• Title/Summary/Keyword: 포화자화

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Effect of the Powder Characteristics of Iron Oxides on the Magnetic Properties of Sr-ferrite (산화철의 분체특성이 Sr-ferrite의 자기특성에 미치는 영향)

  • 조태식;김효준;최승덕;남효덕;염충진
    • Resources Recycling
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    • v.7 no.4
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    • pp.43-49
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    • 1998
  • We investigated the effects of the powder characteristics of various domestic iron oxides (${\alpha}Fe_2O_3$) on the magnetic properties of Sr-ferrites The particle size and the distribution of iron oxides were classified hy three different rerinning methods, and greatly a affected on the magn$\xi$tic prope$\pi$ies and the mmphology of Sr-ferntes. The agglomeration of Ruthner iron oxides and the large particles of Chemirite (CY) above $0.80{\mu}\textrm{m}$ were degraded the prope며es of Sr-fcrrites. The optimal magnetic prope$\pi$ies of Srt territes, showing 68.2 emu/g of saturation magnetization and 4300 Oe of intrinsic coerClvity, were achieved at the following c conditions; Chemirite (P2EP) iron oxides of $0.14{\mu}\textrm{m}$ molar ratio of 5.8. and calcination of $1150^{\circ}C$/1 hr.

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The Effect of Magnetic Property According to Size and Orientation of Crystal for Electroplated Co-Fe-Ni Alloys (전기 도금된 CoFeNi계 박막의 결정크기와 방향성이 자기특성에 미치는 영향)

  • Jeung, Won-Young;Kim, Hyun-Kyung;Park, Chang-Bean
    • Journal of the Korean Magnetics Society
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    • v.16 no.5
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    • pp.249-254
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    • 2006
  • CoFeNi alloys are some of the most studied soft magnetic materials because of their superial properties over FeNi alloys as write head core materials in HDD and MEMS. We studied the effect of magnetic property according to size and orientation of crystal for electroplated Co-Fe-Ni alleys. In case of heat treated ternary alloy, it affect the change of crystal size and structure. In this study, it intends to improve the magnetic properties of CoFeNi thin film by heat treatment. Minimized coercivity and increased magnetization are due to heat treatment from $300^{\circ}C\;to\;400^{\circ}C$. As a bcc phase formation, it grow to amount of magnetization.

Quantitative Analysis of Magnetization Transfer by Phase Sensitive Method in Knee Disorder (무릎 이상에 대한 자화전이 위상감각에 의한 정량분석법)

  • Yoon, Moon-Hyun;Sung, Mi-Sook;Yin, Chang-Sik;Lee, Heung-Kyu;Choe, Bo-Young
    • Investigative Magnetic Resonance Imaging
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    • v.10 no.2
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    • pp.98-107
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    • 2006
  • Magnetization Transfer (MT) imaging generates contrast dependent on the phenomenon of magnetization exchange between free water proton and restricted proton in macromolecules. In biological materials in knee, MT or cross-relaxation is commonly modeled using two spin pools identified by their different T2 relaxation times. Two models for cross-relaxation emphasize the role of proton chemical exchange between protons of water and exchangeable protons on macromolecules, as well as through dipole-dipole interaction between the water and macromolecule protons. The most essential tool in medical image manipulation is the ability to adjust the contrast and intensity. Thus, it is desirable to adjust the contrast and intensity of an image interactively in the real time. The proton density (PD) and T2-weighted SE MR images allow the depiction of knee structures and can demonstrate defects and gross morphologic changes. The PD- and T2-weighted images also show the cartilage internal pathology due to the more intermediate signal of the knee joint in these sequences. Suppression of fat extends the dynamic range of tissue contrast, removes chemical shift artifacts, and decreases motion-related ghost artifacts. Like fat saturation, phase sensitive methods are also based on the difference in precession frequencies of water and fat. In this study, phase sensitive methods look at the phase difference that is accumulated in time as a result of Larmor frequency differences rather than using this difference directly. Although how MT work was given with clinical evidence that leads to quantitative model for MT in tissues, the mathematical formalism used to describe the MT effect applies to explaining to evaluate knee disorder, such as anterior cruciate ligament (ACL) tear and meniscal tear. Calculation of the effect of the effect of the MT saturation is given in the magnetization transfer ratio (MTR) which is a quantitative measure of the relative decrease in signal intensity due to the MT pulse.

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New Methods of Measuring Magnetization and Coercivity by Torque Magnetometer (토크마그네토미터를 이요한 자화 및 보자력측정의 새로운 방법)

  • Heo, Jin;Sin, Seong-Cheol
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.263-267
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    • 1992
  • We have developed new techniques to measure the magnetization and coercivity of a uniaxial magnetic material using a torque magnetometer. The magnetization could be measured from the slope of the linear region in a plot of the torque ${\tau}/H$ versus the applied field H, when the direction of the applied field was normal to the uniaxial orientation. While, the coercivity could be obtained by taking the value of applied field where the torque was zero, when the direction of the applied field was $(180+{\delta})$ degrees from the uniaxial orientation. The techniques were applied to determine the magnetizations and coercivities of several Co /Pd multilayer thin films and the results were confirmed to be similar within a 2 % difference to those obtained by a vibrating sample magnetometer.

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Properties of Lipases and Palm Oil Assimilating Patterns in Palm Oil Fermentation (팜유발효에 있어서 리파제의 특성과 팜유자화와의 관계)

  • Koh, Jeong-Sam
    • Microbiology and Biotechnology Letters
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    • v.14 no.6
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    • pp.473-478
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    • 1986
  • In order to elucidate the patterns of natural oils and fats assimilation by microorganisms, lipases properties of yeast and bacterium strain, Torulopsis candia Y-128 and Acinetobacter calcoaceticus KB-2, which could assimilate palm oil efficiently, were investigated. T candida Y-128 attached palm oil droplets directly, and assimilated unsaturated fatty acid more easily than saturated acids liberated by the action of its lipase. Lipase of A. calcoaceticus KB-2 was extracellular and appeared quickly from the beginning of log phase of growth, whereas lipase of f candida Y-128 appealed intracellular. The lipases of two strains seem to be only enough to utilize the lipid materials for their own growth, without accumulation of lipases in the culture broth. Lipases of the strains have 1 (3-)-positional specificities on triglycerides. The patterns of palm oil assimilation showed that two strains attached droplets of lipid materials directly and split off fatty acids at 1 (3-)-position of triglycerides first, and assimilated the reaction products via fatty acids metabolic pathway.

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Crystall ographic and Magnetic Properties of Ultrafine $CoFe_{1.9}Bi_{0.1}O_4$ Grown by Using a Sol-Gel Method (Sol-gel법에 의한 초미세 분말 $CoFe_{1.9}Bi_{0.1}O_4$의 결정학적 및 자기적 성질 연구)

  • 김우철;김삼진;김철성;이승화
    • Journal of the Korean Magnetics Society
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    • v.9 no.4
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    • pp.177-183
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    • 1999
  • Ultrafine $CoFe_{1.9}Bi_{0.1}O_4$ particles were fabricated by using a sol-gel method and their magnetic and structural properties were investigated with an x-ray diffractometer (XRD), a vibrating sample magnetometer (VSM), and a M$\"{o}$ssbauer spectrometer. The result of x-ray diffraction and M$\"{o}$ssbauer spectroscopy showed that the powders fired at and above 523 K had only cubic spinel structures. M$\"{o}$ssbauer spectra measurements showed that the powders annealed at 523,723 and 823 K possessed ferrimagnetic nature and paramagnetic nature due to superparamagnetism, simultaneously at room temperature and the powders annealed at and above 923 K behaved ferrimagnetically. In the case of the powder annealed at 923 K, the lattice constant was $a_0=8.398$\pm$0.005{\AA}$ and the hyperfine fields were $H_{hf}(A)=479kOe,\; H_{hf}(B)=502kOe$. The isomer shifts indicate that the iron ions are ferric at tetrahedral[A] and octahedral sites [B], respectively. The magnetization as a function of annealing temperature increased as increasing annealing temperature. The largest coercivity values were $H_C=1368\;Oe$ AT 923 K annealing temperature. In the case of the powder annealed at 1123 K, the magnetization value was $M_S=75\;emu/g$ and this value was similler to that of $CoFe_2O_4$.Fe_2O_4$.

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Magnetic Properties of Hard/Soft Nanocomposite Ferrite Synthesized by Self-Combustion Precursors (자전 연소 전구체로 합성한 나노 크기 경/연 복합페라이트의 자기 특성)

  • Oh, Young Woo;Ahn, Jong Gyeon
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.3
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    • pp.45-50
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    • 2015
  • The goal of this research is the create novel magnets with no rare-earth contents, with larger energy product by comparison with currently used ferrites. For this purpose we developed nano-sized hard-type/soft-type composite ferrite in which high remanent magnetization (Mr) and high coercivity (Hc). Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ composite ferrites were prepared by sol-gel combustion method by use of glicine-nitrate and citric acid. Nanocomposite ferrites were calcined at temperature range $700-900^{\circ}C$ for 1h. According to the X-ray diffraction patterns and FT-IR spectra, single phase of NiZn-ferrite and Ba-ferrite were detected and hard/soft nanocomposite ferrite was indicated to the coexistence of the magnetoplumbite-structural $BaFe_{12}O_{19}$ and spinel-structural $Ni_{0.5}Zn_{0.5}Fe_2O_4$ that agreed with the standard JCPDS 10-0325 data. The particle size of nanocomposite turn out to be less than 120 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite ferrite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that of the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite, and $(BH)_{max}$ is increased slightly.

Magnetic Properties of Cr-Doped Inverse Spinel Fe3O4 Thin Films (Cr 치환된 역스피넬 Fe3O4 박막의 자기적 특성)

  • Lee, Hee-Jung;Choi, Seung-Li;Lee, Jung-Han;Kim, Kwang-Joo;Choi, Dong-Hyeok;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.51-54
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    • 2007
  • By substituting Cr in inverse-spinel $Fe_3O_4,\;Cr_xFe_{3-x}O_4$ thin film samples were prepared by sol-gel spin-coating method and their structural electronic, and magnetic properties were analyzed. X-ray diffraction indicates that the lattice constant decrease with increasing Cr composition (x). This result can be explained in terms of occupation of octahedral sites by $Cr^{3+}$ ions with smaller ionic radius than that of $Fe^{3+}$ Vibrating sample magnetometry measurements on the samples at room temperature revealed that saturation magnetization ($M_s$) decrease by Cr substitution, explainable by comparing spin magnetic moment among the related transition-metal ions. A decrease of magnetoresistence effect with x was observed, similar to that of $M_s$. The coercivity of the $Cr_xFe_{3-x}O_4$ films was found to increase with x, attributed to the increase of magnetic anisotropy by the existence of octahedral $Cr^{3+}(d^3)$.

Magneto-electronic Properties of $Si_{ l-x}Mn_x$ Thin Films Grown by MBE (MBE로 성장한 $Si_{ l-x}Mn_x$ 박막의 전자기적 특성 연구)

  • Kim, Jong-Hwan;Ryu, Sang-Su;Kim, Hang-Yeom;Kwon, Dang;Cho, Yeong-Mi;Lim, Yeong-Eun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.100-100
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    • 2003
  • 본 연구에서는 Si에 Mn을 첨가한 Si$_{l-x}$Mn$_{x}$ 박막의 전기적 및 자기적 특성을 조사하였다. Si$_{l-x}$Mn$_{x}$ 박막은 MBE(Molecular Beam Epitaxy)를 이용하여 native oxide층을 제거하지 않은 (100)Si wafer 위에 성장하였다. Substrate 온도는 50$0^{\circ}C$로 하였으며, 첨가한 Mn 농도는 20%에서부터 80%까지였다. 전기적 특성은 Hall, 4-point probe를 통하여 측정하였고, 자기적 특성은 VSM, FMR, SQUID을 이용하여 측정하였다. 상 분석은 XRD, TEM을 이용하여 관찰하였다 Si$_{l-x}$Mn$_{x}$ 박막은 Hall 측정 결과 상온에서 P-type carrier를 가지며, 비저항은 반도체 영역인 7.6$\times$$10^{-4}$~4.2$\times$$10^{-2}$(ohm-cm)의 값을 가진다. 상온 VSM, 측정결과 Mn의 양이 52% 첨가 시 포화 자화 값이 가장 높은 40emu/cc를 가지며, Mn의 양이 증가할수록 포화 자화 값이 증가하다 다시 감소하는 경향을 가진다. FMR, SQUID 측정에서도 이러한 경향을 확인할 수 있었다 특히, SQUID 분석 결과 두 개 이상의 자성 상이 존재하는 것을 관찰할 수 있었다. XRD, TEM 관찰결과, Si$_{l-x}$Mn$_{x}$은 poly crystal로 성장하였으며, Mn 농도에 따라 여러 상들이 관찰되었다.따라 여러 상들이 관찰되었다.

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Structure and Magnetic Properties of $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ Compounds ($(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ 화합물의 구조 및 자기특성)

  • 김희태;김윤배;김창석;김택기;권혁무
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.196-200
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    • 1993
  • $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ compounds have tetragonal $ThMn_{12}$-type structure and show the uniaxial magnetocrystalline anisotropy with the easy magnetization c-axis. Among the $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ series, RE=Sm shows the highest anisotropy field of 11200 kA/m(140 kOe). On the other hand, RE=Nd has the highest saturation magnetization of $122.3\;Am^{2}/kg$(122.3 emu/g) and RE=Gd the highest Curie temperature of $326^{\circ}C$.

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