• Title/Summary/Keyword: 포졸란 재료

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An Experimental Study on Moisture Sensitivity of High Performance Cellulose Fiber Reinforced Cement Composites (고성능 셀룰로우스 섬유보강 시멘트 복합체의 수분영향에 관한 연구)

  • 원종필;문제길
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.163-170
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    • 1996
  • Cellulose fibers, being fairly strong and stiff as well as cheap and plentiful with low energy demand during manufacture, are strong contenders for the reinforcement of cement-based materials. Cellulose fiber-cement composites, generally manufactured by slurry-dewatering procedure, can find applications in the production of flat and corrugated cement sheets and many other thin-sheet cement products. This paper presents the results of an experimental study concerned with the effects of fiber content and moisture conditions on the flexural performance of these composites. An effort was also made to study the effect of pozzolanic admixtures on the flexural performance in different moisture conditions. The test results obtained were analyzed statistically using the analysis of variance in order to derive reliable conclusions. The results generated in this study were indicative of significant effects of fiber content and moisture condition of flexural performance. There is a tendency in flexural strength to increase in increase in fiber content up to 8%: flexural toughness values continue to increase even at higher fiber contents. Moisture content has a significant effect on the flexural performance. There is a tendency in flexural strength to decrease and flexural toughness to increase with increasing moisture content Composites incorporating pozzolans showed an increase in the flexural strength while slightly reducing the flexural toughness and were sensitive to variations in moisture content.

Characteristics of Calcium Leaching Resistance for Concrete Mixed with Mineral Admixture (광물질 혼화재를 혼합한 콘크리트의 칼슘용출 저항 특성)

  • Choi, So-Yeong;Choi, Yoon-Suk;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.59-67
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    • 2016
  • Concrete is a very useful construction material for the sealing disposal of hazardous substances. In general, mass concrete is applied to these structures. And, the mineral admixtures are recommended for the long term performance. Calcium leaching could be happened due to the contact with pure water in underground structures. Thus, it is needed to evaluate the resistance of calcium leaching for concrete mixed with mineral admixtures. From the test results, the mineral admixtures are effective to the improvement of long term compressive strength and chloride diffusion coefficient in concrete members. When calcium leaching is happened, however, the reduction of compressive strength and chloride penetration resistance is severe than OPC case, the micro pore distribution is adversely affected. Consequently, when the mineral admixtures are applied to underground structures which is exposed to calcium leaching environment, it is desirable to reduce water-to-binder ratio, to expose after the sufficient pozolanic reaction, and to use BFS than FA.

Hydration and Mechanical Properties of High-volume Fly Ash Concrete with Nano-silica (나노 실리카를 혼입한 하이볼륨 플라이애시 콘크리트의 수화도 및 역학적 특성)

  • Cha, Soo-Won;Lee, Geon-Wook;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.112-119
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    • 2022
  • Recently, as carbon neutrality has been important factor in the construction industry, many studies have been conducted on the high-volume fly ash concrete. High volume fly ash concrete(HVFC) is usually made by replacing more than 50% of cement with fly ash. However, HVFC has a disadvantage of low compressive strength in early age. To overcome this shortcoming of HVFC, improve this, interest in techonolgy using nanomaterials is increasing. Nano silica is expected to improve the early age strength of HVFC as a pozzolanic material. This study investigated the effect of nano silica on the early hydration reaction and microstructure of HVFC. The early hydration reaction of HFVC was analyzed through setting time, isothermal calorimeter, compressive strength and thermal weight analysis. In addition, the microstructure of HVFC was measured by mercury intrusion porosimetry. From the test results, it was confirmed that nano silica increased the early age strength and improve the microstructure of HVFC.

A Study on the Pore Structure and Compressive Strength of Concrete using Metakaolin (메타카올린을 사용한 콘크리트의 공극구조와 압축강도에 관한 연구)

  • Yeo, Dong Ku;Kim, Nam Wook;Song, Jun Ho;Bae, Ju Seong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.5A
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    • pp.927-934
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    • 2006
  • According to the high demand of concrete structures with high performance, various studies have examined on the high performance concrete, especially high strength concrete. Various admixtures are required to produce high strength concrete and silica fume has been the most popular admixture. Recently, however, metakaolin, which is similar to silica fume in properties but cheaper, has been introduced to high strength concrete. This study conducted XRD and SEM analyses on a cement paste specimens to clarify metakaolin's performance in pozzolan. Additionally, a concrete specimens were fabricated to analyze its pore structure using Mercury Intrusion Porosimetry and its correlation to the compressive strength. In result, it was found that the average diameter of pore reduced and compressive strength increased as more metakaolin content was added. In addition, a regression analysis of $10nm{\sim}10{\mu}m$ pore and compression strength revealed that these two factors had a high correlation of about 0.93 and 10~15% of metakaolin replacement was most appropriate.

광물재료를 이용한 연약지반 점토의 고화안정처리 실험

  • 황진연;류춘길;강병주;김병규
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.7-7
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    • 2001
  • 다량의 점토 퇴적물로 구성된 연약지반은 대단히 큰 압축성과 낮은 강도, 높은 함수량등의 물리·역학적 특성을 갖는다. 이러한 기초지반으로서의 불리한 특성 때문에 이를 대상으로 하는 각종 토목건설공사에서는 지반개량이나 안정처리가 반드시 선행되어야 할 과제이다. 이를 위해 종래에는 샌드드레인, 페이퍼드레인 등의 물리적인 공법에 의한 지반개량이 주류를 이루었으나, 최근에는 생석회나 시멘트계 고화재를 이용한 화학적 안정 처리공법이 크게 주목을 받고 있어 이에 대한 연구가 활발한 상황이다. 본 연구는 연약 지반 안정처리에 대한 방안을 모색하기 위하여 김해 지역에 분포하는 점토 퇴적물을 대상으로 각종 광물재료를 이용한 반응실험을 통하여 반응생성물 조사와 압축강도시험 등을 행하여 그 결과를 검토하였다. 우선 연약지반의 고화에 이용 가능한 생석회, 석고, 플라이에쉬, 고분자폴리머, 시멘트 등을 사용하여 점토와 혼합한 고화실험을 행하였으며, 이에 대한 물성 및 반응생성물을 검토하였다. 이러한 각 재료를 점토에 혼합한 후 PVC관에 모울딩하여 양생시켜 실험하였다. 그 결과, 석고 및 소석회에 비하여 생석회의 경우가 비교적 큰 압축강도를 나타내고, 균열발생 빈도도 낮았다. 생석회의 경우에 Gehlenite, Hillebrandite 등의 생성물질이 검출되었다. 그러나 포틀란트 시멘트와 혼합한 경우가 강도가 가장 크게 나타났다. 반면에 고분자폴리머만 사용한 경우는 강도가 매우 낮았다. 따라서 시멘트를 일정 비율로 배합한 다른 재료를 첨가한 실험을 행하여 그 물성을 검토하였다 물질의 화학적인 특성을 고려하여 포졸란반응이 잘 일어날 수 있을 것으로 생각되는 여러 재료를 선정하여 많은 조합에 대한 실험을 행하였다. 생석회, 석고, 고령토, 규조토, 제올라이트 등의 여러 재료를 여러 조합으로 첨가하여 실험한 결과, 시멘트와 석고를 혼합한 것이 비교적으로 높은 압축강도를 나타내었다. 그리고 이러한 연구 결과를 바탕으로 연약점도의 고화에 최적인 조합과 배합비를 위한 실험을 재차 실시하였으며, 실험 후의 물성과 함께 반응생성물에 대한 검토도 행하여 그 결과를 발표하고자 한다.

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Analysis of the Mix Ratio of Lime Mortar used in Joseon Dynasty Seongnam Godeung-dong Barrier Tombs (성남 고등동 회곽묘 삼물회의 배합비 분석)

  • Lee, Sangok;Bae, Gowoon;Chung, Kwangyong
    • Korean Journal of Heritage: History & Science
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    • v.53 no.1
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    • pp.34-51
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    • 2020
  • In order to clarify the lime-based building method used in the Joseon Dynasty, lime materials, production techniques, and mixing methods recorded in ancient literature were examined. In ancient Joseon Dynasty literature, the use of low grade limestone as a raw material was recorded, and the use of pozzolanic materials such as Hwangtoh, white clay, and roof tile powder as mixing aids to enhance the strength of lime was recorded. In addition, various lime hydration and mixing methods were recorded, and based on re-experiments carried out with regards to this, a physical property evaluation was deemed to be required in accordance with the various types of raw lime materials, lime hydration methods, and mixture ratios. In the early Joseon Dynasty, lime was used for various aspects, but frequent problems were experienced due to lack of supply and poor production techniques. In the late Joseon Dynasty, lime production techniques developed along with mass production. Based on analysis of the manufacturing techniques of Hoegwagmyo lime mortar in the 16th and 18th centuries during the Joseon Dynasty, it was found that mixing ratios and the methods described in the ancient literature had been applied. It was confirmed that the mixing ratio differed depending on mixing materials and lime quality. Since the mixing ratio of Hoegwagmyo lime mortar changed over time and it was produced strictly on the basis of a guidebook, it is believed that if continuous scientific analysis of the Hoegwagmyo lime mortar production method were carried out, this would be helpful for ascertaining the chronological methodology of Hoegwagmyo.

A Study on Self-Hardening Characteristics of Coal Ash by Mixing Ratio of Fly Ash and Bottom Ash (비회와 저회의 배합비에 따른 석탄회의 자경성에 관한 연구)

  • Shin, Woonggi;Lim, Daesung;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.6
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    • pp.85-91
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    • 2010
  • As enormous construction projects of land development are carried out around Korea, useful construction materials are needed to perform the construction projects. However, there are no more enough of fill and reclamation materials in our country. That is why the coal ash is expected to be utilized as an alternative material. Since the coal ash has the characteristics of a pozzolan and a selfhardening material, it is adjudged that coal ash has a great possibility to be used as a fill and reclamation material. In this study, grain size analysis, Atterberg limit test, and specific gravity test were performed to examine the physical characteristics of the coal ash about a self-hardening material before utilizing the coal ash in the construction. Compaction test, unconfined compression test, direct shear test, and flexible wall permeability test were conducted to investigate the engineering characteristics according to mixture ratios of fly ash and bottom ash. As a result of the tests, it was confirmed that the mixing ratio 1:1 of fly ash and bottom ash is the most effective to use as a fill and reclamation material. If the mixture of coal ash is used as a backfill material with light weight around structure, it is expected to play a significant role in reducing earth pressure on the back of the structure. As the age of the mixture of coal ash goes by, it intends to decrease the coefficient of permeability. As described above, the coal ash should be considered as an alternative material of fill and reclamation materials since the result of the tests indicates that the coal ash is suitable to a useful material on the construction design.

A Hydration Reaction and Strength Development Properties of Cement Using Pond Ash in Coal Fired Power Plant (화력 발전소 매립회를 치환한 시멘트의 수화반응 및 강도발현 특성)

  • Lee, Jae-Seung;Noh, Sang-Kyun;Shin, Hong-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.578-584
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    • 2021
  • This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)2 consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

Evaluation of Time-Dependent Chloride Resistance in HPC Containing Fly Ash Cured for 1 Year (1년 양생 조건의 Fly Ash를 혼입한 고성능 콘크리트의 시간의존적 염해저항성 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.52-59
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    • 2018
  • To control chloride attacks which is a representative deterioration in RC(Reinforced Concrete) structures, many studies have been conducted. Above all, a method using mineral admixture was known to be effective for corrosion protection. In this study, durability test about chloride attacks was carried out for concrete specimens containing FA(Fly Ash)-representative concrete mineral admixture and OPC concrete specimens considering 3 different levels of W/B(Water to Binder). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests based on KS F 2405 were performed at each target age day. Also, based on previous studies of 28 days, time-parameter which is a key parameter for diffusion behavior is evaluated and its relations with compressive strength at the age of 365 days is evaluated. After the age of 49 days, chloride resistance of FA concrete is much improved than that of OPC concrete, which arose out of stable hydrates due to pozzolan reaction of fly ash. Time-parameter of FA concrete is evaluated to be about 1.5 times larger than that of OPC concrete. Also, time-parameter of FA concrete has a linearly decreasing relation while that of OPC concrete has a linearly increasing relation with compressive strength development.

Evaluation of Mechanical Properties of Mortar Mixed with Zeolites and Active Hwangtoh (제올라이트 및 활성 황토를 혼입한 모르타르의 역학적 특성 평가)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Kim, Hyeok-Jung;Hyun, Jung-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.405-412
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    • 2019
  • In this study, the physical and chemical properties of mortar are evaluated by micro-analysis, taking into account the substitution rate(20%, 30%, and 40%) of zeolite with porous properties and active hwangtoh. First, the physical and chemical properties of zeolite and active hwangtoh are reviewed to confirm that the specific surface area of those is similar with ordinary portland cement, and the main chemical composition is SiO2, Al2O3, Fe2O3, etc.. So, it is thought that they have the properties of pozolan reactive materials. As the results of the strength test considering the amount of substitution based on that of cement, It is confirmed that strength decreases with the increase of the replacement amount of zeolite and active hwangtoh, and the strength of mortar with replacement rate of 20% is higher than OPC mortar. It is confirmed that the amount of porosity is increased due to chemical properties of zeolite and active hwangtoh, and in particular, the size of the pore is greater than 1㎛ in mortar mixed with active hwangtoh.