials. It can be said that the heat and mass transfer rate of plastic materials are almost equivalent with those of aluminum.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.7
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• pp.667-672
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• 2004

An experimental study has been carried out to investigate the frosting behavior on the plate of thermally conductive plastic (PBT based resin) by comparing it with those of aluminum and some plastic test specimens (PTFE based resin). It is found that the frosting behavior of plastic specimens with 1 mm thickness shows similar trend to that of aluminum except PTFE. The properties of frost formed on the specimens are found to be affected by both thermal conductivity and surface characteristics of the materials. The results indicate that the heat and mass transfer rates of PBT resin are almost equivalent to those of aluminum.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.525-530
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• 2003

Recently an automobile industry is concerned about an automobile wiring harness system. It means that development of component modules is on the increase. An importance of the connector in one part of the modules will be enhanced. A connector is made of P.B.T. (Poly Butylene Terephthalate). PBT is resistant to the high temperature. This paper deals with thermal strain of connector. According as temperature increase, effects of the temperature and thermal strains give an analysis of the deformation using ABAQUS. This apparent thermal strain results actually from the variation of temperature. Being based on this analysis, axiomatic design applies to design parameters of the connector. As compared with CAE analysis, a performance improvement makes certain of the truth of the matter.

• Polymer(Korea)
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• v.29 no.2
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• pp.190-197
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• 2005

Nanocomposites of three different polyesters with dodecyltriphenylphosphonium-montmorillonite $(C_{12}PPh-MMT)$ as an organoclay are compared with their thermal properties, mechanical properties, and morphologies. Poly (butylene terephthalate) (PBT), poly(ethylene terephthalate) (PET), and poly(trimethylene terephthalate) (PTT) were used as matrix polymers in the fabrication of polyester nanocomposite fibers. The variations of their properties with organoclay content in the polymer matrix and draw ratio (DR) are discussed. Transmission electron microscopy (TEM) micrographs show that some of the clay layers are dispersed homogeneously within the polymer matrix on the nano-scale, although some clay particles are agglomerated. We also found that the addition of only a small amount of organoclay is enough to improve the thermal stabilities and mechanical properties of the polyester nanocomposite fibers. Even polymers with low organoclay contents $(<5\;wt\%)$ were found to exhibit much higher strength and modulus values than pure polyester fibers. In the cases of all polyester hybrid fibers, the values of the tensile mechanical properties were found to decrease linearly with increasing DR. However, the initial tensile modulus of the PTT hybrid fibers were found to be independent of DR.

• Polymer(Korea)
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• v.31 no.5
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• pp.399-403
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• 2007

Trans-esterification behavior of polycarbonate/poly(butylene terephthalate) (PC/PBT) blends was investigated during the melt mixing process. Rheological and fracture behaviors, and fracture morphology were also investigated as a function of PC/PBT blend ratio. Based on FT-IR and $^1H-NMR$ results, a trans-esterification reaction was confirmed to occur between PC and PBT during the melt mixing process. The melt index(MI) decreased with increased PC content, indicating the higher flow resistance of PC. The storage and loss moduli were increased by increasing the PC loading, and the PC/PBT blends were rheologically incompatible based on the Cole-Cole plot. The tensile property increased linearly with the increased PC content. However, the impact strength increased until 50 wt% of PC loading, notably around $30{\sim}40wt%$, and then was levelled off at 50 wt%. Rough ridges were formed on the impact fracture surfaces above the 40 wt% of PC content, supporting the observed higher impact strength in this range.