• 한국도로학회:학술대회논문집
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• 1999.11a
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• pp.81-88
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• 1999

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.444-444
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• 2010

최근 복잡한 고진공 시스템에서 수행되는 플라즈마 공정을 대신하여 진공 시스템 없이 대기압 플라즈마를 이용한 보다 경제적이고 신속하게 공정을 수행하는 연구가 활발히 진행 중이다. 이러한 대기압 플라즈마의 높은 응용성을 이용한 에칭과 증착 등의 기술은 플라즈마의 물리적 접근 없이 세계적으로 몇몇 선도 연구그룹에서 시도되고 있다. 본 연구팀에서는 대기 중에서 He, Ar, $N_2$, $O_2$, Air 등의 여러 종류의 기체에서 방전하여 미세가공이 가능한 $500\;{\mu}m$ 이하의 마이크로 제트를 개발하였다. 입력전압, 기체유량, 노즐의 구조와 크기 등의 여러 운전변수의 조절을 통해 폴리머 기판위에서 방전되는 마이크로 플라즈마 제트의 안정된 방전조건을 찾았고, 전압-전류 특성곡선(V-I characteristics), 광방출분광법(OES), 시간분해 이미지 촬영법(ICCD), 기체온도 측정법 등을 이용하여 발생된 플라즈마의 물리적인 특성을 분석하였다. 발생된 플라즈마를 이용해 처리된 폴리머 기판의 물성변화를 AFM을 통해 관찰하여 짧은 플라즈마 처리시간에도 효과적인 표면개질의 변화를 확인하였다. 마지막으로 본 기술을 이용한 대기압 마이크로 공정의 응용기술 및 가능성을 연구하였다.

• Magazine of the Korean Society of Agricultural Engineers
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• v.41 no.5
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• pp.104-105
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• 1999

This study was performend to examine Poisson's ration of polymer-modified asphalt concrete due to temperature variatino . Asphalt binder used in this study was an AC85-100, penetration grade of 85-100, and polymer for modifying asphalt were domestic LDPE(Low-density polyethylene) and SBS(Styrene-butadiene-styrene). Aggregate was a crushed gneiss which was most widely used in the middle part of Korea. Using these materias, asphalt mixture slab(340mm$\times$240mm$\times$80mm) with optimum asphalt content from mix design was made and cut into square pillar (80mm$\times$80mm$\times$160mm). Poisson's ration was measured in various temperture (-15$^{\circ}C$, -1$0^{\circ}C$, -5$^{\circ}C$,$0^{\circ}C$,5$^{\circ}C$,1$0^{\circ}C$ and 2$0^{\circ}C$) under the load of one axis repeated compression mode. Poisson's ration of normal asphalt polymer modified asphalt mixtures in normal temperatures. This indicated that AP mixture was more susceptible to temperature effects. From regression aalysis of experimental results, the difference of Poisson's ration between normal and low temperature showed that polymer modified asphalt mixture were lower than AP mixture except for SBS modified asplat mixture.

• Polymer(Korea)
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• v.25 no.4
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• pp.594-601
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• 2001

Direct thermal lamination of polyethylene film on aluminum plate without using adhesive was tried by modifying their surfaces to have polar groups. Polyethylene film was modified by treating with oxygen or acrylic acid plasma. Aluminum plate was modified by treating with boiling water or diaminocyclohexane plasma. Fairly high adhesion strength was obtained even in the case when only the polyethylene film was modified, and adhesion strength was so high that film was broken during the adhesion test if both the film and the aluminum plate were modified. Even chemical bonding seemed to be possible when the film treated with acrylic acid was laminated on the plate treated with diaminocyclohexane plasma by forming amide linkage through the reaction between COOH groups on the film surface and NH$_2$ groups on the plate surface.

• Polymer(Korea)
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• v.27 no.6
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• pp.589-595
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• 2003

Unsaturated polyester (UP) nanocomposite with montmorillonite (MMT) which contains different types of organic modifiers far nano-filler have been prepared to investigate the effect of chemical structure of organic modifiers and mixing time of all components on properties of products. It was found that the morphology and various physical properties of UP/MMT nanocomposites were influenced by properties of organic modifiers of MMTs. It was also confirmed that the content of MMT does not significantly affect properties of UP/MMT nanocomposites.

• Polymer(Korea)
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• v.32 no.2
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• pp.116-124
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• 2008

A commercialized biobased and biodegradable poly(lactic acid)(PLA) containing the functional monomer of glycidyl methacrylate (GMA) was chemically modified using reactive extrusion to enhance its melt strength. Modified PLAs were prepared with various contents of GMA and initiator, and were characterized by observing their gel fraction, thermal properties, melt viscoelasticity and biodegradability. The complex viscosity and storage modulus of chemically modified PLA with the initiator alone was increased by addition of initiator and were more increased in the presence of GMA. There was a optimum content of GMA showing the maximum complex viscosity with the amount of initiator. The biodegradebility of modified PLA was slightly decreased by addition of GMA.

• Polymer(Korea)
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• v.31 no.1
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• pp.68-73
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• 2007

This study is on the synthesis of reactive polymer modifiers by emulsion polymerization to improve properties of asphalt for paving. Styrene, methyl methacrylate (MMA), isoprene and glycidyl methacrylate (GMA) which has epoxy ring to react with carboxyl group of asphaltene were used to synthesize polymer modifiers. Modifiers with various composition were tested miscibility with asphalt. Modifiers which showed good miscibility with asphalt were investigated by DSC for $T_g$. Existence of epoxy rings and their reaction with asphaltene wore investigated by FTIR. Molecular structures of synthesized modifiers were confirmed by $^1H-NMR$. The synthesized modifiers which showed good miscibility had their $Tg's$ in the range of $37.5{\sim}56.5^{\circ}C$ and had isoprene contents of 30 wt%. They showed good miscibility in the 1 and 2 wt% concentrations, but not in the 3 wt% concentration.

• International Journal of Highway Engineering
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• v.8 no.3 s.29
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• pp.163-172
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• 2006

This study evaluated the laboratory properties of asphalt binder and mixture modified with SPC(Sulfur Polymer Cement), which consists of sulfur as a main ingredient that is an industrial by-product made from refining process of crude oil and carbon-black as an additive. Four levels of SPC modifier ratios(0, 10, 30, 50%) were evaluated in the laboratory. Superpave(Superior Performing Asphalt Pavements) system was used to determine the PG(Performance Grade) and evaluate the property of SPC modified binder at the different temperatures. IDT(Indirect Tensile Test) was performed to evaluate the resistance of fatigue and low-temperature cracking at $10^{\circ}C\;and\;-10^{\circ}C$. Wheel-tracking test was also performed to evaluate the rutting-resistance of SPC modified asphalt mixtures. Test results showed that the more SPC modifier ratios, the better rutting-resistance and the more potential of low-temperature cracking resistance. However, SPC modifier did not show the effect on the fatigue cracking resistance.

• International Journal of Highway Engineering
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• v.12 no.4
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• pp.87-92
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• 2010

This study evaluates the laboratory properties of asphalt binder and mixture modified with R-EPDM(Recycling Ethylene Propylene Dien Monometer), which consists of R-EPDM as a main ingredient that is an industrial by-product made by manufacturing waste EPDM below 50 mesh as an additive. Superpave system was used to determine the PG(Performane Grade) and evaluate the property of R-EPDM modified binder. OACs(Optimum Asphalt Contents) of R-EPDM modified asphalt mixtures were determined by Superpave mix design using gyratory compactor and wheel tracking test and moisture susceptibility test were carried out with R-EPDM modified asphalt mixtures at OACs. The results from these tests, rutting-resistance and freezing and thawing resistance by moisture susceptibility of R-EPDM modified asphalt mixtures were superior to one of general asphalt mixtures(AP-5).

• International Journal of Highway Engineering
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• v.3 no.1 s.7
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• pp.185-197
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• 2001

This paper dealt with modification of effective crack length model (ECM) by adding Poisson's ratio term to evaluate fracture toughness of asphalt concrete which varies its material property by temperature. The original ECM model was developed for solid materials, such as cement concrete, and Poisson's ratio of materials was not considered. However, since asphalt concrete is sensitive to temperature variation and changes its Poisson's ratio by temperature, it should be taken into consideration to know exact fracture property under various temperatures. Four binders, including 3 polymer-modified asphalt (PMA) binders, were used to make a dense-grade asphalt mixture and 3-point bending test was peformed on notched beam at low temperatures, from -5oC to 35oC. Elastic modulus, flexural strength and fracture toughness were obtained from the test. The results showed that, since Poisson's ratio was considered, the more accurate test values could be obtained using modified ECM equation than original ECM. PMA mixture showed higher stiffness and fracture toughness than normal asphalt mixture under very low temperatures.