• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2018.05a
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• pp.189-190
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• 2018

금회 연구대상인 아산만 내측에 위치한 배수로는 항만 건설로 인하여 인공적으로 생성된 감조하천의 성격을 띄고 있다. 이러한 인위적으로 설정된 배수로는 일반 하천에 비하여 유속이 크고 단순화된 유로로 인하여 퇴적 또는 침식우세 등의 극단적인 성격이 보인다. 따라서 이러한 퇴적환경 현황을 파악하기 위하여 금회 연구에서는 퇴적환경의 외력조건으로 작용하는 조석, 파랑, 그리고 하천 등의 영향을 분석하였으며, 이에 따라 유동 및 퇴적환경 현황을 재현하였다. 재현결과 협수로와 곡선부에서 침식이 기타 수로에서는 퇴적이 우세한 양상을 보이는 것으로 나타났다. 또한 이를 근거하여 차후 1, 5, 10년에 대한 장기간의 모델링을 수행하였으며, 이에 대한 결과 현재 배수로의 퇴적환경은 평형상태로 유지되는 것으로 판단된다. 그러나 배수로로는 대부분 간사지로 대기노출시간의 높은 편으로 지반의 고화현상이 발생하여 이에 대한 고려는 거의 불가하기 때문에 결과 보정 시 이를 고려한 결과해석이 필요할 것으로 판단된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.401-405
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• 2016

중소하천에 기능을 상실한 하천 횡단 수리구조물이 많이 설치되어 있으며, 수리구조물 상류와 하류에 흐름 및 유사의 이송에 대한 연속성을 차단하고, 하천 교란의 원인이 되고 있다. 또한 사회적으로 수리구조물의 기능을 개선하거나 철거하여 하천복원의 필요성이 제기되고 있다. 따라서 본 연구에서는 실내실험을 통해 하천횡단 수리구조물에 의하여 형성된 상류의 지형이 하류에 미치는 영향을 분석하였다. 흐름이 하천횡단 수리구조물을 월류하면서 직하류에 세굴이 발생하고, 상류에서 델타를 형성하면서 퇴적되었다. 상류에서는 사주가 형성되었으며, 하류의 지형변화에 영향을 주었다. 하천횡단 수리구조물의 상류에 형성된 델타는 하류로 일정하게 이동하고 있으며, 델타가 구조물에 도달하기 바로 직전에서 수리구조물하류의 세굴이 가장 깊게 나타났다. 수리구조물 철거 후, 상류에 퇴적된 토사는 흐름에 의하여 급격하게 하류로 유실되었다. 천급점은 상류로 이동하며, 두부침식을 일으켰다. 일정한 시간이 지난 후에 상류에서 유입되는 유사에 의하여 침식은 감소되었다. 시간이 지나면서 하류에서 교호사주의 형상을 유지하며, 평형상태를 유지하였다.

• Prospectives of Industrial Chemistry
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• v.24 no.3
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• pp.28-41
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• 2021

고분자 시스템의 경우 매우 상이한 시간 및 길이 스케일(time and length scale)에 연관된 복잡한 내부 구조(internal structure)를 가지고 있기 때문에 전통적인 실험 방법만으로는 체계적이고 종합적인 연구가 쉽지 않다. 최근 다양한 시간 및 길이 스케일에 연관된 연구를 진행할 수 있는 다중 스케일 전산 모사(multiscale computer simulation) 방법은 이러한 고분자 시스템 연구에 있어서 새로운 대안으로 각광받고 있다. 본 논문에서는 최근 급격한 발전을 이룬 고분자 용액(polymeric liquid) 시스템에 대한 평형(equilibrium) 및 비평형(nonequilibrium) 전산 모사(computer simulation) 방법들에 관해 소개하고 이를 통합적으로 해석할 수 있는 다중 스케일 전산 모사 방법에 대해 여러 가지 사례를 들어 살펴보았다.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.282-291
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• 2012

The PGLE and PGLE3 nonionic surfactants were synthesized from the reaction between glycidol and lauryl acid and their structures were confirmed by $^1H$ and $^{13}C$ NMR analysis. The CMCs of PGLE and PGLE3 surfactants were found to be $3.59{\times}10^{-2}$ mol/L and $8.80{\times}10^{-2}$ mol/L respectively and the surface tensions at their CMC conditions were 26.09 mN/m and 28.68 mN/m respectively. Dynamic surface tension measurement has shown that the adsorption rate of surfactant molecules at the interface between air and surfactant solution was found to be relatively fast in both surfactant systems, presumably due to high mobility of surfactant molecules. The contact angles of PGLE and PGLE3 nonionic surfactants were $25.5^{\circ}$ and $9.5^{\circ}$ respectively. Dynamic interfacial tension measurement showed that both surfactant systems reached equilibrium in 20 minutes and the interfacial tensions at equilibrium condition in both systems were 0.42 mN/m and 0.53 mN/m respectively. The PGLE surfactant system has indicated higher foam stability than the PGLE3 surfactant system, which is consistent with surface tension measurement. The phase behavior experiments performed at $25{\sim}60^{\circ}C$ in systems containing nonionic surfactant, water, n-hydrocarbon oil and cosurfactant showed a lower phase or oil in water microemulsion in equilibrium with excess oil phase at all conditions investigated during this study.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.29 no.6
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• pp.583-590
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• 2016

This paper presents a dynamic crack propagation algorithm with Rayleigh damping effect based on the MLS(Moving Least Squares) Difference Method. Dynamic equilibrium equation and constitutive equation are derived by considering Rayliegh damping and governing equations are discretized by the MLS derivative approximation; the proportional damping, which has not been properly treated in the conventional strong formulations, was implemented in both the equilibrium equation and constitutive equation. Dynamic equilibrium equation including time relevant terms is integrated by the Central Difference Method and the discrete equations are simplified by lagging the velocity one step behind. A geometrical feature of crack is modeled by imposing the traction-free condition onto the nodes placed at crack surfaces and the effect of movement and addition of the nodes at every time step due to crack growth is appropriately reflected on the construction of total system. The robustness of the proposed numerical algorithm was proved by simulating single and multiple crack growth problems and the effect of proportional damping on the dynamic crack propagation analysis was effectively demonstrated.

• Applied Biological Chemistry
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• v.39 no.5
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• pp.398-402
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• 1996

This study was carried out to compare the fermentation rates of Dongchimi as affected by fermentation temperature and salt concentration of brining solution. The Dongchimi was prepared by fermentation of the radish in salt solutions of 2.0, 3.2 and 5.1% NaCl respectively with addition of garlic, green onion, ginger at $4^{\circ}C,\;10^{\circ}C,\;20^{\circ}C$. The fermentation was classified into 3 steps of initial, intermediate and final stages according to pH changes and the rates of fermentation and color change were calculated from intermediate stage. The time reached equilibrium in hardness of radish and salt concentration and their equilibrated values were also compared. Fermentation rate became more rapid as fermentation temperature and salt concentration increased. The rates of Hunter color change of Dongchimi liquid were increased as the temperature increased. The 'L' values decreased slowly, and 'a' and 'b' values increased rapidly to maximum at the intermediate stage. The time required to reach equilibrium was reduced for both salt concentration and hardness of radish as the fermentation temperature increased. The equilibrated values of salt concentration were increased while those of hardness of radish were decreased as the temperature and salt concentration increased. The data obtained can be used for prediction of some of the major characteristics of Dongchimi during fermentation.

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.37-44
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• 2011

The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.

• Applied Chemistry for Engineering
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• v.24 no.3
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• pp.327-332
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• 2013

Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

• Journal of Energy Engineering
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• v.17 no.4
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• pp.241-246
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• 2008

Increase of $CO_2$ by using fossil fuels makes mainly global warming and the international efforts to reduce the $CO_2$ emission is being promoted. Absorption process using aqueous alkanolamine solution to remove acid components in the mixed gases has been used commercially. This method was used to remove $CO_2$ in the flue gas in recent years. $CO_2$ Absorption characteristics of several aqueous alkanolamine solutions such as MEA, DEA and AMP was studied by measuring vapor-liquid-equilibrium(VLE) and absorption velocity in this study. VLE measuring equipment, shell and reactor type, was used to acquire VLE data, equilibrium $CO_2$ pressure(${P_{CO_2}}^*$) and time at each pulse gas input. We also acquired the $CO_2$ absorption velocity by measuring the time to arrive the VLE at $40{\sim}80^{\circ}C$ and first gas input. The $CO_2$ absorption capacity of MEA 10wt% solution was higher than two alkanolamine solutions at $40^{\circ}C$ and the equilibrium $CO_2$ loading was 0.5. Absorption capacity was excellent as follows; AMP>DEA>MEA. But absorption velocity was fast as follows; MEA>AMP>DEA. Though good absorbent was considered by many variables, absorption velocity and capacity was more important factor.

• Clean Technology
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• v.25 no.1
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• pp.56-62
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• 2019

The equilibrium, kinetic and thermodynamic parameters of adsorption of murexide by granular activated carbon were investigated. The experiment was carried out by batch experiment with the variables of the amount of the adsorbent, the initial concentration of the dye, the contact time and the temperature. The isothermal adsorption equilibrium was best applied to the Freundlich equation in the range of 293 ~ 313 K. From the separation factor (${\beta}$) of Freundlich equation, it was found that adsorption of murexide by granular activated carbon could be the appropriate treatment method. The adsorption energy (E) obtained from the Dubinin- Radushkevich equation shows that the adsorption process is a physical adsorption process. From the kinetic analysis of the adsorption process, pseudo second order model is more consistent than pseudo first order model. It was found that the adsorption process proceeded to a spontaneous process and an endothermic process through Gibbs free energy change ($-0.1096{\sim}-10.5348kJ\;mol^{-1}$) and enthalpy change ($+151.29kJ\;mol^{-1}$). In addition, since the Gibbs free energy change decreased with increasing temperature, adsorption reaction of murexide by granular activated carbon increased spontaneously with increasing temperature. The entropy change ($147.62J\;mol^{-1}\;K^{-1}$) represented the increasing of randomness at the solid-solution interface during the adsorption reaction of murexide by activated carbon.