• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.121-125
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• 1998

1977년 polyacetylene(PA)이 할로겐 도핑에 의해 금속에 필적하는 도전성을 나타낸다는 것이 발견된 이래 전도성 고분자는 전기 전도도 및 전자 상태를 자유롭게 제어 할 수 있다는 특징 때문에 2차 전지 및 연료 전지, 가스분리막, 우주 항공용 경량 도전재료, 대전방지제등의 넓은 응용분야를 가지며 현재에도 기초 연구 및 응용 연구의 양면에서 활기를 띠고 있다.(중략)

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.126-129
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• 1998

전기 전도성 고분자는 전하 이동체의 종류에 따라 이온과 전자 전도성 고분자로 구분되며 전자 전도성 고분자는 절연체인 고분자에 전도체를 혼합하는 전도성복합체와 본질적으로 전도성을 갖는 고분자로 나뉘어진다. 전도성복합체는 제법이 간단하여 이미 전기ㆍ전자산업에 많이 이용되고 있지만 일정한 전도도의 유지와 가공성 향상 및 염가의 제품 제조는 아직 과제로 남아있다.(중략)

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.368-370
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• 2001

폴리비닐알코올(poly(vinyl alcohol) (PVA))은 구조적인 단량체인 비닐알코올의 호변 이성질화 때문에 직접 중합에 의해서는 얻을 수 없으며, 아세트산 비닐 (vinyl acetate (VAc))이나 피발산 비닐 (vinyl pivalate (VPi))같은 비닐에스테르 계열 단량체를 사용하여 중합과 비누화 반응을 거쳐 제조되고 비누화 반응에서 모든 측쇄기가 효과적으로 제거되는 히드록시기 함유 선형 결정성 고분자이다[1-4]. (중략)

• 기계와재료
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• v.23 no.4
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• pp.46-58
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• 2011

홍합은 수중 환경에서 다양한 표면에 강하게 붙어서 자라는 수중 생물이며, 이러한 홍합의 특이적인 접착능력은 많은 연구자들에게 관심을 받고 있다. 홍합의 접착력에 관여하는 화학적 작용기를 모방한 폴리도파민/폴리노르에피네프린 표면 개질 기술은 자연의 홍합이 가지는 특성을 그대로 가지고 있어 수용액 상의 조건에서 표면의 성질에 관계없이 거의 모든 표면에 뛰어난 접착력을 나타낸다. 이러한 자연 모방 표면 개질 기술은 다양한 생체/에너지 재료, 신소재 복합 재료 등의 개발에 응용되고 있으며, 다양한 분야에서 활용될 수 있다.

• Polymer(Korea)
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• v.27 no.1
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• pp.3-8
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• 2003

Polysiloxanes with methacrylate groups at both terminals were synthesized by a hydrosilylation reaction between allyl methacrylate and hydride-terminated polysiloxanes. The polysiloxane methacrylates with high molecular weights could be prepared through the reaction of polysiloxane methacrylates and octamethylcyclotetrasiloxane with an acid catalyst. The structures of the prepared polysiloxane methacrylates were verified by $^1$H- and $^{29}Si-NMR.$ The polysiloxane methacrylates were freely miscible with silicone oils. Polysiloxane films with microphase-separated liquid silicone oil were prepared by photo-crosslinking the mixture of polysiloxane methacrylates and silicone oil. Scanning electron microscopy (SEM) of the films showed that the size of silicone oil droplets became smaller with a lower loading of silicone oil, lower molecular weight of polysiloxane methacrylate, and lower molecular weight of silicone oil.

• Polymer Science and Technology
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• v.16 no.1
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• pp.93-100
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• 2005

• Polymer(Korea)
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• v.35 no.6
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• pp.531-536
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• 2011

Homopolymer distribution in block copolymer/homopolymer blends was investigated as a function of homopolymer concentration and homopolymer molecular weight. The deuterated poly(methyl methacrylate) or polystyrene was blended with a deuterated polystyrene-poly(methyl methacrylate) diblock copolymer up to a concentration of 20 wt%. Samples were characterized by small-angle X-ray scattering (SAXS), neutron reflectivity and transmission electron microscopy. The block copolymer with a thin-film geometry formed alternating lamellar microdomains oriented parallel to the substrate surface. By adding the homopolymer, the microdomain structure was significantly disturbed. As a consequence, a poorly ordered morphology appeared when the homopolymer concentration exceeded 15 wt%. Increasing the homopolymer concentration and/or the homopolymer molecular weight caused the microdomains to swell less uniformly, resulting in segregation of the homopolymer toward the middle of the microdomains.

• Elastomers and Composites
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• v.40 no.3
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• pp.204-211
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• 2005

Effect of chlorinated polyethylene(cPE) on the morphology and mechanical properties of isotactic polypropylene(iPP) and nitrile rubber(NBR) blends was investigated. It was found that incorporation of a small amounts of cPE leads to a decrease in domain size of the dispersed phase, and uniform distribution of the dispersed phase in the blends. The PP/NBR/cPE ternary blends showed an improved tensile and tear strength as well as elongation-at-break as compared to binary PP/NBR blends. From the results on morphology and mechanical properties, optimum amount of the cPE is 5-10 wt% with repect to NBR in the blend.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.305-312
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• 2005

Poly(urethane-imide)s were prepared by reaction between crosslinkable endgroup containing soluble polyimide (PI) by chemical imidization and acrylate end-capped polyurethane (PU). Poly (amic acid) was prepared from 2,2'-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) and 4,4'-oxydianiline (ODA) and then end-capped with maleic anhydride (MA). The PU prepolymers were prepared by the reaction of polycaprolactone diol, tolylene 2,4-diisocyanate and end-capped with hydroxyl ethyl acrylate. The effect of PU content on the residual stress behavior, morphology and thermal property was studied. The poly(urethane-imide)s were characterized by thin film stress analyzer (TFSA), XRD, TGA and DMTA. Low residual stress and slope in cooling curve were achieved by higher PU content. Compared to typical polyurethane, these polymers exhibited better thermal stability due to the presence of the imide groups. Finally the residual stress of poly(urethane-imide)s was strongly affected by the morphological structure.

• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.709-716
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• 2015

In this study, structural developments of polypropylene / ionomer / clay ternary composites were investigated depending on the dispersion and localization of clay. The changes in physical properties were observed adding organoclays 1~10wt% to 90% polypropylene and 10% ionomer blends. The organoclays were localized inside of the dispersed phase under the composition of 3wt%, however, over that composition, clay particles formed stiff network structure in the dispersed phase and additional clays were localized at the interface between two phases. According to the developments of microstructure, the interaction of ternary composites changed from polypropylene-ionomer to polypropylene-ionomer and ionomer-clay which affected rheological properties. The storage modulus (G') of the composites was similar to the blends when clays were localized inside of dispersed phase but increased when clays were localized at interface. Also, the fractured morphology of the composites showed phase boundary and growing radius of dispersed phase depending on addition of fillers when clays were found inside. However, when fillers found at the interface between blends, the radius of the dispersed phase decreased and compatibilized morphology were observed. The interfacial interaction of the ternary composite was quantified depending on the structural development of dispersed phase and localization of clay particles by the rheological properties. The interaction of composites at solid state which was measured through peel adhesion strength increased by growth of interfacial interaction of each component. Furthermore, the crystallinity of the composites was decreased when the clay particles were localized at the interface.