• Title/Summary/Keyword: 평형 접촉각

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Synthesis and Characterization of Interfacial Properties of Sorbitan Laurate Surfactant (Sorbitan Laurate 계면활성제 합성 및 계면 특성에 관한 연구)

  • Lee, Seul;Kim, ByeongJo;Lee, JongGi;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.37-44
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    • 2011
  • The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.

Determination of Surface Energy by Means of Home-Made Goniometer and Image Analyzing Software for Contact Angle Measurement (수제 접촉각 측정기와 영상 분석 프로그램을 이용한 표면에너지의 측정)

  • Cho, Seo-Rin;Cho, Han-Gook
    • Journal of the Korean Chemical Society
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    • v.57 no.4
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    • pp.432-438
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    • 2013
  • We report a contact angle goniometer that can be easily assembled and used in high school and general chemistry experiments. It consists of an LED flash, a sample stand, and a camera fixed on an optical bread board, and the sample area is covered to block light from outside with a box with holes on both sides. ImageJ, free image analyzing software and a JAVA plugin (Drop_analysis) were used to determine the contact angle of liquid drop resting on solid surface. The contact angles of various liquids were successfully measured on various surfaces. The solid surface energies have also been determined using the Owen-Wendt method from the contact angles of $H_2O$ and $CH_2I_2$. The results reasonably agree with the previously reported values, showing the surface characteristics and modification as well as the dispersive and polar contributions. These contact angle goniometer and method for determination of the contact angle and surface energy can be applied to observation of various surface properties including wettability, hydrophilicity, and water repelling. Students can learn how the surface properties are related to the intermolecular interactions and gain experience about the equilibrium between the related forces, optics, and mathematical derivations.

Analysis of Frictional Contact Problems of Nonlinearly Deformable Bodies by Using Contact Error Vector (접촉 오차 벡터를 이용한 비선형 변형체의 마찰접촉 해석)

  • Lee, Kisu;Kim, Bang-Won
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.3
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    • pp.305-319
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    • 2000
  • Numerical solution lot frictional contact problems of nonlinearly deformable bodies having large deformation is presented. The contact conditions on the possible contact points are expressed by using the contact error vector, and the iterative scheme is used to reduce the contact error vector monotonically toward zero. At each iteration the solution consists of two steps : The first step is to revise the contact force by using the contact error vector given by the previous geometry, and the second step is to compute the displacement and the contact error vector by solving the equilibrium equation with the contact force given at the first step. Convergence of the iterative scheme to the correct solution is analyzed, and the numerical simulations we performed with a rigid-plastic membrane and a nonlinear elastic beam.

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Study on the Resistance for Atmospheric Corrosion of Conventional Epoxy Resins applied to the Restoration of Iron Relics (철기 유물 복원에 사용되는 에폭시 수지 내후성 연구)

  • Lee, Sang-Jin;Kwon, Jeong-Soon;Nam, Byeong-Jik;Ahn, Byung-Chan
    • Journal of Conservation Science
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    • v.21
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    • pp.41-48
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    • 2007
  • The resistance for atmospheric corrosion of the conventional 5 epoxy resins (Araldite rapid, Araldite AW 106, Araldite SV 427, Devcon, and CDK), those were used to restoration of the iron relics, were investigated in this study. Temperature, UV light, and water were chosen for the factors of the atmospheric corrosion. The drastic voluminous changes of the epoxy resins were found at the temperature range between $40^{\circ}C$ and $70^{\circ}C$ After UV exposure, the colors of the epoxy resins were severely changed. In case of the indoor exposure the chroma value(${\Delta}E$) of the resins were less than 2, which showed a little changes of the colors. The result of the water contact angle test was Araldite rapid>AW 106>Devcon>SV 427>CDK. Although the contact angles of the resins were reduced by UV exposure, SV 427 was stable comparatively.

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Shear Angle Variation Depending on Chip-Tool Friction in Orthogonal Cutting (二次元 切削時 칩-工具 마찰상태에 따른 剪斷角 변화)

  • 이영문;송지복
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.2
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    • pp.252-261
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    • 1988
  • Through the careful interpretation of the results of the cutting tests carried out in this study, it is found that under the cutting conditions when the internal shear of the chips take place the cutting can be treated essentially as a steady state problem. A new shear angle equation has been developed employing the conditions of force and moment equilibrium about the tool edge and the stress distribution model suggested by Zorev.The equation contains the chip-tool contact length C and stress distribution index n as important parameters.

Wetting Behavior and Evaporation Characteristics of Nanofluid Droplets on Glass Surfaces (나노유체 액적의 젖음거동 및 증발 특성)

  • Shin, Dong-Hwan;Lee, Seong-Hyuk
    • Journal of ILASS-Korea
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    • v.17 no.1
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    • pp.9-13
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    • 2012
  • This study investigates experimentally evaporation characteristics of nanofluid droplets containing 50 nm alumina($Al_2O_3$) particles and the wettability changes on a hydrophilic glass surfaces. From the captured digital images by using a CMOS camera and a magnifying lens, we examined the effect of particle concentration on droplet evaporation rate which can be indirectly deduced from the measured droplet volumes varying with time. In particular, with the use of a digital image analysis technique, the present study measured droplet perimeters and the contact angles to study the wetting dynamics during evaporating process. In addition, we compared the measured total evaporation time with theoretically estimated values. It was found that as the volume fractions of nanofluid increased, the total evaporation time and the initial contact angles decreased, while the droplet perimeters increased.

The Fluxless Wetting Properties of TSM-coated Glass Substrate to the Pb-free Solders (TSM(Top Surface Metallurgy)이 증착된 유리기판의 Pb-free 솔더에 대한 무플럭스 젖음 특성)

  • 홍순민;박재용;박창배;정재필;강춘식
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.2
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    • pp.47-53
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    • 2000
  • The fluxless wetting properties of TSM-coated glass substrate were evaluated by the wetting balance method. We could estimate the wettability of the TSM with new parameters obtained from the wetting balance test for one side-coated specimen. It was more effective in wetting to use Cu as a wetting layer and Au as a protection layer than to use Au itself as a wetting layer. The SnSb solder showed better wettability than SnAg, SnBi, and SnIn solders. The contact angle of the one side-coated glass substrate to the Pb-free solders could be calculated from the farce balance equation by measuring the static force and the tilt angle.

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옥천변성대 서남부지역 변성퇴적암

  • 김성원;오창환;이덕수;이정후
    • Proceedings of the Petrological Society of Korea Conference
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    • 2002.05a
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    • pp.1-38
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    • 2002
  • 옥천변성대 서남부지역은 변성이질암의 광물조합을 기준으로 남동부부터 북서방향으로 흑운모대, 석류석대, 십자석대의 3개의 변성광물분대로 나누어진다. Oh et al. (1995a)의 연구에서 보고된 남정석들은 산출되지 않는 것이 확인되었고 변성도는 흑운모대에서 석류석대를 거쳐 십자석대로 갈수록 증가한다. 쥬라기 화강암 접촉부의 국부적인 변성암류에서는 화강암에 의한 접촉변성작용에 의해 형성된 홍주석과 규선석이 산출된다. 흑운모대의 변성 압력-온도는 4.2 - 5.1 kb, 400 - 500 $^{\circ}C$이다. 십자석대의 정누대구조를 가지는 석류석과 석류석안의 사장석, 흑운모, 금흥석, 일메나이트포유광물의 공생관계로 추정한 압력-온도 (석류석 주변부: 7.0 - 8.0 kb, 550 - 620 $^{\circ}C$; 석류석 중심부: 4.0 - 5.0 kb, 420 - 520 $^{\circ}C$) 및 십자석대 내에서 후퇴변성작용 및 접촉변성작용 받은 석류석 주변부에 기록된 압력-온도 조건(약 2.0 - 3.0kb, 450 - 55$0^{\circ}C$)과 함께 옥천변성대 서남부지역의 변성암류가 시계방향의 압력-온도 경로를 겪었음을 지시한다. 연구지역 내에서 정밀 기재된 단면들에 대한 퇴적환경을 종합하면 대체 적으로 남동부에서는 천해성 환경이 인지되나 북서쪽으로 갈수록 대륙사면을 거쳐 분지 중심의 환경으로 전이되는 경향을 보인다. 이러한 퇴적상의 공간적 분포는 분지의 남동쪽보다 북서쪽의 침강이 우세하였던 것으로 해석될 수 있으며, 이는 곧 분지가 형성될 때 반지구대 (half graben) 형태로 분지가 열개 (rifting) 되었음을 의미한다. 각 변성분대에서 채취한 변성이질암으로부터 측정된 K-Ar 과 40Ar/39Ar 흑운모와 백운모 연대들은 149 - 167 Ma에 집중된다. 그리고 각 변성분대에서 동일시료에 대한 K-Ar 과 40Ar/39Ar 연대들은 동일시기를 지시함으로 연대적인 신뢰성을 확인 할 수 있었다. 옥천변성대 서남부지역의 변성암류를 관입하는 2개의 괴상의 화강암과 1개의 엽리화강암에서 얻어진 백운모와 흑운모들의 K-Ar 연대는 모두 156 Ma이며 옥천변성대 서남부지역의 변성이 질암의 연대와 유사하다. 이는 연구지역의 변성암류와 화강암류는 40Ar/39Ar 과 K-Ar 계의 흑운모와 백운모의 폐쇄온도 (약 300 - 350 $^{\circ}C$) 까지 동시에 냉각된 사실을 지시한다. 각섬석 편암내의 각섬석들은 복잡한 40Ar/39Ar 연대를 보여주며 일부가 평형연대를 보여주지만 특별한 의미 부여가 힘들다.

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The Effect of the Wettability of Solid Surface on Printing Pattern in Screen Printing (스크린 인쇄 공정에서 고체면의 젖음성이 인쇄형상에 미치는 영향)

  • Park, Jungkwon;Kim, Chongyoup
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.397-400
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    • 2010
  • The interfacial hydrodynamic issues in the screen printing are experimentally investigated by using model inks that are prepared by dispersing alumina nanoparticles in water. The printing patterns of the inks that are passed through differing geometrical shapes of screen on solid surfaces with differing wettability are not solely determined by the pattern on the screen. The dynamic contact angle cannot solely explain the physics of the problem, either. The difference between the screen and printing patterns was not the same for concave and convex corners. Especially the elasticity of ink affects the edge shape.

Boundary/Finite Element Analysis of the Seismic Wave Amplifications Due to Inhomogeneous Alluvial Deposits (비균질 퇴적층으로 인한 지진파 증폭의 경계/유한요소 해석)

  • 김효건;손영호;김종주;최광규
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.4
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    • pp.591-597
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    • 1999
  • 본 연구에서는 비 균질 퇴적층으로 인한 지진파의 증폭에 대한 경계/유한요소 해석을 수행하였다. 수치해석을 위해, 비 균질 퇴적층은 8절점 등 매개 변수 유한요소 사용하여 모델링하였고, 그 주위의 균질 반무한 지반은 3절점 등매개 변수 경계요소를 사용하여 모델링하였다. 경계요소와 유한요소의 접촉면에서, 표면 력의 평형조건과 변위의 적합 조건에 의해 두 개의 요소를 결합하는 알고리듬을 개발하였다. 수치해석의 영향인자로서 SH파, P파와 SV파의 입사각, 무 차원 진동수 그리고 반무한 지반과 퇴적층사이의 전단 파 속도 비와 질량밀도 비를 고려하였다.

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