• Title/Summary/Keyword: 폴리(아릴렌이써케톤)

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Poly(arylene ether ketone) block copolymer prepared through sulfonation process for polymer electrolyte membrane fuel cell (술폰화 공정을 통해 제조한 고분자 전해질형 연료전지용 폴리(아릴렌 이서 케톤) 블록 코폴리머)

  • Jang, Hyeri;Nahm, Keesuk;Yoo, Dongjin
    • Journal of Energy Engineering
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    • v.25 no.3
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    • pp.66-72
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    • 2016
  • In this study, a sulfonated poly(arylene ether ketone) block copolymer was prepared from hydrophilic oligomer and hydrophobic oligomer. The structure of the prepared membrane was characterized by $^1H$-NMR, FT-IR and GPC. The $M_w$(weight-average molecular weights) of the polymer was $209,700g\;mol^{-1}$ and the molecular weight distribution($M_w/M_n$) of 1.25 was obtained. The prepared membrane showed excellent thermal stability with gradual weight loss up to $200^{\circ}C$. The proton conductivity of SPAEK block copolymer reached the maximum of $9.0mS\;cm^{-1}$ at $90^{\circ}C$ under 100% relative humidity (RH). From the observed results, it is necessary to do more aggressive attempt to study the possibility of application as an ion-conductive composite electrolyte.