• Title/Summary/Keyword: 평형조건

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Optical Resolution of Racemic Ibuprofen by Candida Rugosa Lipase Catalyzed esterification (Candida Rugosa Lipase에 의한 Ibuprofen 에스테르화 반응과 광학분할)

  • 홍중기;김광제;소원욱;문상진;이용택
    • KSBB Journal
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    • v.17 no.6
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    • pp.543-548
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    • 2002
  • The enantioselective esterification of racemic ibuprofen catalyzed by a Candida rugosa lipase was studied according to reaction conditions such as a lipase concentration, reaction temperature, alcohol chain length and alcohol concentration. The S-(+)-ibuprofen alkyl esters prepared were converted to S-(+)-ibuprofen by hydrolysis with sulfuric acid as a catalyst. High conversions in the esterifications were obtained at 60$^{\circ}C$ and an equimolar ratio of octanol to ibuprofen. The initial reaction rate of the esterification decreased with increasing octanol concentration. Conversion and initial reaction rate increased with increasing alcohol chain length. Values of enantiomeric excess(ee) according to esterification reaction conditions did not change below 60$^{\circ}C$. On the other hand, values of conversion and ee for the chemical hydrolysis of S-(+)-ibuprofen alkyl esters were independent of alcohol alkyl chain length. Optical resolution of racemic ibuprofen was achieved by lipase catalyzed esterification and chemical hydrolysis. The separation method provided a high yield and enantioselectivity for the production of S-(+)-ibuprofen from racemic ibuprofen.

Characteristics of Turbulent Flows and Suspended Sediment Transport in Open-channel with Submerged Vegetation (침수식생 개수로에서 난류 및 부유사 이동 특성)

  • Yang, Won-Jun;Jang, Ji-Yeon;Choi, Sung-Uk
    • Journal of Korea Water Resources Association
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    • v.44 no.5
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    • pp.417-427
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    • 2011
  • The open-channel flow with submerged vegetation shows distinct features in two separate regions, namely upper and vegetation layers. In the upper layer, the flow is akin to the open-channel flow, while the flow in the vegetation layer is relatively uniform with suppressed turbulence due to vegetation stems. This paper presents laboratory experiments to investigate the characteristics of turbulent flows and suspended sediment transport in open-channel flows with submerged vegetation. An open-channel facility, 0.5 m wide and 12 m long, was used for laboratory experiments. Various discharges were employed with depth ratios of 2~3, and wooden cylinders were used for vegetation. To make equilibrium suspension, sediment particles of median diameter of 75 ${\mu}M$ were fed until capacity condition. Laser Doppler velocimeter was used to measure instantaneous velocity, and direct sampling with vinyl tube was used to measure the concentration of suspended sediment. Using the sampled data, the mean flow and turbulence structures were provided and characteristics of suspended sediment concentration with Rouse number were presented.

Physical Properties of Freeze-Dried Powder of Aloe Vera Gel with Respect to the Concentrating Degree as Pre-Treatment (전처리 농축 정도에 따른 Aloe Vera gel의 동결건조분말의 물성)

  • Lee, Nam-Jae;Lee, Seung-Ju
    • Korean Journal of Food Science and Technology
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    • v.41 no.1
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    • pp.32-36
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    • 2009
  • The physical properties of freeze-dried Aloe vera gel powders were examined according to the influence of the concentration degrees of the gel solutions as raw materials during freeze-drying. As a pre-treatment prior to freeze-drying, the gel solutions were vacuum-concentrated at three concentration levels (g water/g solids): high (H), 76; medium (M), 119; and low (L), 159. The water contents of the three powder samples were almost the same. For their viscosity measurements, non-Newtonian fluid behavior with shear thinning was observed in samples H and M, whereas Newtonian liquid behavior was found in sample L. In electrical conductivity measurements, sample H showed the highest conductivity upon dissolving the powder in water. For their water sorption isotherms, sample H was analyzed to have the least amount of bound water. Finally, it was determined that the degree of concentration caused only slight differences in the physical properties of freeze-dried Aloe gel powders.

Optimum Operation of Power System Using Fuzzy Linear Programming (퍼지 선형계획법을 적용한 전력계통의 최적운용에 관한 연구)

  • 박성대;정재길;조양행
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.8 no.1
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    • pp.37-45
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    • 1994
  • A method of optimal active and reactive power control for economic operation in electrical power system is presented in this paper. The major features and techniques of this paper are as follows: 1) The method presented for obtaining the equivalent active power balance equation applying the sparse Jacobian matrix of power flow equation instead of using B constant as active power Balance equation considering transmission loss, and for determining directly optimal active power allocation without repeating calculations. 2) More reasonable and economic profit by minimizing total fuel cost of thermal power plants instead of using transmission loss as objective function of reactive Power control can be achieved. 3) Particularly in reactive power control, computing time can be considerably reduced by using Fuzzy Linear Programming instead of using conventional Linear Programming.

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An approach to predict size distribution of suspended sediment - cohesive sediment (유사의 입경분포 모의를 위한 방안 연구 - 점착성 유사의 경우)

  • Son, Minwoo;Byun, Jisun;Park, Byeoung Eun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.288-288
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    • 2018
  • 점착성 유사는 응집 현상을 겪는 유사로, 응집 현상(Flocculation Process)는 응집 과정(Aggregation Process)와 파괴 과정(Breakup Process)의 경쟁으로 이루어진다고 여겨진다. 응집 현상을 통해 점착성 유사는 물과 점착성을 띠는 작은 입자들의 덩어리인 플럭(Floc)을 형성하여 흐름 내에서는 대부분이 플럭의 형태로 이동한다. 점착성 유사의 응집 모형 중 하나인 플럭 성장모형(Floc Growth Model, FGM)은 상미분 방정식으로 시간에 따른 플럭의 크기를 계산하는 모형이다. 응집과 파괴의 평형 상태에서 평균 입경을 얻는다. 이러한 FGM은 낮은 수치 계산 비용으로 합리적인 계산 결과를 얻을 수 있으며, 유사 이동 모형 혹은 흐름 모형과의 결합이 수월한 장점을 가진다. 또한, 닫힌 계(Closed System)에서 질량이 보존되는 특징이 있다. 반면, 결정론적인 특성을 띠면서 특정 플럭 크기만을 계산하기 때문에 점착성 유사의 입도 분포에 대한 정보를 얻을 수 없다. 결정론적 특성을 띠는 FGM에 추계학적 방법을 적용함으로써 특정 확률 분포형을 가지는 플럭의 입도 분포를 얻을 수 있다. 본 연구에서는 기 개발된 추계학적 FGM과 유사 이동 모형의 결합을 통해 변화하는 유수동역학적 조건에서 플럭의 입도 분포를 산정하고자 한다. 이전의 많은 실험실 실험 결과들은 부유가 발생한 상태를 유지하면서 수행되는 것으로, 특정 난류 특성(난류 소산 매개변수)와 특정 유사 농도 조건에서의 입도 분포를 얻는다. 그러나 하구부 및 하천의 하류는 조류의 영향을 받는 구간으로, 점착성 유사의 특성을 분석하기 위해서는 변화하는 유수동역학적 특성에 관한 고려가 필수적이라 할 수 있다. 결합된 점착성 유사 입도 분포 모형은 플럭의 침강과 재부유를 고려할 수 있는 특징을 가지며, 실측자료와의 비교를 통해 입도 분포를 합리적으로 모의하는 것으로 나타난다. 본 연구에서 개발된 점착성 유사 입도 분포 모형은 나아가 비점착성 유사의 입도 분포 모형과의 결합을 통해 두 종류의 유사가 혼재하는 구간에서도 합리적인 입도분포와 유사의 이동을 모의할 수 있을 것으로 예측된다.

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Development of Gas Turbine Engine Simulation Program Based on CFD (CFD 기반 가스터빈 엔진 모사 코드 개발)

  • Jin, Sang-Wook;Kim, Kui-Soon;Choi, Jeong-Yeol;Ahn, Iee-Ki;Yang, Soo-Seok;Kim, Jae-Hwan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.2
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    • pp.42-53
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    • 2009
  • Gas turbine engine simulation program has been developed. In compressor and turbine, 2-D NS implicit code is used with k-$\omega$ SST turbulent model. In combustor, 0-D lumped method chemical equilibrium code is adopted under the limitations, the products are only 10 species of molecular and air-fuel is perfectly mixed state with 100% combustion efficiency at constant pressure. Fluid properties are shared on interfaces between engine components. The outlet conditions of compressor have been used as the inlet condition of combustor. The inlet condition of turbine comes from the compressor The back pressure in compressor outlet is transferred by the inlet pressure of turbine. Unsteady phenomena at rotor-stator in compressor and turbine is covered by mixing-plane method. The state of engine can be determined only by given inlet condition of compressor, outlet condition of turbine, equivalence ratio and rotating speed.

Ability to Maintain Dynamic Posturography in Gymnastic, Free style skier, and Figure skater (여자 체조, 피겨 및 프리스타일 선수의 동적자세 유지능력의 비교)

  • Jeong, Cheol;Park, Woo-Young
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1472-1479
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    • 2018
  • The purpose of this study was to investigate the ability to maintain dynamic posturography(EquiTest) in gymnastic, freestyle skier, and figure skater. A total of 32 subjects(22 athletic woman and 10 collegiate woman) were participated in this study. Computerized dynamic posturography(EquiTest) was adopted to test sensory organization and motor control. EquiTest facilitated the quantification of the role of somatosensory, visual and vestibular systems in the maintenance of postural balance and was also pertinent to measure the reaction time to the stimulus to change center of gravity on force platform. As a result were as follow. There was not difference among with exercise group. But there was a significantly difference with between groups. It was suggested that the acrobatic and physical activity developed the function of visual system and the role of the combination of visual and vestibular system in maintaining postural balance to surrounding stimulus, and presented shorter reaction time in automatic postural response.

Prediction of Rolling Moment for a Hand-Launched UAV Considering the Interference Effect of Propeller Wake (프로펠러 후류 간섭 효과를 고려한 투척식 무인기 롤 모멘트 예측)

  • Sang-Mann, Woo;Dong-Hyun, Kim;Ji-Min, Park
    • Journal of Aerospace System Engineering
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    • v.16 no.6
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    • pp.114-122
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    • 2022
  • This paper explores three-dimensional unsteady computational fluid dynamic (CFD) analyses with an overset grid technique to analyse the wake effect created by a rotating propeller on a hand-launched unmanned aerial vehicle (UAV). Additionally, the influence of actual aileron deflection on the equilibrium condition of the rolling moment is examined in various hand-launched take-off conditions. The results of this study demonstrate the importance of initial aileron deflection in increasing the initial rolling stability during the hand-launched take-off process. Furthermore, an aerodynamic database is constructed to rapidly predict the aileron set values required for different take-off speeds and angle-of-attacks.

Numerical Investigation on the Stability of Reinforced Earth Wall during Rainfall (강우시 보강토 옹벽의 안정성에 관한 수치 해석 연구)

  • Yoo, Chung-Sik;Kim, Sun-Bin;Han, Joon-Yeon
    • Journal of the Korean Geotechnical Society
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    • v.24 no.12
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    • pp.23-32
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    • 2008
  • This paper presents the results of numerical investigation on the stability of reinforced earth wall during rainfall. A series of limit-equilibrium based slope stability analyses within the framework of unsaturated shear strength, coupled with transient seepage analyses, were conducted with due consideration of rainfall characteristics in Korea. It is shown that the factor of safety of the reinforced wall during rainfall decreases with time due to decreases in the suction in the reinforced as well as retained zones. Also revealed is that the decrease in the factor of safety depends not only on the backfill soil type but also on the rainfall characteristics. Practical implications of the findings were discussed.

Residual Liquid Behavior Calculation for Vacuum Distillation of Multi-component Chloride System (다성분 염화물계 진공 증류의 잔류 액체 거동 계산)

  • Park, Byung Heung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.179-189
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    • 2014
  • Pyroprocessing has been developed for the purpose of resolving the current spent nuclear fuel management issue and enhancing the recycle of valuable resources. An electrolytic reduction of the pyroprocessing is a process to reduce oxides into metals using LiCl as an electrolyte and requires a post-treatment process due to the inclusion of residual salt in porous metal products. A vacuum distillation has been adopted for various molten salt systems and could be applied to the post-treatment process of the electrolytic reduction. The residual salt in the metal products includes LiCl, alkali chlorides, and alkaline earth chlorides. In this paper, vapor pressures of chlorides have been estimated and the composition changes on the residual liquid during the vacuum distillation process have been calculated. A model combining a material balance and vapor-liquid equilibrium relations has been proposed under a constant vapor discharging flow rate and liquid composition changes have been calculated using the vapor pressures with respect to a dimensionless time. The behaviors have been compared with temperature and molten salt composition changes to simulate the process condition variation. The distillation of the residual salt has been dominated by LiCl which is the main component of the salt and CsCl of which vapor pressure is higher than that of LiCl would be readily removed. RbCl exhibits similar vapor pressure with LiCl and maintains its composition. However, $SrCl_2$ and $BaCl_2$ of which vapor pressures are much lower than that of LiCl are concentrated with time and expected to be possibly precipitated during the distillation when the initial compositions are increased.