• Resources Recycling
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• v.27 no.6
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• pp.59-67
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• 2018

Efflorescence is a white deposit of powders in the surface of cement concrete which can also occur in geopolymers. Efflorescence occurs when sodium ions in alkali activator react with atmospheric carbon dioxide to form sodium carbonate components. In this study, we investigated whether the secondary efflorescence can be reduced by controlling the Na/Al mole ratio or by changing the curing temperature and heat curing time in fly ash-based geopolymers. The 28 days compressive strength in geopolymers having Na/Al ratio of 1.0 was higher than geopolymers having Na/Al ratio of 0.8. The strength increased with the increasing curing temperature and longer heat curing time. On the other hand, efflorescence was lower when the curing temperature was high and the heat curing time was longer in the geopolymers having Na/Al ratio of 1.0. The geopolymers having Na/Al ratio of 0.8 showed accelerated efflorescence occurrence than the geopolymers having Na/Al ratio of 1.0. In order to reduce the occurrence of the secondary efflorescence of fly ash-based geopolymers, it will be advantageous to maintain the Na/Al ratio at 1.0, increase the curing temperature, and lengthen the heating curing time.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.6
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• pp.27-34
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• 2005

The purpose of this study is to improve the durability performance of polymer modified cement composites for repair of concrete under combined aging conditions. The experimental procedure was divided into three parts. First, the replacement level of mineral admixtures in polymer modified cement composites were determined in an experimental study based on a Box Behnken design. Second, the flow value, compressive strength and chloride permeability test of sixteen types of mixtures were conducted. Test results show that the polymer modified cement composites were effected on the improvement of the compressive strength and permeability performance. Third, the effects on the replacement level of silica fume mixture was evaluated by the compressive strength, chloride permeability, chemical resistance and repeated freezing and thawing cycles test. They demonstrated that the polymer modified cement composites using mixture of silica fume, fly ash, and blast furnace slag improved the durability performance.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.236-237
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• 2015

Concrete is the one of the most widely used in every country as a structural materials. On the other hand, a lot of fire incident has been occurred all over the world. But maintenance methods such as inspection and diagnostic methods, design methods, quality control methods for the purpose of improving the performance of concrete structures damaged by fire has made in its own way. Therefore, the purpose of this proposal of new working item is is to ensure the safety of the concrete structures damaged by fire in the field of assessment of damage, design, repair methods and so on through the International Organization for Standardization.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.19-20
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• 2014

This study is to find out the tensile strength and bonding strength of VAE powder as a preliminary study for the application of the powder to the high strength concrete. The result of the study showed that the compressive strength decreases when more polymers is put into the concrete. On the other hand, it showed that the tensile strength and the bonding strength get improved when the more polymers are put into the concrete. Especially in case of the mixture for high strength concrete, it was found out that more strength is produced than the ordinary concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.1005-1010
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• 2001

Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top layers with thin thicknesses, typically 5~ 15mm. The purpose of this study is to evaluate basic properties of self leveling materials using polymer modifier as kinds of SBR, PAE, SUBA. Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as in order to facilitate the workability required. The self leveling materials using four types of polymer dispersion are prepared with polymer-cement ratios which respectively range from 50%, 75%, and were tested for basic characteristics such as adhesion in tension, crack resistance test, rebound test after the preparative tests for unit weight, air content, consistency ratio etc. The results show almost as equal quality as existing commercial industrial flooring when mortar is modified by polymer dispersion. Adhesion in tension of polymer modified mortars using each SBR and PAE emulsion was over 10 kgf/$cm^{2}$. Crack or flaw derived from shrinkage is strongly dependent on the type of polymer dispersion because of each different total solid of polymer. It is judged that polymer modified mortar with self-leveling can be very well suited for Floor-finished.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.1017-1022
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• 2001

The bend resistance of coated reinforcing bar is greatly influenced by adhesion strength of bar and coating materials and transformation of coating materials to the bar. Expecially, tearing state or a limited microscopic cracks are predicted on the inside and outside of bending angle because of adhesion strength and elongation is very different with types of polymer materials using bar coating, and these parts are accelerated corrosion as penetration of bar corrosion effects factor. In this study, cement modified polymer are prepared four types and differ from polymer cement ratio of 50% and 100%, coating thickness of 250$\mu$m and 450$\mu$m, coating number, curing age of 3, 7, 14 and 280days, and then tested bend resistance as bending angle $90^{\circ}$, $135^{\circ}$ and $180^{\circ}$ for observe the microscopic demage effect according as bar bend. From the test results, when is used cement modified polymer as coating materials of bar, St/BA is showed excellent bend resistance than a polyacrylic emulsion and SBR because of softness. But it is to need attention because as coating parts are pressed down and tearing, also experimental study is proceeded to corrosion potential on the inside and outside of coated reinforcing bar.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.117-122
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• 2001

Recently, epoxy-coated re-bar used to the structure partly and put to practical use step, but not economical and appeared to the defect of deterioration of long term bond strength between concrete. The method for complement the defect of epoxy coated re-bar, study of polymer cement slurry coated re-bar started and basic properties appeared to excellent, but study of bond properties embedded in concrete specimens insufficient until now. This study attempts to examination of using possibility for bond strength of polymer cement slurry coated re-bar between concrete specimens compare to ACI Code and KS Code through pull-out test of 15cm$\times$15cm$\times$15cm specimens with polymer cement slurry coated re-bar as polymer cement ratio 50%, 100%, 150%, coating thickness 250${\mu}{\textrm}{m}$, 440${\mu}{\textrm}{m}$ and curing age. In the results of this study, the bond strength of polymer cement slurry coated re-bar compare to plain re-bar, epoxy coated re-bar decreased St/BA-modified polymer cement slurry coated re-bar, but bond strength of PA-modified polymer cement slurry coated re-bar appeared to excellent results. The bond properties of polymer cement slurry coated re-bar between concrete will be obtain more precise results according to compressive strength change of concrete and re-bar diameter size.

• Journal of the Korea Institute of Building Construction
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• v.16 no.1
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• pp.25-34
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• 2016

From 1990's, a study on the development of exothermic concrete, a concrete which electro-conductive material is mixed, has been proceeded. However, due to the difficulty of exothermic reproducibility of concrete specimen, the study has been unable to continuously carried out. Accordingly, this study was focused on developing an exothermic concrete for the purpose of snow-melting material. Cement paste and mortar specimens mixed with graphite, conductive metal powder and chemical admixture were made. The evaluation of exothermic performance and reproducibility was conducted under $-2^{\circ}C$ of low temperature. In addition, micro-chemical analysis was carried out to investigate a cause of exothermic reproducibility. As a test result, the specimen mixed with graphite and superplasticizer with air entrained showed the best exothermic performance and reproducibility. Through micro-chemical analysis, it is judged that polymer or methacrylic acid (MAA), the contents inside the superplasticizer with air entrained, gave exothermic reproducibility by generating the electrochemical reaction with graphite.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.6
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• pp.319-326
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• 2017

In this study, a lightweight geopolymer was prepared using by slag discharged from IGCC (Integrated Gasification Combined Cycle) power plant and its physical properties, the density and compressive strength, were analyzed as a function of the concentration of alkali activators, W/S ratio and aging times. Also the possibility of applying it to lightweight materials by adding Si sludge as a foaming agent to the geopolymerg was investigated. In particular, a complex composition of alkali activator and a pre-curing process were applied to improve the strength properties of lightweight geopolymers. While the compressive strength of the lightweight geopolymer using a single activator was 9.5 MPa, the specimen made with a complex composition of alkali activator had compressive strength of 2~5 times higher. In addition, the lightweight geopolymer with pre-curing process showed a compressive strength value of 18~48 % higher than that of specimen made with no precuring process. In this study, by using a complex activator and a pre-curing process. the maximum compressive strength of lightweight geopolymer was obtained as 40 MPa (The specimen was aged for 3 days and had density of $1.83g/cm^3$), which is comparable to cement concrete. By analyzing the crystal phase and microstructure of geopolymers obtained in this study using by XRD and SEM, respectively, it was confirmed that the flower-bud-like zeolite crystal was homogeneously distributed on the surface of the C-S-H gel (sodium silicate hydrate gel) in the geopolymer.

• Journal of the Korea Institute of Building Construction
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• v.15 no.5
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• pp.483-489
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• 2015

The Purpose of this study was to establish the basic data on the mechanical properties of PCM in the high temperature range. To this end, an experiment was conducted on the characteristics of the residual compressive strength by temperature (100, 200, 400 and $600^{\circ}C$) with a fixed temperature heating. An after heating test was performed to investigate the properties after fire damage. The result showed that the residual compressive strength of PCM had a tendency to decrease, regardless of the type of polymer. It was also found that when the contents were low, the residual compressive strength started to greatly decrease from the high temperature range of $400^{\circ}C$, and that the specimen containing PAE showed a steeper slope than the specimen containing EVA. However, since little studies have been conducted on the mechanical properties of PCM with the high temperature, it is considered that, in addition to this study, basic studies must be preceded, including studies on the repairing methods.